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Basic Information
| CAS No.: | 95-46-5 |
|---|---|
| Name: | 2-Bromotoluene |
| Article Data: | 174 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H7Br |
| Molecular Weight: | 171.037 |
| Synonyms: | Toluene,o-bromo- (8CI);1-Bromo-2-methylbenzene;2-Bromo-1-methylbenzene;2-Bromotoluene;2-Methyl-1-bromobenzene;2-Methylbromobenzene;2-Methylphenylbromide;2-Tolyl bromide;NSC 6532;o-Bromomethylbenzene;o-Bromotoluene;o-Methylbromobenzene;o-Methylphenyl bromide;o-Tolyl bromide; |
| EINECS: | 202-421-7 |
| Density: | 1.403 g/cm3 |
| Melting Point: | -27 °C |
| Boiling Point: | 180.8 °C at 760 mmHg |
| Flash Point: | 67.1 °C |
| Solubility: | <0.1 g/100 mL at 15 °C in water |
| Appearance: | liquid |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22-36/37/38 |
| Safety: | 36/37/39-37/39-26 |
| PSA: | 0.00000 |
| LogP: | 2.75750 |
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2-Bromotoluene
Chemistry
The Molecular formula of 2-BROMOTOLUENE(95-46-5): C7H7Br
The Molecular Weight of 2-BROMOTOLUENE(95-46-5): 171.03
Molecular Structure:
EINECS: 202-421-7
Boiling Point: 180.8 °C at 760 mmHg
Flash Point: 67.1 °C
Index of Refraction: 1.548
Molar Refractivity: 38.76 cm3
Molar Volume: 121.8 cm3
Polarizability: 15.36 10 -24 cm3
Surface Tension: 34.4 dyne/cm
Density: 1.403 g/cm3
Enthalpy of Vaporization: 39.99 kJ/mol
Vapour Pressure: 1.2 mmHg at 25°C
Water Solubility: <0.1 g/100 mL at 15 oC
Stability: Stable. Incompatible with strong oxidizing agents.
Merck: 14,1439
BRN: 1904176
IUPAC Name: 1-bromo-2-methylbenzene
Synonyms: 1-Brom-2-methylbenzol;1-Methyl-2-bromobenzene;2-Methylphenylbromide;2-Tolyl bromide;2-tolylbromide;2-bromo-toluen;2-Bromtoluol;1-bromo-2-methyl-benzen;
The Molecular Weight of 2-BROMOTOLUENE(95-46-5): 171.03
Molecular Structure:
EINECS: 202-421-7
Boiling Point: 180.8 °C at 760 mmHg
Flash Point: 67.1 °C
Index of Refraction: 1.548
Molar Refractivity: 38.76 cm3
Molar Volume: 121.8 cm3
Polarizability: 15.36 10 -24 cm3
Surface Tension: 34.4 dyne/cm
Density: 1.403 g/cm3
Enthalpy of Vaporization: 39.99 kJ/mol
Vapour Pressure: 1.2 mmHg at 25°C
Water Solubility: <0.1 g/100 mL at 15 oC
Stability: Stable. Incompatible with strong oxidizing agents.
Merck: 14,1439
BRN: 1904176
IUPAC Name: 1-bromo-2-methylbenzene
Synonyms: 1-Brom-2-methylbenzol;1-Methyl-2-bromobenzene;2-Methylphenylbromide;2-Tolyl bromide;2-tolylbromide;2-bromo-toluen;2-Bromtoluol;1-bromo-2-methyl-benzen;
Uses
2-BROMOTOLUENE(95-46-5) is used for organic synthesis of raw materials and intermediates, also used in the pharmaceutical industry.
Toxicity Data With Reference
| 1. | orl-mus LD50:1864 mg/kg | GISAAA Gigiena i Sanitariya. 44 (12)(1979),19. | ||
| 2. | ipr-mus LD50:1358 mg/kg | GISAAA Gigiena i Sanitariya. 44 (12)(1979),19. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by ingestion and intraperitoneal route. When heated to decomposition it emits toxic vapors of Br−.
The Hazard Codes of 2-BROMOTOLUENE(95-46-5):
Xn,Xi
Hazard Note: Harmful/Irritant
The Risk Statements information of 2-BROMOTOLUENE(95-46-5):
22: Harmful if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 2-BROMOTOLUENE(95-46-5):
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
37/39: Wear suitable gloves and eye/face protection
WGK Germany: 3
RTECS: XS7965500
HS Code: 29036990
The Hazard Codes of 2-BROMOTOLUENE(95-46-5):
Xn,Xi Hazard Note: Harmful/Irritant
The Risk Statements information of 2-BROMOTOLUENE(95-46-5):
22: Harmful if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 2-BROMOTOLUENE(95-46-5):
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
37/39: Wear suitable gloves and eye/face protection
WGK Germany: 3
RTECS: XS7965500
HS Code: 29036990