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| CAS No.: | 96-34-4 |
|---|---|
| Name: | Methyl chloroacetate |
| Article Data: | 71 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H5ClO2 |
| Molecular Weight: | 108.525 |
| Synonyms: | Aceticacid, chloro-, methyl ester (6CI,8CI,9CI);Chloroacetic acid methyl ester;Methyl 2-chloroacetate;Methyl monochloracetate;Methyl a-chloroacetate;Monochloroacetic acid methyl ester;NSC 2635; |
| EINECS: | 202-501-1 |
| Density: | 1.167 g/cm3 |
| Melting Point: | -33 °C |
| Boiling Point: | 132.2 °C at 760 mmHg |
| Flash Point: | 51.7 °C |
| Solubility: | water: 28 g/L (20 °C) |
| Appearance: | clear colourless liquid |
| Hazard Symbols: |
 T, Xi, F
|
| Risk Codes: | 10-23/25-41-40-36/37/38 |
| Safety: | 26-37/39-45-36-16 |
| Transport Information: | UN 2295 6.1/PG 1 |
| PSA: | 26.30000 |
| LogP: | 0.39820 |
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| Conditions | Yield |
|---|---|
| With titanium tetrachloride; acrylic acid methyl ester In dichloromethane at 20℃; for 0.0333333h; Inert atmosphere; | 96% |
| With hydrogenchloride In water |
| Conditions | Yield |
|---|---|
| F-4SK (H form) In dichloromethane at 41℃; for 15h; | 94% |
| With iron(III) sulfate; sulfuric acid for 1h; Heating; | 94% |
| With sulfuric acid for 6h; Fischer–Speier Esterification; Reflux; | 89% |
- 6832-16-2
methyl diazoacetate
- 292638-85-8
acrylic acid methyl ester
A
- 19255-80-2
5-methoxycarbonyl-pyrazoline-3-carboxylic acid methyl ester
B
- 96-34-4
methyl chloroacetate
| Conditions | Yield |
|---|---|
| With ethylaluminum dichloride In hexane; dichloromethane at 20℃; for 0.0666667h; Inert atmosphere; | A 90% B 5% |
| With tin(IV) chloride In dichloromethane at 20℃; for 0.0333333h; Inert atmosphere; | A 10% B 85% |
- 6832-16-2
methyl diazoacetate
- 292638-85-8
acrylic acid methyl ester
A
- 19255-80-2
5-methoxycarbonyl-pyrazoline-3-carboxylic acid methyl ester
B
- 1262030-04-5
dimethyl 1-(2-methoxy-2-oxoethyl)-4,5-dihydro-1H-pyrazole-3,5-dicarboxylate
C
- 96-34-4
methyl chloroacetate
| Conditions | Yield |
|---|---|
| With gallium(III) trichloride In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere; | A 15% B 76% C 5% |
- 96-34-4
methyl chloroacetate
| Conditions | Yield |
|---|---|
| With hydrogenchloride In chloroform-d1 for 24h; Ambient temperature; | 72% |
| Conditions | Yield |
|---|---|
| sulfuric acid In methanol Heating; | 51% |
| Conditions | Yield |
|---|---|
| With silver tetrafluoroborate; lithium fluoride In methanol; diethyl ether at 0℃; for 0.5h; Yield given; | A n/a B 6% C 10% |
| With silver tetrafluoroborate; lithium fluoride In methanol; diethyl ether at 0℃; for 0.5h; | A n/a B 6% C 10% |
| With silver tetrafluoroborate; lithium fluoride In diethyl ether at 0℃; for 30h; | A n/a B 6% C 10% |
- 67-66-3
chloroform
- 6832-16-2
methyl diazoacetate
A
- 20618-07-9
methyl 2,3,3-trichloropropanoate
B
- 96-34-4
methyl chloroacetate
| Conditions | Yield |
|---|---|
| UV-Licht.Irradiation; | |
| im UV-Licht; |
- 67-56-1
methanol
- 42345-82-4
(E)-1,2-dichloro-1-ethoxy-ethene
A
- 96-34-4
methyl chloroacetate
B
- 105-39-5
chloroacetic acid ethyl ester
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Chemistry
IUPAC Name: Methyl 2-chloroacetate
Synonyms of Methyl chloroacetate (CAS NO.96-34-4): AI3-39185 ; Acetic acid, chloro-, methyl ester ; CCRIS 7749 ; Chloroacetic acid methyl ester ; EINECS 202-501-1 ; HSDB 5303 ; Methyl alpha-chloroacetate ; Methyl chloroethanoate ; Methyl monochloracetate ; Methyl monochloroacetate ; Methylester kyseliny chloroctove ; Methylester kyseliny chloroctove [Czech] ; Monochloroacetic acid methyl ester ; NSC 2635 ; Acetic acid, 2-chloro-, methyl ester ; Methyl chloroacetate [UN2295] [Poison] ; UN2295
CAS NO: 96-34-4
Molecular Formula of Methyl chloroacetate (CAS NO.96-34-4): C3H5ClO2
Molecular Weight: 108.5236
Molecular Structure:
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Melting Point: -33 °C
ProductCategories: Organics ; Alpha sort ; H-MAlphabetic ; M ; META - METH ; Pesticides&Metabolites ;C2 to C5 ; Carbonyl Compounds ; Esters ; 500 Series Drinking Water Methods ; EPA ; Method 552
Polar Surface Area: 26.3 Å2
Index of Refraction: 1.4
Molar Refractivity: 22.57 cm3
Molar Volume: 92.9 cm3
Surface Tension: 28.4 dyne/cm
Density of Methyl chloroacetate (CAS NO.96-34-4): 1.167 g/cm3
Flash Point: 51.7 °C
Enthalpy of Vaporization: 39.23 kJ/mol
Boiling Point: 132.2 °C at 760 mmHg
Vapour Pressure: 8.97 mmHg at 25°C
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mammal (species unspecified) | LD50 | oral | 240mg/kg (240mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974. | |
| mouse | LC50 | inhalation | 1gm/m3/2H (1000mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 82, 1982. | |
| mouse | LD50 | oral | 240mg/kg (240mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 82, 1982. | |
| rat | LCLo | inhalation | 250ppm/7H (250ppm) | KIDNEY, URETER, AND BLADDER: OTHER CHANGES | Toxicology and Applied Pharmacology. Vol. 19, Pg. 1, 1971. |
| rat | LD16 | subcutaneous | 560mg/kg (560mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 82, 1982. |
Consensus Reports
Methyl chloroacetate (CAS NO.96-34-4) Market Research Report 2009
Safety Profile
Hazard Codes: 
T,
Xi,
F
Risk Statements: 10-23/25-41-40-36/37/38
R10: Flammable.
R23/25: Toxic by inhalation and if swallowed.
R41: Risk of serious damage to the eyes.
R40: Limited evidence of a carcinogenic effect.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39-45-36-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36: Wear suitable protective clothing.
S16: Keep away from sources of ignition.
RIDADR: UN 2295 6.1/PG 1
WGK Germany: 2
RTECS: AF9500000
F: 19
HazardClass: 6.1
PackingGroup: I
Hazardous Substances Data: 96-34-4(Hazardous Substances Data)