104182-98-1Relevant articles and documents
Palladium-Catalyzed Distal C?H Selenylation of 2-Aryl Acetamides with Diselenides and Selenyl Chlorides
Gu, Linghui,He, Meicui,Ma, Wenbo,Tan, Yuqiang,Wang, Yang,Wang, Yuchi,Zhang, Chunran
supporting information, p. 5708 - 5715 (2020/12/01)
A convenient and effective method of palladium-catalyzed C?H selenylation of the 2-aryl acetamides assisted with removable 8-aminoquinoline with readily available diselenides and selenyl chlorides has been developed. This selenylation reaction is scalable and tolerates a wide range of functional groups, providing a straightforward way of the preparing unsymmetrical diaryl selenides and dibenzoselene-pinone. Preliminary mechanistic studies indicated that a single-electron transfer type mechanism and facile C?H metalation are operative. (Figure presented.).
Distal Weak Coordination of Acetamides in Ruthenium(II)-Catalyzed C?H Activation Processes
Bu, Qingqing,Rogge, Torben,Kotek, Vladislav,Ackermann, Lutz
supporting information, p. 765 - 768 (2018/01/17)
C?H activations with challenging arylacetamides were accomplished by versatile ruthenium(II) biscarboxylate catalysis. The distal C?H functionalization offers ample scope—including twofold oxidative C?H functionalizations and alkyne hydroarylations—throug
ETUDE STRUCTURALE DE DERIVES DU PHENYL-ETHANE
Lere-Porte, J. P.,Bonniol, A.,Petrissans, J.
, p. 77 - 88 (2007/10/02)
Analysis of the methylene bending modes of phenyl ethane derivatives is consistent with the existence of trans-gauche conformational equilibria in the dissolved state.The relative amounts of each conformer have been determined and agree well with previous
