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10450-60-9

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10450-60-9 Usage

General Description

Periodic(VII) acid, also known as Perjodic acid, is a strong and unstable oxidizing agent with the formula H5IO6. It can be prepared by the reaction of iodine pentoxide with water, and it is one of the most powerful oxides of iodine. Periodic(VII) acid is a colorless, hygroscopic solid with strong oxidizing properties. It is commonly used as a reagent for the oxidation of various organic compounds and as a precursor to other iodine compounds. However, due to its instability, it must be handled with extreme caution, as it can decompose explosively under certain conditions.

Check Digit Verification of cas no

The CAS Registry Mumber 10450-60-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,5 and 0 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 10450-60:
(7*1)+(6*0)+(5*4)+(4*5)+(3*0)+(2*6)+(1*0)=59
59 % 10 = 9
So 10450-60-9 is a valid CAS Registry Number.
InChI:InChI:1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)

10450-60-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (B20172)  Periodic acid, 34% w/w aq. soln.   

  • 10450-60-9

  • 100g

  • 372.0CNY

  • Detail
  • Alfa Aesar

  • (B20172)  Periodic acid, 34% w/w aq. soln.   

  • 10450-60-9

  • 500g

  • 1387.0CNY

  • Detail
  • Alfa Aesar

  • (B20172)  Periodic acid, 34% w/w aq. soln.   

  • 10450-60-9

  • 2500g

  • 5771.0CNY

  • Detail
  • Alfa Aesar

  • (B20433)  Periodic acid, 99%   

  • 10450-60-9

  • 50g

  • 431.0CNY

  • Detail
  • Alfa Aesar

  • (B20433)  Periodic acid, 99%   

  • 10450-60-9

  • 250g

  • 1349.0CNY

  • Detail
  • Alfa Aesar

  • (B20433)  Periodic acid, 99%   

  • 10450-60-9

  • 1000g

  • 4608.0CNY

  • Detail
  • Alfa Aesar

  • (30472)  Periodic acid, ACS, 99.0-101.0%   

  • 10450-60-9

  • 50g

  • 1096.0CNY

  • Detail
  • Sigma-Aldrich

  • (77310)  Periodicacid  puriss. p.a., ACS reagent, for oxidimetric titration, crystallized, ≥99.0% (RT)

  • 10450-60-9

  • 77310-25G

  • 893.88CNY

  • Detail
  • Sigma-Aldrich

  • (77310)  Periodicacid  puriss. p.a., ACS reagent, for oxidimetric titration, crystallized, ≥99.0% (RT)

  • 10450-60-9

  • 77310-100G

  • 4,520.88CNY

  • Detail
  • Sigma-Aldrich

  • (375810)  Periodicacid  ACS reagent, 99%

  • 10450-60-9

  • 375810-25G

  • 1,037.79CNY

  • Detail
  • Sigma-Aldrich

  • (375810)  Periodicacid  ACS reagent, 99%

  • 10450-60-9

  • 375810-100G

  • 2,827.89CNY

  • Detail
  • Sigma-Aldrich

  • (P7875)  Periodicacid  ReagentPlus®, ≥99.0%

  • 10450-60-9

  • P7875-25G

  • 669.24CNY

  • Detail

10450-60-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name orthoperiodic acid

1.2 Other means of identification

Product number -
Other names PENTAHYDROXY-L5-IODANE OXIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10450-60-9 SDS

10450-60-9Synthetic route

iodic acid
7782-68-5

iodic acid

periodic acid
10450-60-9

periodic acid

Conditions
ConditionsYield
In water Electrolysis; special apparatus with Pt wire net covered with PbO2 as anode and current intensity of 12 - 15A; 24h;; evapn. of anode soln. in vac. at 40 - 60°C not to dryness, addn. of some HNO3, further evapn.; crystn.; decantation of mother lye; dissolving H5IO6 in hot concd. HNO3 soln., filtration, recrystn., heating in desiccator over KOH to 40°C;;98%
In water Electrolysis; special apparatus with Pt wire net covered with PbO2 as anode and current intensity of 12 - 15A; 24h;; evapn. of anode soln. in purified air stream at 70 - 85°C; loss by partial formation of HIO3;;
In sulfuric acid Electrolysis; 50% HIO3 soln.; anode region: clay cell with MnO2 anode; cathode region: filled with 2n H2SO4 soln., Pt cathode; current yield: 0.39%;;
calcium dimesoperiodate

calcium dimesoperiodate

ammonia
7664-41-7

ammonia

A

8CaO*3I2O7

8CaO*3I2O7

B

periodic acid
10450-60-9

periodic acid

Conditions
ConditionsYield
In ammonia pptn. of a solution of Ca2I2O9 with aq. NH3-solution under formation of product and H5IO6;;
In ammonia aq. ammonia=NH3; pptn. of a solution of Ca2I2O9 with aq. NH3-solution under formation of product and H5IO6;;
sodium periodate
7790-28-5

sodium periodate

A

periodic acid
10450-60-9

periodic acid

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
With water
With H2O
bariumparaperiodate

bariumparaperiodate

nitric acid
7697-37-2

nitric acid

A

barium(II) nitrate

barium(II) nitrate

B

periodic acid
10450-60-9

periodic acid

Conditions
ConditionsYield
In nitric acid reaction of concd. HNO3 with Ba3H4(IO6)2 forms H5IO6 and Ba(NO3)2;;
In nitric acid aq. HNO3; reaction of concd. HNO3 with Ba3H4(IO6)2 forms H5IO6 and Ba(NO3)2;;
Cs(1+)*H4IO6(1-)*H5IO6=CsH4IO6*H5IO6

Cs(1+)*H4IO6(1-)*H5IO6=CsH4IO6*H5IO6

A

cesium periodate
13478-04-1

cesium periodate

B

periodic acid
10450-60-9

periodic acid

Conditions
ConditionsYield
In neat (no solvent) at room temp. in vac.;
Cs(1+)*H4IO6(1-)*H5IO6*0.5H2O=CsH4IO6*H5IO6*0.5H2O

Cs(1+)*H4IO6(1-)*H5IO6*0.5H2O=CsH4IO6*H5IO6*0.5H2O

A

cesium periodate
13478-04-1

cesium periodate

B

periodic acid
10450-60-9

periodic acid

Conditions
ConditionsYield
In neat (no solvent) at room temp. in vac.;
chromium(III) nitrate nonahydrate

chromium(III) nitrate nonahydrate

thorium(IV) nitrate hydrate

thorium(IV) nitrate hydrate

periodic acid
10450-60-9

periodic acid

Th(4+)*2IO3(1-)*CrO4(2-)=Th(IO3)2(CrO4)

Th(4+)*2IO3(1-)*CrO4(2-)=Th(IO3)2(CrO4)

Conditions
ConditionsYield
In water High Pressure; loading of Th(NO3)4*nH2O (0.435 mmol), H5IO6 (0.451 mmol), Cr(NO3)3*9H2O(0.451 mmol) and water in PTFE-lined autoclave; sealing, placing in pre heated furnace for 3 d at 2o0°C; cooling at 9°C/h to 23°C; crystn., washing with MeOH and drying;99%
erbium

erbium

periodic acid
10450-60-9

periodic acid

erbium(III) iodate

erbium(III) iodate

Conditions
ConditionsYield
In water High Pressure; Er and H5IO6 mixed with H2O, placed in vessel, heated at 180°C for 70 h, cooled to 20°C;99%
gadolinium

gadolinium

periodic acid
10450-60-9

periodic acid

gadolinium(III) iodate

gadolinium(III) iodate

Conditions
ConditionsYield
In water High Pressure; Gd and H5IO6 mixed with H2O, placed in vessel, heated at 180°C for 70 h, cooled to 20°C;99%
Tl(3+)*3ClO4(1-)*6H2O=Tl(ClO4)3*6H2O

Tl(3+)*3ClO4(1-)*6H2O=Tl(ClO4)3*6H2O

periodic acid
10450-60-9

periodic acid

thallium(III) periodate

thallium(III) periodate

Conditions
ConditionsYield
In perchloric acid mixed, stirred (30 min); filtered, washed (dilute HClO4, H2O), dried (40°C in air); elem.anal.;98%
potassium fluoride

potassium fluoride

hydrogen fluoride
7664-39-3

hydrogen fluoride

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

periodic acid
10450-60-9

periodic acid

KBi2(IO3)2F5

KBi2(IO3)2F5

Conditions
ConditionsYield
In water at 210℃; for 96h;97%

10450-60-9Relevant articles and documents

Complexing between orthoperiodic acid and periodate ion in nitric acid solutions

Nikitina,Nikitina

, p. 1694 - 1696 (2007)

Preparative synthesis techniques have been developed for four complex salts (Rb[H4IO6 ? H5IO6], Cs[H 4IO6 ? H5IO6], Cs[H 4IO6 ? H5IOs

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