100696-90-0Relevant articles and documents
Indium(I) bromide-promoted stereoselective preparation of (E)-α,β-unsaturated ketones via sequential intermolecular aldol-type coupling/elimination reactions of α,α-dichloroketones with aldehydes
Peppe, Clovis,das Chagas, Rafael Pav?o
, p. 5868 - 5872 (2007/10/03)
Indium(I) bromide promotes the reaction of α,α-dichloroketones with aldehydes to produce (E)-α,β-unsaturated ketones, exclusively. The transformation occurs via two sequential reactions, an aldol-type coupling between the two carbonylic reagents followed by an elimination process.