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10488-95-6

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10488-95-6 Usage

General Description

Ethyl 3-oxooctanoate is a chemical compound with the molecular formula C10H18O3. It is a colorless liquid with a fruity, pineapple-like odor. Ethyl 3-oxooctanoate is commonly used as a flavoring agent in food products, particularly in the production of pineapple and other fruit-flavored beverages and confectionery. It is also used in the fragrance industry as a component in perfumes and body care products. Additionally, ethyl 3-oxooctanoate is utilized as an intermediate in the synthesis of various pharmaceuticals and agrochemicals. Overall, it is a versatile compound with widespread applications in food, fragrance, and pharmaceutical industries.

Check Digit Verification of cas no

The CAS Registry Mumber 10488-95-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,8 and 8 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 10488-95:
(7*1)+(6*0)+(5*4)+(4*8)+(3*8)+(2*9)+(1*5)=106
106 % 10 = 6
So 10488-95-6 is a valid CAS Registry Number.

10488-95-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl 3-oxooctanoate

1.2 Other means of identification

Product number -
Other names ethyl 2-butyl-acetoacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10488-95-6 SDS

10488-95-6Relevant articles and documents

Synthesis of coumarins by Pt-catalyzed hydroarylation of propiolic acids with phenols

Oyamada, Juzo,Kitamura, Tsugio

, p. 6918 - 6925 (2006)

Synthesis of coumarins from phenols and propiolic acids was examined by using a Pt catalyst such as PtCl2/AgOTf, K2PtCl4/AgOTf, and K2PtCl4/AgOAc. Propiolic acid reacted even with less reactive phenols in trifluoroacetic acid to give coumarins and dihydrocoumarins. In the case of substituted propiolic acids, phenylpropiolic acid and 2-octynoic acid, the reactions proceeded selectively to afford coumarins in good to high yields.

One-pot synthesis of β-keto esters and preparation of 3-ketopalmitoyl-CoA

Ko?ak, Urban,Kova?, Andreja,Gobec, Stanislav

, p. 1609 - 1612 (2012)

β-Keto esters were synthesized from acyl chlorides and sodium ethyl acetoacetate in EtOH using a simple one-pot, one-step' method. The deacetylation of α-acetyl β-keto ester to β-keto ester was performed simply, by heating the reaction mixture at reflux for 12 hours, without the addition of additional reagents (e.g., NHl, NH MeOH, or NaOH). One of the β-keto esters prepared using this method was ethyl 3-oxohexadecanoate, a key intermediate in the synthesis of 3-ketopalmitoyl coenzyme A (3-oxohexadecanoyl coenzyme A), a potential substrate of the biologically important enzyme 17β-hydroxysteroid dehydrogenase type 12. Georg Thieme Verlag Stuttgart ? New York.

Simple synthesis of enantiomers of 6-hydroxyalkan-4-olides by stereoselective hydrogenation of methyl 4,6-dioxoalkanoates

Schulz, Stefan

, p. 1239 - 1240 (1999)

A simple method for the synthesis of (S,S)- or (R,R)-6-hydroxyalkan-4-olides, components of the pheromonal secretion of the butterfly Idea leuconoe, in high ee by enantioselective hydrogenation of 4,6-diketo esters with a commercial available Ru-BINAP catalyst is described.

Efficient Synthesis of Functionalized β-Keto Esters and β-Diketones through Regioselective Hydration of Alkynyl Esters and Alkynyl Ketones by Use of a Cationic NHC–AuICatalyst

Tarigopula, Chandrahas,Thota, Ganesh Kumar,Balamurugan, Rengarajan

, p. 5855 - 5861 (2016)

Regioselective hydration of α-alkynyl esters and ketones by using a cationic NHC–AuIcatalyst results in β-keto esters and β-diketones, respectively. Controlled release of water in acetone by aldol self-condensation under the reaction conditions makes acetone as better solvent than 1,4-dioxane/water for the hydration of α-alkynyl esters having sensitive ester moieties.

A novel convenient route to the naturally occurring 3-oxoacyl-L-homoserinelactones and related bacterial autoinducers

Dekhane, Mouloud,Douglas, Kenneth T.,Gilbert, Peter

, p. 1883 - 1884 (1996)

The naturally occurring 3-oxohexanoyl-L-homoserinelactone (1a), a bacterial autoinducer has been prepared in 47% overall yield by condensing stable 3-oxohexanoic acid (2), prepared by hydrolysis from the corresponding ester (3), with L-homoserinelactone using hydroxybenzotriazole (HOBT) and dicyclohexylcarbodiimide (DCC) in non-aqueous media.

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Rathke,Deitch

, p. 2953,2955 (1971)

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Non-metal Lewis acid-catalyzed cross-Claisen condensation for β-keto esters

Han, Zhengyu,Huang, Hai,Meng, Fuliang,Yang, Zhenkun,Zhang, Tianyu,Zhou, Dapeng

supporting information, p. 9163 - 9166 (2021/11/16)

In this work, we disclose a new catalytic and highly chemoselective cross-Claisen condensation of esters. In the presence of TBSNTf2 as a non-metal Lewis acid, various esters can undergo cross-Claisen condensation to form β-keto esters which are important building blocks. Compared with the traditional Claisen condensation, this process, employing silyl ketene acetals (SKAs) as carbonic nucleophiles to achieve cross-Claisen condensation, requires mild conditions and has good tolerance of functional groups. This journal is

Pyrazole alcohol compound, pharmaceutical composition thereof and application thereof to drugs

-

Paragraph 0128; 0130, (2018/10/19)

The invention discloses a 1-(3,5,6-trimethyl pyrazine-2-yl)-5-pyrazole alcohol compound, a tautomer thereof, a pharmaceutical composition thereof and application thereof to drugs. The 1-(3,5,6-trimethyl pyrazine-2-yl)-5-pyrazole alcohol compound has double effects of resisting platelet aggregation and protecting nerve cells, and comprises a compound as shown in the formula (I), a tautomer (Ia) thereof, or a stereoisomer, a geometrical isomer, a hydrate or a solvate thereof, or a pharmaceutically acceptable salt or prodrug as shown in the description. The 1-(3,5,6-trimethyl pyrazine-2-yl)-5-pyrazole alcohol compound and the pharmaceutical composition thereof provided by the invention can be used for preparing drugs for prevention and/or treatment and/or auxiliary treatment of cerebral apoplexy, cardiovascular and cerebrovascular diseases, senile dementia and complications thereof caused by thrombosis and excessive free radicals.

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