Products Categories
CAS No.: | 99059-63-9 |
---|---|
Name: | 1-(4-Iodophenyl)-2-methylpropan-1-one |
Article Data: | 9 |
Molecular Structure: | |
Formula: | C10H11IO |
Molecular Weight: | 274.101 |
Synonyms: | 1-(4-Iodophenyl)-2-methylpropan-1-one;1-(4-iodophenyl)-2-methyl-1-propanone |
PSA: | 17.07000 |
LogP: | 3.12990 |
Isobutyronitrile
1-(4-iodophenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; palladium(II) trifluoroacetate; water; trifluoroacetic acid In tetrahydrofuran at 80℃; for 36h; Inert atmosphere; Schlenk technique; | 84% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium hydroxide In toluene at 70℃; for 24h; | 79% |
Conditions | Yield |
---|---|
With bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]; bis[2-(diphenylphosphino)phenyl] ether; lithium tert-butoxide at 110℃; for 24h; Inert atmosphere; regioselective reaction; | 72% |
1-(4-iodophenyl)propan-1-one
methyl iodide
1-(4-iodophenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
With sodium amide |
isopropylmagnesium chloride
4-iodobenzoic acid chloride
1-(4-iodophenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
iron(III)-acetylacetonate In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; | |
iron(III)-acetylacetonate In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; | |
iron(III)-acetylacetonate In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; | |
With iron(III)-acetylacetonate In tetrahydrofuran at 20℃; |
Conditions | Yield |
---|---|
With aluminum (III) chloride at 45℃; for 15h; Friedel-Crafts Acylation; |
1-(4-iodophenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
With bis(acetylacetonate)nickel(II) In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique; | 85% |
1-(4-iodophenyl)-2-methyl-1-propanone
p-methoxybenzyl chloride
1-[4-(4-methoxybenzyl)phenyl]-2-methylpropan-1-one
Conditions | Yield |
---|---|
Stage #1: p-methoxybenzyl chloride With indium; chloro-trimethyl-silane; ethylene dibromide; lithium chloride In tetrahydrofuran at 40℃; for 15h; Inert atmosphere; Stage #2: With TurboGrignard In tetrahydrofuran at -60 - -50℃; Inert atmosphere; Stage #3: 1-(4-iodophenyl)-2-methyl-1-propanone With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In tetrahydrofuran; ethanol at 40℃; for 16h; Inert atmosphere; chemoselective reaction; | 82% |
1-(4-iodophenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
With bis(acetylacetonate)nickel(II) In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique; | 80% |
3-iodobenzoic acid methyl ester
1-(4-iodophenyl)-2-methyl-1-propanone
ethyl 4'-isobutyrylbiphenyl-3-carboxylate
Conditions | Yield |
---|---|
Stage #1: 3-iodobenzoic acid methyl ester With chloro-trimethyl-silane; aluminium; lithium chloride; lead(II) chloride In tetrahydrofuran at 25 - 30℃; Inert atmosphere; Stage #2: With zinc diacetate In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Stage #3: 1-(4-iodophenyl)-2-methyl-1-propanone With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl) palladium(II) dichloride In tetrahydrofuran at 25 - 30℃; Inert atmosphere; chemoselective reaction; | 78% |