10570-48-6Relevant articles and documents
Kluger,Chin
, p. 7382,7383-7385 (1978)
Phosphorus compounds as photoinitiators for radicalic polymerization
Macarie, Lavinia,Ilia,Iliescu, Smaranda,Popa, Adriana,Dehelean,Manoviciu,Petrean,Abadie
, p. 165/[421]-173/[429] (2004)
p-Methoxybenzoyldialkylphosphonates, where alkyl = methyl, ethyl and p-methoxy-benzoyldiphenylphosphine oxide were synthesized by Michaelis-Arbuzov reaction. These compounds were used as photoinitiators for radicalic polymerization of acrylic monomers. Th
Selective P?C(sp3) Bond Cleavage and Radical Alkynylation of α-Phosphorus Alcohols by Photoredox Catalysis
Jia, Kunfang,Li, Junzhao,Chen, Yiyun
supporting information, p. 3174 - 3177 (2018/02/09)
Herein the first P?C(sp3) bond cleavage and radical alkynylation of α-phosphorus alcohols to construct phosphonoalkynes is reported. The phosphorus radical is generated upon P?C bond cleavage reaction via the alkoxyl radical through photoredox catalysis with cyclic iodine(III) reagents. Various arylphosphinoyl-, alkylphosphinoyl-, phosphonate-, and phosphonic amide alcohols serve as radical phosphorus precursors to construct phosphonoalkynes for the first time.
Reactions of acyl phosphonates with organoaluminum reagents: A new method for the synthesis of secondary and tertiary α-hydroxy phosphonates
Seven, Ozlem,Polat-Cakir, Sidika,Hossain, Md. Shakhawoat,Emrullahoglu, Mustafa,Demir, Ayhan S.
body text, p. 3464 - 3469 (2011/06/19)
The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and alkyl acyl phosphonates, which lead to the formation of α-hydroxy phosphonates in moderate to good yields, are reported. This method provides easy access to