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95-46-5

Basic Information
CAS No.: 95-46-5
Name: Benzene,1-bromo-2-methyl-
Article Data: 174
Cas Database
Molecular Structure:
Molecular Structure of 95-46-5 (Benzene,1-bromo-2-methyl-)
Formula: C7H7Br
Molecular Weight: 171.037
Synonyms: Toluene,o-bromo- (8CI);1-Bromo-2-methylbenzene;2-Bromo-1-methylbenzene;2-Bromotoluene;2-Methyl-1-bromobenzene;2-Methylbromobenzene;2-Methylphenylbromide;2-Tolyl bromide;NSC 6532;o-Bromomethylbenzene;o-Bromotoluene;o-Methylbromobenzene;o-Methylphenyl bromide;o-Tolyl bromide;
EINECS: 202-421-7
Density: 1.403 g/cm3
Melting Point: -27 °C
Boiling Point: 180.8 °C at 760 mmHg
Flash Point: 67.1 °C
Solubility: <0.1 g/100 mL at 15 °C in water
Appearance: liquid
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 22-36/37/38
Safety: 36/37/39-37/39-26
Transport Information: N/A
PSA: 0.00000
LogP: 2.75750
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Chemistry

The Molecular formula of 2-BROMOTOLUENE(95-46-5): C7H7Br
The Molecular Weight of 2-BROMOTOLUENE(95-46-5): 171.03
Molecular Structure:
EINECS: 202-421-7
Boiling Point: 180.8 °C at 760 mmHg 
Flash Point: 67.1 °C 
Index of Refraction: 1.548 
Molar Refractivity: 38.76 cm
Molar Volume: 121.8 cm
Polarizability: 15.36 10 -24 cm3 
Surface Tension: 34.4 dyne/cm 
Density: 1.403 g/cm3 
Enthalpy of Vaporization: 39.99 kJ/mol 
Vapour Pressure: 1.2 mmHg at 25°C 
Water Solubility: <0.1 g/100 mL at 15 oC
Stability: Stable. Incompatible with strong oxidizing agents.
Merck: 14,1439
BRN: 1904176
IUPAC Name: 1-bromo-2-methylbenzene
Synonyms: 1-Brom-2-methylbenzol;1-Methyl-2-bromobenzene;2-Methylphenylbromide;2-Tolyl bromide;2-tolylbromide;2-bromo-toluen;2-Bromtoluol;1-bromo-2-methyl-benzen;

Uses

2-BROMOTOLUENE(95-46-5) is used for organic synthesis of raw materials and intermediates, also used in the pharmaceutical industry.

Toxicity Data With Reference

1.   

orl-mus LD50:1864 mg/kg

   GISAAA    Gigiena i Sanitariya. 44 (12)(1979),19.
2.   

ipr-mus LD50:1358 mg/kg

   GISAAA    Gigiena i Sanitariya. 44 (12)(1979),19.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and intraperitoneal route. When heated to decomposition it emits toxic vapors of Br.
The Hazard Codes of 2-BROMOTOLUENE(95-46-5):  Xn,Xi
Hazard Note: Harmful/Irritant
The Risk Statements information of 2-BROMOTOLUENE(95-46-5):
22:  Harmful if swallowed 
36/37/38:  Irritating to eyes, respiratory system and skin 
The Safety Statements information of 2-BROMOTOLUENE(95-46-5):
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
37/39:  Wear suitable gloves and eye/face protection 
WGK Germany: 3
RTECS: XS7965500
HS Code: 29036990