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99-99-0

Basic Information
CAS No.: 99-99-0
Name: Benzene,1-methyl-4-nitro-
Molecular Structure:
Molecular Structure of 99-99-0 (Benzene,1-methyl-4-nitro-)
Formula: C7H7NO2
Molecular Weight: 137.14
Synonyms: Toluene,p-nitro- (8CI);1-Methyl-4-nitrobenzene;4-Methyl-1-nitrobenzene;4-Methylnitrobenzene;4-Nitrotoluene;4-Nitrotoluol;NSC 9579;p-Methylnitrobenzene;p-Nitrotoluene;para-Nitrotoluene;
EINECS: 202-808-0
Density: 1.166 g/cm3
Melting Point: 51-54 °C
Boiling Point: 238 °C at 760 mmHg
Flash Point: 106.1 °C
Solubility: water: 0.35 g/L (20 °C)
Appearance: light yellow crystals
Hazard Symbols: ToxicT; FlammableF; DangerousN
Risk Codes: 23/24/25-33-51/53-36/37/38-11
Safety: 28-37-45-61-27-16
Transport Information: UN 3446 6.1/PG 2
PSA: 45.82000
LogP: 2.42640
Related products
Synthetic route
104-03-0

4-nitrobenzeneacetic acid

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
copper(I) oxide In acetonitrile at 50℃;100%
With [Rh(OH)(cod)]2; 1,3-bis-(diphenylphosphino)propane; water; sodium hydroxide In toluene at 100℃; for 16h; Inert atmosphere;87%
With potassium carbonate In chloroform at 20℃; for 24h; Irradiation; Inert atmosphere;81%
636-98-6

p-nitrobenzene iodide

(CH3)4Sn

(CH3)4Sn

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
polymer supported palladium catalyst In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 1h; Stille coupling reaction;100%

4-nitrobenzenediazonium o-benzenedisulfonimide

594-27-4

tetramethylstannane

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
palladium diacetate In tetrahydrofuran at 40℃; for 0.5h;100%
100-14-1

4-nitrobenzyl chloride

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; cetyltributylphosphonium bromide In water; toluene at 40℃; for 0h; Product distribution;99%
With phosphonic Acid; iodine In benzene at 100℃; for 36h; Inert atmosphere;42%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In toluene for 3h; Mechanism; Irradiation;24%
100-11-8

1-bromomethyl-4-nitro-benzene

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; cetyltributylphosphonium bromide In water; toluene at 18℃; for 0h; Product distribution;99%
With sodium tetrahydroborate In aq. phosphate buffer at 70℃; for 2.5h; pH=12; Reagent/catalyst; Green chemistry;95%
With sodium tetrahydroborate In various solvent(s) at 70℃; for 10h;88%

potassium (4-methylphenyl)trifluoroborate

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With bismuth (III) nitrate pentahydrate In toluene at 120℃; for 0.333333h; Reagent/catalyst; Microwave irradiation;99%
With sodium dihydrogen phosphate monohydrate; dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); sodium nitrite In toluene at 120℃; for 0.5h; Microwave irradiation; Inert atmosphere;33%
106-49-0

p-toluidine

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With calcium tungstate; dihydrogen peroxide In water at 50℃; for 0.5h; Reagent/catalyst; Green chemistry; Large scale;98%
With oxaziridinium tetrafluoroborate derived from N-methyl-1,2,3,4-tetrahydroisoquinoline In dichloromethane at 0℃; for 10h;92%
With 1,9-diperoxynonanedioic acid In acetonitrile at 50℃; for 0.5h;92%
636-98-6

p-nitrobenzene iodide

594-27-4

tetramethylstannane

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With C31H33INPPd In N,N-dimethyl-formamide at 80℃; for 24h; Stille coupling;98%
With iodophenylbis(triphenylphosphine)palladium In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 0.5h;87%
108-88-3

toluene

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium nitrate In neat (no solvent) at 20℃; for 0.05h; Catalytic behavior; Reagent/catalyst; Green chemistry;96%
With nitric acid; sodium dodecyl-sulfate In water at 25℃; for 0.333333h; Micellar solution; Green chemistry; regioselective reaction;86%
With tetrammine copper(II) sulphate; nitric acid In dichloromethane; water at 20℃; for 3h; regioselective reaction;85%

2-methyl-5-nitrobenzenediazonium o-benzenedisulfonimide

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran for 0.166667h; Heating;94%
823-96-1

Trimethylboroxine

100-00-5

4-chlorobenzonitrile

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether; bis-phenanthrylimidazolium chloride; palladium diacetate In tetrahydrofuran at 20℃; for 8h; Suzuki-Miyaura coupling;93%
3113-72-2

5-methyl-2-nitrobenzoic acid

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sulfolane; sodium hydrogencarbonate at 230℃; for 2.5h; Temperature; Reagent/catalyst;92%
With copper(l) iodide; triethylamine In dimethyl sulfoxide at 120℃; under 760.051 Torr; for 20h; Inert atmosphere; Schlenk technique;88%
With copper(I) oxide; 1,10-Phenanthroline In 1-methyl-pyrrolidin-2-one; quinoline at 190℃; for 0.0833333h; Microwave irradiation;80%
With copper(I) oxide at 120℃; for 24h; Ionic liquid;
5720-05-8

4-methylphenylboronic acid

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;92%
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction;92%
With bismuth (III) nitrate pentahydrate In toluene at 70 - 80℃; for 1.5h; Inert atmosphere;87%
108-88-3

toluene

A

99-99-0

1-methyl-4-nitrobenzene

B

88-72-2

1-methyl-2-nitrobenzene

Conditions
ConditionsYield
With nickel ammonium sulfate; nitric acid In chloroform; water at 20℃; for 4h;A 88%
B 12%
With sodium nitrite for 0.0166667h; Reagent/catalyst; Microwave irradiation;A 82%
B 15%
With bismuth(III) nitrate In tetrachloromethaneA 80%
B n/a
555-16-8

4-nitrobenzaldehdye

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane87%
With hydrogen; palladium on activated charcoal In methanol under 760 Torr; for 18h;33%
636-98-6

p-nitrobenzene iodide

59201-86-4

tris(diethylamino)sulfonium difluorotrimethylsiliconate

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
π-allyl-palladium chloride In tetrahydrofuran 1.) room temperature; 2.) 50 deg C, 20 h;86%
2417-95-0

p-tolyllithium

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dinitrogen tetraoxide In tetrahydrofuran -190 deg C -> room temperature;86%
1747-50-8

4-methyl-N'-[(4-nitrophenyl)methylidene]benzene-1-sulfonohydrazide

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dichloro bis(1,4-diazabicyclo[2.2.2]octane)(BH4)Zr(IV); toluene-4-sulfonic acid In sulfolane; N,N-dimethyl-formamide at 110℃; for 6h;86%
17763-80-3

para-nitrophenyl triflate

potassium trifluoro(methyl)boranuide

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; water; caesium carbonate In tetrahydrofuran Suzuki coupling reaction; Heating;85%
108-88-3

toluene

A

99-99-0

1-methyl-4-nitrobenzene

B

88-72-2

1-methyl-2-nitrobenzene

C

65-85-0

benzoic acid

Conditions
ConditionsYield
With methanesulfonic acid; 1-butyl-3-methylimidazolium nitrate In water for 48h; Heating / reflux;A n/a
B n/a
C 85%
With nitric acid; 1-butyl-3-methylimidazolium nitrate In water for 48h; Heating / reflux;A n/a
B n/a
C 85%
With nitric acid; 1-n-butyl-3-methylimidazolium methanesulfonate In water for 48h; Heating / reflux;A n/a
B n/a
C 70%
With nitric acid; 1-n-butyl-3-methylimidazolium methanesulfonate In water for 48h; Heating / reflux;A n/a
B n/a
C 70%
108-88-3

toluene

A

99-99-0

1-methyl-4-nitrobenzene

B

121-14-2

2,4-dinitrotoluene

C

606-20-2

2,6-dinitrotoluene

Conditions
ConditionsYield
With succinic acid anhydride; nitric acid at 4℃; for 50h; Product distribution / selectivity;A 7.9%
B 85%
C 6.3%
With nitric acid; dichloroacetic anhydride In dichloromethane at 50℃; for 0.166667h; Time;
99-94-5

p-Toluic acid

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction;85%
With 1,3-disulfonic acid imidazolium nitrate In neat (no solvent) at 50℃; for 0.5h; Inert atmosphere;76%
99-97-8

Dimethyl-p-toluidine

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; ammonium iodide; water In dimethyl sulfoxide at 90℃; for 4h; Mechanism; Temperature; Reagent/catalyst; Solvent; Time; Sealed tube;85%

C12H13NO4

A

99-99-0

1-methyl-4-nitrobenzene

B

C11H13NO2

Conditions
ConditionsYield
With C53H50IrNO2P(1-)*ClO4(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 14h; Reagent/catalyst; Inert atmosphere; Sealed tube; enantioselective reaction;A n/a
B 83%
636-98-6

p-nitrobenzene iodide

143-36-2

methylmercury(II) iodide

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride; sodium iodide In N,N-dimethyl-formamide at 20℃; for 0.333333h; Inert atmosphere;82%
With PhPd(PPh3)2 In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 1.5h; Product distribution; other solvent, reaction time, temperature;91 % Chromat.
With iodide; iodophenylbis(triphenylphosphine)palladium In acetone at 20℃; for 0.5h;98 % Chromat.
594-27-4

tetramethylstannane

p-nitrobenzenediazonium hydrogen sulfate

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
palladium diacetate In water; acetonitrile at 20℃; for 2h;81%
With palladium diacetate In water; acetonitrile at 20℃; for 2h;81%
palladium diacetate In water; acetonitrile at 20℃; for 2h; other aryldiazonium salts;81%
13061-96-6

dihydroxy-methyl-borane

17763-80-3

para-nitrophenyl triflate

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In tetrahydrofuran; water for 18h; Suzuki coupling reaction; Heating;80%
586-78-7

para-nitrophenyl bromide

(CH3)4Sn

(CH3)4Sn

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
polymer supported palladium catalyst In N,N-dimethyl-formamide at 70℃; for 4h; Stille coupling reaction;80%
123726-16-9

bis(4-methylphenyl)iodonium trifluoromethanesulfonate

99-99-0

1-methyl-4-nitrobenzene

Conditions
ConditionsYield
With sodium nitrite In ethyl acetate at 70℃; for 16h; Sealed tube;80%
108-88-3

toluene

A

99-08-1

1-methyl-3-nitrobenzene

B

99-99-0

1-methyl-4-nitrobenzene

C

88-72-2

1-methyl-2-nitrobenzene

Conditions
ConditionsYield
With copper(II) nitrate on K10 montmorillonite; acetic anhydride In tetrachloromethane for 120h; Ambient temperature;A 1%
B 79%
C 20%
With nitric acid In trifluoroacetic acid at 25℃; Rate constant;A 0.7%
B 66.7%
C 32.6%
With ortho-methylphenyl iodide; potassium nitrate In trifluoroacetic acid for 0.5h; Product distribution; nitration of aromatic compounds in the presence of aryl iodides; other temperatures, other reagents;A n/a
B 64%
C 33%
99-99-0

1-methyl-4-nitrobenzene

121-14-2

2,4-dinitrotoluene

Conditions
ConditionsYield
With nitric acid at 50℃; for 3h;100%
With nitrourea; sulfuric acid at 25℃; for 24h;99%
With ethylene glycol dinitrate In sulfuric acid at 0 - 20℃;99%
99-99-0

1-methyl-4-nitrobenzene

623-10-9

N-(4-methylphenyl)hydroxylamine

Conditions
ConditionsYield
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere;100%
With rhodium contaminated with carbon; hydrazine hydrate In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;100%
99-99-0

1-methyl-4-nitrobenzene

121-02-8

2-methyl-5-nitrobenzene-1-sulfonyl chloride

Conditions
ConditionsYield
With chlorosulfonic acid100%
With chlorosulfonic acid at 60℃; for 20h;96%
With chlorosulfonic acid at 5 - 140℃; for 22.5h;80.6%
99-99-0

1-methyl-4-nitrobenzene

106-49-0

p-toluidine

Conditions
ConditionsYield
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.5h; Inert atmosphere;100%
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction;100%
With sodium tetrahydroborate In ethanol; water at 39.84℃; for 2h; Reagent/catalyst;100%
99-99-0

1-methyl-4-nitrobenzene

100-11-8

1-bromomethyl-4-nitro-benzene

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water for 4h; Reagent/catalyst; Reflux;100%
With 2,2'-azobis(isobutyronitrile); hydrogen bromide; dihydrogen peroxide at 70 - 120℃; Reagent/catalyst; Temperature;99.3%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Reflux;95%
99-99-0

1-methyl-4-nitrobenzene

108-24-7

acetic anhydride

103-89-9

4-Methylacetanilide

Conditions
ConditionsYield
With ammonium formate; titanium(IV) oxide; β‐cyclodextrin In water for 3.5h; Irradiation; Inert atmosphere;100%
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 60 - 70℃; Green chemistry;
Stage #2: acetic anhydride In water at 60 - 70℃; Green chemistry;
95%
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 20℃; for 0.5h; Green chemistry;
Stage #2: acetic anhydride In water at 20℃; for 2.16667h; Green chemistry;
95%
109-74-0

propyl cyanide

99-99-0

1-methyl-4-nitrobenzene

A

31144-33-9

N,N-dibutyl-4-methylaniline

B

10387-24-3

N-butyl-4-methylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃;
Stage #2: propyl cyanide In methanol; water
A n/a
B 100%
99-99-0

1-methyl-4-nitrobenzene

107-12-0

propiononitrile

A

54837-90-0

N-propyl-p-tolylamine

B

3480-93-1

4-methyl-N,N-dipropylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With ammonium formate; palladium on activated charcoal In methanol; water at 20℃;
Stage #2: propiononitrile In methanol; water
A 100%
B n/a
99-99-0

1-methyl-4-nitrobenzene

110-13-4

2,5-hexanedione

5044-26-8

2,5-dimethyl-1-p-tolyl-1H-pyrrole

Conditions
ConditionsYield
With formic acid for 12h; Autoclave; Inert atmosphere; Green chemistry;100%
With indium; acetic acid In toluene at 80℃; for 2.5h; Inert atmosphere;98%
99-99-0

1-methyl-4-nitrobenzene

3284-64-8

1-nitro-4-(trichloromethyl)benzene

Conditions
ConditionsYield
With hypochlorous anhydride In tetrachloromethane at 25℃; for 96h;99%
99-99-0

1-methyl-4-nitrobenzene

100-52-7

benzaldehyde

1694-20-8

trans-4-nitrostilbene

Conditions
ConditionsYield
With 18-crown-6 ether; graphitic carbon nitride In toluene at 25℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Knoevenagel Condensation;99%
With potassium carbonate at 90℃; for 2h; neat (no solvent); stereoselective reaction;71%
111-71-7

heptanal

99-99-0

1-methyl-4-nitrobenzene

371959-15-8

N-heptyl-4-methylbenzene amine

Conditions
ConditionsYield
With Au/Al2O3; hydrogen In toluene at 80℃; under 37503.8 Torr; Temperature; Flow reactor; chemoselective reaction;99%
With hydrogen In toluene at 110℃; under 22502.3 Torr; Catalytic behavior; Temperature; Flow reactor;92 %Chromat.
99-99-0

1-methyl-4-nitrobenzene

106-49-0

p-toluidine

589-92-4

1-methylcyclohexan-4-one

620-93-9

di-p-tolylamine

Conditions
ConditionsYield
palladium-carbon In water; N,N-dimethyl-formamide; benzene98.6%
palladium-carbon In water; N,N-dimethyl-formamide; benzene98.6%
99-99-0

1-methyl-4-nitrobenzene

5258-64-0

4-nitrotoluene-2-sulfonic acid sodium salt

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With chlorosulfonic acid at 115℃; for 3h;
Stage #2: With sodium carbonate In water at 20℃;
98.2%
99-99-0

1-methyl-4-nitrobenzene

7745-93-9

2-bromo-4-nitrotoluene

Conditions
ConditionsYield
With bromine fluoride In ethanol; chloroform at -40℃; for 1h;98%
With thallium (III) oxide; trifluoroacetic acid; potassium bromide at 20℃; for 165h;98%
With N-Bromosuccinimide; sulfuric acid In water at 20℃; for 24h;93%
99-99-0

1-methyl-4-nitrobenzene

555-16-8

4-nitrobenzaldehdye

Conditions
ConditionsYield
With oxygen; 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt In tetrahydrofuran Ambient temperature; laccase from Coriolus versicolor;98%
With dihydrogen peroxide In acetonitrile at 50 - 80℃; for 24h; Reagent/catalyst;95%
With nickel-doped graphene carbon nitride nanoparticles; air In ethanol at 25℃; for 8h; Irradiation; Green chemistry;95%
99-99-0

1-methyl-4-nitrobenzene

3085-54-9

N-(4-methylphenyl)formamide

Conditions
ConditionsYield
With cobalt nanoparticles coated by N,P-codoped carbon shell pyrolyzed at 800°C In tetrahydrofuran at 120℃; for 12h; Schlenk technique; Inert atmosphere;98%
With hydrogen; palladium on activated charcoal In acetonitrile at 95℃; for 7h;89%
With gold nanoparticles supported on titanium dioxide (TiO2) In acetonitrile for 3h; Inert atmosphere; Reflux;88%
With glycolic Acid at 30℃; for 48h; Catalytic behavior; Reagent/catalyst; Temperature; Irradiation; Inert atmosphere;85 %Spectr.
99-99-0

1-methyl-4-nitrobenzene

24424-99-5

di-tert-butyl dicarbonate

14618-59-8

N-(tert-butoxycarbonyl)-4-methylaniline

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene With sodium tetrahydroborate In water at 20℃; for 0.5h; Green chemistry;
Stage #2: di-tert-butyl dicarbonate In water at 20℃; for 1.16667h; Green chemistry;
98%
With tin; ammonium chloride In methanol at 25℃; for 4.5h; Sonication;87%
50-00-0

formaldehyd

99-99-0

1-methyl-4-nitrobenzene

141-97-9

ethyl acetoacetate

ethyl 3-(N-methyl-N-4-tolylamino)butanoate

Conditions
ConditionsYield
Stage #1: 1-methyl-4-nitrobenzene; ethyl acetoacetate With Decaborane; palladium on activated charcoal In methanol for 1.5h; Heating;
Stage #2: With Decaborane In methanol at 20℃; for 2h;
Stage #3: formaldehyd With Decaborane In methanol; water at 20℃; for 3h;
98%
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    Para-Nitrotoluene

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    99-99-0

    4-Nitrotoluene

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      Wuhan Kemi-Works Chemical Co., Ltd, specialized in R&D, production and sales of pharmaceutical intermediates, electronic chemicals, organic fluorine surfactant,

  •  Wuhan Kemi-Works Chemical Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-27-85736489

    Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China

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  • 4-Nitrotoluene

  • Casno:

    99-99-0

    4-Nitrotoluene

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    We, Jilin Tely Imp & Exp Co., Ltd. mainly supply and export products including: pharmaceutical raw materials,Chemical reagents, Food additives, pharmaceutical and pesticide interme

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

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    Address:Room 302, 47 Changping Street, Chaoyang District, Changchun, Jilin Province,China

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    99-99-0

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  •  Hangzhou J&H Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    99-99-0

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    99%, in stock Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-21-50762507

    Address:No. 3377, Kang Xin Road, Pudong New Area, Shanghai

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  • Casno:

    99-99-0

    4-Nitrotoluene

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    Product Name 4-Nitrotoluene Synonyms 4-Methylnitrobenzene; p-Nitrophenylmethane; 4-Nitrotoluol CAS No. 99-99-0 EINECS 202-808-0 Molecular Formula

    Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

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    Address:Zhang zhe, guangzong county, xingtai city, hebei province

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    99-99-0

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    Kono Chem Co.,Ltd is a leading producer of standardized herbal extracts, natural active ingredients and APIs for pharmaceutical, health food and cosmetic industries. Annually, mo

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-29-86107037-8015

    Address:No.11 Daqing Road,Lianhu District,Xi’an 710082,China

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  • Casno:

    99-99-0

    Para Nitro Toluene

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    Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

    Xiamen Aeco Chemical Industrial Co., Ltd(same as Aecochem Corp.) An ISO 9001:2015 Certified Company Your Partner in China, a Professional chemical raw material supplier, our

  •  Aecochem Corp.

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:+86-592 599 8717

    Address:No 611 Sishui Road,Huli

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  • Casno:

    99-99-0

    4-Nitrotoluene

    Min.Order: 0

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    high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

    Located in Zhengdong New District,?Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is a comprehensive high-tech modern enterprises integrating professional R&D, pro

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:+86-0371-87507775

    Address:No 260 Dongming Road,Jinshui District

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  • Casno:

    99-99-0

    4-Nitrotoluene

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    4-Nitrotoluene CAS#99-99-0 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

    Orchid Chemical was established in 2009; we are headquartered in Hangzhou, which is 200 km from China's biggest sea port, Shanghai. Orchid chemical is a joint-venture company, com

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-571-85395792

    Address:607, North Zhongshan Road, Hangzhou 310000 China

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  • Casno:

    99-99-0

    99-99-0

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    Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu P

  •  Nanjing Chemlin Chemical Co., Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-25-83697070

    Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China

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  • Casno:

    99-99-0

    4-Nitrotoluene

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:0086-21-50563169

    Address:Room1027,No.Jinyu Road,Pudong

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  • Casno:

    99-99-0

    Benzene,1-methyl-4-nitro-

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    Who we are ? Located in Zhengzhou City, China , Henan Daken Chemical Co.,Ltd was Established in June ,1983.We have a 35 years history for fine chemical synthesis .Daken has young

  •  Henan DaKen Chemical CO.,LTD.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-371-55541817

    Address:No.56 Hongzhuan Road,Jinshui,Zhengzhou,450000,China

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  • Casno:

    99-99-0

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    Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketi

  •  Hangzhou ZeErRui Chemical Co., Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-82512721

    Address:No 317,Jingling Road,Guali Town,Xiaoshan District

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    99-99-0

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:0086-576-84610586

    Address:Chemical Development Zone

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  • 4-Nitrotoluene

  • Casno:

    99-99-0

    4-Nitrotoluene

    Min.Order: 0

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    in store Package:100g Application:Organic Chemicals

    We are engaged in the research and development of active pharmaceutical ingredients, the manufacture of pharmaceutical intermediates and the production of a variety of organic fine

  •  HWRK Chem

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-21-51691807

    Address:shanghai

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  • 4-Nitrotoluene

  • Casno:

    99-99-0

    4-Nitrotoluene

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    4-Nitrotoluene Basic information Product Name: 4-Nitrotoluene Synonyms: 1-Methyl-4-mitrobenaene;1-methyl-4-nitro-benzen;4-methyl-1-nitrobenzene;4-nitrobenzene;Benzene,1-methyl-4-nitro-;nci9579;NCI-C60537;

    Henan Sunlake Enterprise Corporation is located in Henan Province , the central plain of China , which enjoys favorable geogeaphical position and convenient transportion. The compa

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    Business Type:Trading Company

    Tel:+86-371- 86259723

    Address:Mingmen International Center, NO.222 Dongming Road,Zhengzhou,Henan,China

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  • Casno:

    99-99-0

    4-Nitrotoluene

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    Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

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    United Kingdom  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+44 (0)2036089360-31

    Address:Chanceryhouse,Chancery Lan

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  • 4-Nitrotoluene

  • Casno:

    99-99-0

    4-Nitrotoluene

    Min.Order: 1 Gram

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    Suzhou Lai Teou Ltd. is located in Suzhou in the Yangtze River Delta region, with convenient transportation, the company start to finish, in order to provide customers with high qu

  • SuZhou LaiTeou

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    Business Type:Trading Company

    Tel:+86-0512-88957371

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    1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

    Chemical Technology Co.,LTD is a professional enterprise which engaged in pharmaceutical intermediates, material intermediates production research and development.Company foc

  • Chemical Technology Co.,LTD

     China (Mainland)  |  Contact Details

    Business Type:Other

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    99-99-0

    p-Nitrotoluene

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    Business Type:Other

    Tel:+86-755-2324.2554

    Address:A3-#9, YongChuan Street, Suite 501

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    99-99-0

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    Share Chemical Co., Ltd. is an innovative chemical producer engaged in the production of organic specialty chemicals, pharmaceuticals, and fine chemicals of high purity for product

  • Hangzhou Share Chemical Co., Ltd

    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-57187093700

    Address:Hang Xing Road

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  • Casno:

    99-99-0

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    Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

    Bide Pharmatech Ltd., founded in 2007, focuses on the field of organic chemistry by providing organic reagents, functional materials, biochemical reagents and bulk drug intermediat

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:021-61629020

    Address:Room 3501, 1077 Zuchongzhi Road, Zhangjiang Hi-Tech Park, Pudong New Area, Shanghai 201203, China

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  • 4-Nitrotoluene

  • Casno:

    99-99-0

    4-Nitrotoluene

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

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    Kunshan Yalong Trading Co.,Ltd is one of the key trading enterprises engaged in fine chemical more than 10 years. With good-quality products, reasonable price, flexible terms of p

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-512-57621185

    Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu,China

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    99-99-0

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    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

  • Nanjing Raymon Biotech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-025-52181296

    Address:Block B, No. 918, Shuanglong Avenue

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  • Casno:

    99-99-0

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    Min.Order: 0

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    Do best quality products, erect the morality model Application:please email us, thanks

    Wuxi Morality Chemical Co., Ltd is specialized in the development and manufacture of industrial additives, bulk chemical intermediates, pharmaceutical raw materials and pesticide

  • Wuxi Morality Chemical Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-510-83597286 17768505220

    Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China

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    99-99-0

    4-Nitrotoluene

    Min.Order: 0

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    Angene supplies the compounds with the most competitive price and the best quality; specializes in custom synthesis & building blocks. Welcome the enquiries & orders around the world. Application:chemical research

    Angene is pledged to providing quality chemicals for use in research and development and commercial manufacturing. Angenes offers over 100,000 products including lab reagents, inte

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    United Kingdom  |  Contact Details

    Business Type:Trading Company

    Tel:+852 8191 6999

    Address:CHURCHILL HOUSE 142-146 OLD STREET

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    99-99-0

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    Antaeus-biotech with Established in July 5871 is a high-technical enterprise which focus on the development of health products. We have excellent professionals, first-class facilities and perfect management system. Through persistent efforts, we cont

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    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:021-31252569

    Address:shanghai pudong

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  • 1-Methyl-4-nitrobenzene

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    99-99-0

    1-Methyl-4-nitrobenzene

    Min.Order: 0

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    Cool Pharm, a High and New Technology company,is a supplier of fine chemicals, building blocks and pharmaceutical intermediates which located in Ch

  • coolpharm Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86 (21) 60455363

    Address:Shanghai China

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  • Casno:

    99-99-0

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    1.We are specializing in providing customers with complete chemical raw materials.2.Superior quality, moderate price & quick delivery.3. Extensive international cooperation experience.4. Outstanding communication skills. Application:contact us for de

    Langchem is a research and development company specializing in custom synthesis of organic compounds and projects. Our credo is to provide products and services of the highest qual

  • Langchem

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86+21-58956006

    Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai

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  • Casno:

    99-99-0

    4-nitrotoluene

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    CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

    CFTC PharmaChem is a service based company in China, a pharmachem division of Changzhou Foreign Trade Corp.,supplying raw materials, intermediates, APIs and fine chemicals for the

  • Changzhou Foreign Trade Corp

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-519-86623222

    Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China

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  • Casno:

    99-99-0

    Benzene,1-methyl-4-nitro-

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    YUYONGMEI was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well-equipped synthetic laboratory a

    YUYONGMEI was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’

  • yuyongmei

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:.+86-571-12345678

    Address:sichuan

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  • Casno:

    99-99-0

    Benzene,1-methyl-4-nitro-

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    Benzene,1-methyl-4-nitro-Appearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect t

  • Chemical Co.Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

       Inquiry Now

  • 4-nitrotoluene

  • Casno:

    99-99-0

    4-nitrotoluene

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    high purity Application:Drug intermediates Materials intermediates and active molecules

    Novachemistry offers a broad range of specialty chemicals and customized synthesis services to a range of pharmaceutical, agrochemical and biochemical industries. Novachemistry has

  • NovaChemistry

    United Kingdom  |  Contact Details

    Business Type:Trading Company

    Tel:+44 (0)208 191 7890

    Address:Unit11, Ark Business Centre, Gorden Road, Loughborough, United Kingdom

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 2 ppm (skin)
ACGIH TLV: TWA 2 ppm (skin)
DFG MAK: 5 ppm (28 mg/m3)
DOT Classification:  6.1; Label: Poison

Analytical Methods

For occupational chemical analysis use NIOSH: Nitrobenzenes 2005.

Specification

The p-Nitrotoluene with CAS registry number of 99-99-0 is also known as 4-Nnitrophenylmethane. The IUPAC name is 1-Methyl-4-nitrobenzene. It belongs to product categories of 4-Methylnitrobenzene; Organics; Analytical Chemistry; Environmental Endocrine Disruptors; Estradiol, etc. (Environmental Endocrine Disruptors); Solid WasteMethod Specific; 2000/60/ECMore...Close...; 8000 Series Solidwaste Methods; Analytical Standards; AromaticsEnvironmental Standards; Chemical Class; Environmental Standards; European Community: ISO and DIN; ExplosivesEPA;Method 8330Alphabetic; N; NA - NIAnalytical Standards; Nitro CompoundsChromatography; Volatiles/ Semivolatiles. Its EINECS registry number is 202-808-0. In addition, the formula is C7H7NO2 and the molecular weight is 137.14. This chemical is light yellow crystal and should be stored in sealed containers in cool and dry place away from oxidizers, acids and so on.

Physical properties about p-Nitrotoluene are: (1)ACD/LogP: 2.41; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.41; (4)ACD/LogD (pH 7.4): 2.41; (5)ACD/BCF (pH 5.5): 39.85; (6)ACD/BCF (pH 7.4): 39.85; (7)ACD/KOC (pH 5.5): 486.59; (8)ACD/KOC (pH 7.4): 486.59; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Index of Refraction: 1.553; (13)Molar Refractivity: 37.62 cm3; (14)Molar Volume: 117.5 cm3; (15)Surface Tension: 42.6 dyne/cm; (16)Density: 1.166 g/cm3; (17)Flash Point: 106.1 °C; (18)Enthalpy of Vaporization: 45.56 kJ/mol; (19)Boiling Point: 238 °C at 760 mmHg; (20)Vapour Pressure: 0.0669 mmHg at 25 °C.

Preparation of p-Nitrotoluene: it is prepared by reaction of toluene with mixed acid (nitric acid 25% to 30%, 55% to 58% sulfuric acid and water 20% to 21%). Nitrobenzene is separated, washed, caustic washed. At last, the crude nitrotoluene is vacuum distillated and the product is obtained by vacuum distillation, cooling and crystallization.

C6H5CH3+HNO3→C7H7NO2+H2O

Uses of p-Nitrotoluene: it is used in manufacture of aniline, toluene diisocyanate, and also used as pesticide, dye, pharmaceutical, plastics additive and synthetic intermediate. Besides, it is used to prepare 2-chloro-4-nitro-toluene. The reaction needs reagents Cl2O, H2SO4 and solvent CCl4. The yield is about 99%.

p-Nitrotoluene is used to prepare 2-chloro-4-nitro-toluene.

When you are using this chemical, please be cautious about it. As a chemical, it is irritating to eyes, respiratory system and skin. Besides, it is toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment and it is highly flammable. During using it, wear suitable gloves and avoid release to the environment. Keep away from sources of ignition. After using it, take off immediately all contaminated clothing. In case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
1. SMILES: O=[N+]([O-])c1ccc(C)cc1
2. InChI: InChI=1/C7H7NO2/c1-6-2-4-7(5-3-6)8(9)10/h2-5H,1H3
3. InChIKey: ZPTVNYMJQHSSEA-UHFFFAOYAU

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 419mg/m3 (419mg/m3) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

LIVER: FATTY LIVER DEGERATION

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 22(7), Pg. 52, 1978.
mouse LD50 oral 1231mg/kg (1231mg/kg)   National Technical Information Service. Vol. PB214-270,
rabbit LD50 oral 1750mg/kg (1750mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN

LIVER: FATTY LIVER DEGERATION
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 22(7), Pg. 52, 1978.
rat LC50 inhalation 975mg/m3 (975mg/m3) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

LIVER: FATTY LIVER DEGERATION

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 22(7), Pg. 52, 1978.
rat LD50 intraperitoneal 940mg/kg (940mg/kg) BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 24(9), Pg. 15, 1959.
rat LD50 oral 1960mg/kg (1960mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(8), Pg. 50, 1981.
rat LD50 skin > 16gm/kg (16000mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: FATTY LIVER DEGERATION
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 24(9), Pg. 15, 1959.