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107-45-9 Usage

Chemical Properties

CLEAR LIQUID

Check Digit Verification of cas no

The CAS Registry Mumber 107-45-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 7 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 107-45:
(5*1)+(4*0)+(3*7)+(2*4)+(1*5)=39
39 % 10 = 9
So 107-45-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H19N/c1-7(2,3)6-8(4,5)9/h6,9H2,1-5H3/p+1

107-45-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-Octylamine

1.2 Other means of identification

Product number -
Other names Tert-Octylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Functional fluids (open systems)
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:107-45-9 SDS

107-45-9Synthetic route

3-Methyl-3-tert-octylamino-1-butyne
263254-99-5

3-Methyl-3-tert-octylamino-1-butyne

A

tert-Octylamine
107-45-9

tert-Octylamine

B

tert-Octyl-tert-pentylamine
263255-00-1

tert-Octyl-tert-pentylamine

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In various solvent(s) under 2947.74 Torr; Hydrogenolysis; Catalytic hydrogenation;A 60%
B 35%
2,2,4-trimethyl-4-nitro-pentane
5342-78-9

2,2,4-trimethyl-4-nitro-pentane

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With nickel Hydrogenation;
With hydrogenchloride; tin
2-chloro-2,4,4-trimethylpentane
6111-88-2

2-chloro-2,4,4-trimethylpentane

silver cyanate
3315-16-0

silver cyanate

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
Kochen des Reaktionsprodukts mit 40prozentig.KOH;
2-chloro-2,4,4-trimethylpentane
6111-88-2

2-chloro-2,4,4-trimethylpentane

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With diethyl ether; magnesium anschliessend mit Chloramin;
N-(2,4,4-trimethylpentan-2-yl)formamide
10151-02-7

N-(2,4,4-trimethylpentan-2-yl)formamide

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With sodium hydroxide
2,2,4,4-tetramethylpentanoic acid
3302-12-3

2,2,4,4-tetramethylpentanoic acid

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With thionyl chloride Umsetzung des erhaltenen Saeurechlorids mit NaN3 in siedendem Toluol und anschliessendes Kochen mit 40prozentig.KOH;
N-1,1'3,3'-tetramethylbutylacetamide
5459-42-7

N-1,1'3,3'-tetramethylbutylacetamide

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With potassium hydroxide; ethylene glycol
2,4,4-trimethyl-1-pentene
107-39-1

2,4,4-trimethyl-1-pentene

cyanogen chloride
506-77-4

cyanogen chloride

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
With sulfuric acid anschliessend mit Wasser;
2-chloro-2,4,4-trimethylpentane
6111-88-2

2-chloro-2,4,4-trimethylpentane

A

tert-Octylamine
107-45-9

tert-Octylamine

B

tert-butylamine
75-64-9

tert-butylamine

Conditions
ConditionsYield
With aluminium trichloride; nitrogen trichloride In dichloromethane
2,4,4-trimethyl-1-pentene
107-39-1

2,4,4-trimethyl-1-pentene

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated H2SO4; glacial acetic acid
2: KOH; ethylene glycol
View Scheme
Multi-step reaction with 2 steps
1: concentrated H2SO4; glacial acetic acid
2: aq. NaOH solution
View Scheme
Multi-step reaction with 2 steps
1: hydrogen chloride / unter Kuehlung mit Eis
2: Kochen des Reaktionsprodukts mit 40prozentig.KOH
View Scheme
Multi-step reaction with 2 steps
2: NCl3, AlCl3 / CH2Cl2
View Scheme
1,1,3,3-tetramethylbutane isonitrile
14542-93-9

1,1,3,3-tetramethylbutane isonitrile

tert-Octylamine
107-45-9

tert-Octylamine

Conditions
ConditionsYield
Stage #1: 1,1,3,3-tetramethylbutane isonitrile In methanol; dichloromethane at 20℃;
Stage #2: With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 2h;
tert-Octylamine
107-45-9

tert-Octylamine

propionaldehyde
123-38-6

propionaldehyde

2,4,4-trimethyl-N-propylidene-2-pentanamine

2,4,4-trimethyl-N-propylidene-2-pentanamine

Conditions
ConditionsYield
With sodium sulfate In dichloromethane at 10 - 20℃;100%
7-phenylacetamido-3-(4-methylthiazol-5-yl)vinyl-3-cephem-4-carboxylic acid
823792-22-9

7-phenylacetamido-3-(4-methylthiazol-5-yl)vinyl-3-cephem-4-carboxylic acid

C21H19N3O4S2

C21H19N3O4S2

tert-Octylamine
107-45-9

tert-Octylamine

A

C8H19N*C21H19N3O4S2

C8H19N*C21H19N3O4S2

B

C8H19N*C21H19N3O4S2

C8H19N*C21H19N3O4S2

Conditions
ConditionsYield
In water; acetone at 5℃; for 3h;A 99.3%
B n/a
1,1,1-trichloroethanol
115-20-8

1,1,1-trichloroethanol

tert-Octylamine
107-45-9

tert-Octylamine

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

(1,1,3,3-Tetramethyl-butyl)-carbamic acid 2,2,2-trichloro-ethyl ester

(1,1,3,3-Tetramethyl-butyl)-carbamic acid 2,2,2-trichloro-ethyl ester

Conditions
ConditionsYield
With dmap In acetonitrile at 82℃; for 34h;99%
3-Chloropyridine
626-60-8

3-Chloropyridine

tert-Octylamine
107-45-9

tert-Octylamine

N-(2,4,4-trimethylpentan-2-yl)pyridin-3-amine

N-(2,4,4-trimethylpentan-2-yl)pyridin-3-amine

Conditions
ConditionsYield
With chloro(η3-2-cinnam-1-yl)(1,3-(diisopropylphenyl)-4-(diisopropylamino)imidazol-2-ylidene)palladium(II); potassium tert-butylate In 1,2-dimethoxyethane at 60℃; for 4h; Buchwald-Hartwig Coupling; Schlenk technique; Glovebox; Sealed tube; Inert atmosphere;99%
With C26H33N2P; C39H46N3O3PPdS; sodium t-butanolate In 1,4-dioxane at 100℃; for 24h; Inert atmosphere;73%
pentanal
110-62-3

pentanal

tert-Octylamine
107-45-9

tert-Octylamine

triphenylacetic acid
595-91-5

triphenylacetic acid

(R)-1-oxo-1-((2,4,4-trimethylpentan-2-yl)amino)hexan-2-yl 2,2,2-triphenylacetate

(R)-1-oxo-1-((2,4,4-trimethylpentan-2-yl)amino)hexan-2-yl 2,2,2-triphenylacetate

Conditions
ConditionsYield
Stage #1: pentanal; triphenylacetic acid With (R)-3,3'-bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate; magnesium sulfate In chloroform at -20℃; for 0.166667h; Passerini Condensation; Schlenk technique; Inert atmosphere;
Stage #2: tert-Octylamine In chloroform at -20℃; for 36h; Passerini Condensation; Inert atmosphere; Schlenk technique; enantioselective reaction;
99%
piperonol
495-76-1

piperonol

tert-Octylamine
107-45-9

tert-Octylamine

(E)-N-(benzo[d][1,3]dioxol-5-ylmethylene)-2,4,4-trimethylpentan-2-amine
1137195-75-5

(E)-N-(benzo[d][1,3]dioxol-5-ylmethylene)-2,4,4-trimethylpentan-2-amine

Conditions
ConditionsYield
With palladium on aluminium oxyhydroxide; oxygen at 90℃; under 760.051 Torr; for 24h;98%
tert-Octylamine
107-45-9

tert-Octylamine

2,4,6-trimethoxybenzaldehyde
830-79-5

2,4,6-trimethoxybenzaldehyde

1-(2,4,6-trimethoxyphenyl)-N-(2,4,4-trimethylpentan-2-yl)methanimine

1-(2,4,6-trimethoxyphenyl)-N-(2,4,4-trimethylpentan-2-yl)methanimine

Conditions
ConditionsYield
In benzene Reflux; Dean-Stark;98%
tert-Octylamine
107-45-9

tert-Octylamine

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

1,1,3,3-tetramethylbutyl isocyanate
1611-57-0

1,1,3,3-tetramethylbutyl isocyanate

Conditions
ConditionsYield
With dmap In dichloromethane at 25℃; for 0.166667h;97%
tert-Octylamine
107-45-9

tert-Octylamine

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

allyl alcohol
107-18-6

allyl alcohol

A

allyl N-1,1,3,3-tetramethylbutylcarbamate
100247-48-1

allyl N-1,1,3,3-tetramethylbutylcarbamate

B

N,N'-bis(1,1,3,3-tetramethylbutyl)urea
2092-58-2

N,N'-bis(1,1,3,3-tetramethylbutyl)urea

Conditions
ConditionsYield
With dmap In acetonitrile at 82℃; for 34h;A 97%
B n/a
tert-Octylamine
107-45-9

tert-Octylamine

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

N-(1,1,3,3-tetramethyl-butyl)-methanesulfonamide
899252-59-6

N-(1,1,3,3-tetramethyl-butyl)-methanesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 1.75h;97%
tert-Octylamine
107-45-9

tert-Octylamine

N-sulfinyl-tert-octylamine

N-sulfinyl-tert-octylamine

Conditions
ConditionsYield
With thionyl chloride; triethylamine In diethyl ether at 0℃; for 2h; Inert atmosphere;97%
With thionyl chloride; Triphenylmethylamin In diethyl ether at 0℃; for 2h; Inert atmosphere;30%
tert-Octylamine
107-45-9

tert-Octylamine

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

benzyl alcohol
100-51-6

benzyl alcohol

A

N,N'-bis(1,1,3,3-tetramethylbutyl)urea
2092-58-2

N,N'-bis(1,1,3,3-tetramethylbutyl)urea

B

(1,1,3,3-Tetramethyl-butyl)-carbamic acid benzyl ester

(1,1,3,3-Tetramethyl-butyl)-carbamic acid benzyl ester

Conditions
ConditionsYield
With dmap In acetonitrile for 17h; Heating;A n/a
B 96%
4-(acetylamino)-5-amino-7-tert-butyl-N,N-diisopropyl-9-oxo-9H-xanthene-2-carboxamide
866431-82-5

4-(acetylamino)-5-amino-7-tert-butyl-N,N-diisopropyl-9-oxo-9H-xanthene-2-carboxamide

phosgene
75-44-5

phosgene

tert-Octylamine
107-45-9

tert-Octylamine

4-(acetylamino)-7-tert-butyl-N,N-diisopropyl-9-oxo-5-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxamide

4-(acetylamino)-7-tert-butyl-N,N-diisopropyl-9-oxo-5-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxamide

Conditions
ConditionsYield
Stage #1: 4-(acetylamino)-5-amino-7-tert-butyl-N,N-diisopropyl-9-oxo-9H-xanthene-2-carboxamide; phosgene In dichloromethane; toluene for 0.333333h; Heating;
Stage #2: tert-Octylamine In toluene
96%
tert-Octylamine
107-45-9

tert-Octylamine

tantalum pentachloride
7721-01-9

tantalum pentachloride

2H3NC(CH3)2CH2C(CH3)3(1+)*Ta(NC(CH3)2CH2C(CH3)3)Cl5(2-)=[H3NC(CH3)2CH2C(CH3)3]2[Ta(NC(CH3)2CH2C(CH3)3)Cl5]

2H3NC(CH3)2CH2C(CH3)3(1+)*Ta(NC(CH3)2CH2C(CH3)3)Cl5(2-)=[H3NC(CH3)2CH2C(CH3)3]2[Ta(NC(CH3)2CH2C(CH3)3)Cl5]

Conditions
ConditionsYield
In diethyl ether; toluene N2-atmosphere; 3 equiv. amine, stirring for 4 h; evapn. (vac.), washing (pentane), drying (vac.);96%
maleic anhydride
108-31-6

maleic anhydride

tert-Octylamine
107-45-9

tert-Octylamine

N-[(1,1,3,3-tetramethyl)butyl]maleamic acid
131365-14-5

N-[(1,1,3,3-tetramethyl)butyl]maleamic acid

Conditions
ConditionsYield
In toluene at 45 - 50℃; for 1h;95%
In toluene at 45 - 50℃; for 2h;
phosgene
75-44-5

phosgene

tert-Octylamine
107-45-9

tert-Octylamine

8-Amino-6-tert-butyl-4-oxo-4H-chromene-2-carboxylic acid butylamide
168705-30-4

8-Amino-6-tert-butyl-4-oxo-4H-chromene-2-carboxylic acid butylamide

6-tert-Butyl-4-oxo-8-[3-(1,1,3,3-tetramethyl-butyl)-ureido]-4H-chromene-2-carboxylic acid butylamide

6-tert-Butyl-4-oxo-8-[3-(1,1,3,3-tetramethyl-butyl)-ureido]-4H-chromene-2-carboxylic acid butylamide

Conditions
ConditionsYield
95%
butyl 4-amino-7-tert-butyl-5-nitro-9-oxo-9H-xanthene-2-carboxylate
866431-85-8

butyl 4-amino-7-tert-butyl-5-nitro-9-oxo-9H-xanthene-2-carboxylate

phosgene
75-44-5

phosgene

tert-Octylamine
107-45-9

tert-Octylamine

butyl 7-tert-butyl-5-nitro-9-oxo-4-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxylate
866431-86-9

butyl 7-tert-butyl-5-nitro-9-oxo-4-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxylate

Conditions
ConditionsYield
Stage #1: butyl 4-amino-7-tert-butyl-5-nitro-9-oxo-9H-xanthene-2-carboxylate; phosgene In dichloromethane; toluene
Stage #2: tert-Octylamine In toluene
95%
tert-Octylamine
107-45-9

tert-Octylamine

dichlorodiethylstannane
866-55-7

dichlorodiethylstannane

1,3-bis(2,4,4-trimethyl-2-pentyl)-2,2,4,4-tetraethyl-1,3,2,4-diazadistannetidine
121043-81-0

1,3-bis(2,4,4-trimethyl-2-pentyl)-2,2,4,4-tetraethyl-1,3,2,4-diazadistannetidine

Conditions
ConditionsYield
With n-butyllithium In hexane exclusion of oxygen and moisture; refluxing (3 h) of tert-octylamine and n-BuLi, cooling (-78°C), addn. of Et2SnCl2, warming to room temp., refluxing (2 h); filtn., volatiles removal (room temp., vac.);95%
tert-Octylamine
107-45-9

tert-Octylamine

benzaldehyde
100-52-7

benzaldehyde

benzyl-(1,1,3,3-tetramethyl-butyl)-amine
3598-75-2

benzyl-(1,1,3,3-tetramethyl-butyl)-amine

Conditions
ConditionsYield
Stage #1: tert-Octylamine; benzaldehyde With titanium(IV) isopropylate In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;
Stage #2: With ammonia borane In tetrahydrofuran at 20℃; for 7h; Inert atmosphere;
95%
Glyoxal
131543-46-9

Glyoxal

tert-Octylamine
107-45-9

tert-Octylamine

N,N'-bis(1,1,3,3-tetramethylbutyl)-1,4-diaza-1,3-butadiene
56376-10-4

N,N'-bis(1,1,3,3-tetramethylbutyl)-1,4-diaza-1,3-butadiene

Conditions
ConditionsYield
In water at 20℃; for 1h;95%
In water at 20℃; for 1h;95%
In water at 20℃; for 1h;95%
tert-Octylamine
107-45-9

tert-Octylamine

3,5-di-t-butyl-4-hydroxybenzaldehyde
1620-98-0

3,5-di-t-butyl-4-hydroxybenzaldehyde

2,6-di-tert-butyl-4-((2,4,4-trimethylpentan-2-ylimino)methyl)phenol
1151854-56-6

2,6-di-tert-butyl-4-((2,4,4-trimethylpentan-2-ylimino)methyl)phenol

Conditions
ConditionsYield
In toluene at 60 - 110℃; for 2h;94.48%
In toluene at 60 - 110℃; Azeotropic removal of water; Inert atmosphere;94.48%
tert-Octylamine
107-45-9

tert-Octylamine

2,2,4-tetramethyl-4-nitrosopentane
31044-98-1

2,2,4-tetramethyl-4-nitrosopentane

Conditions
ConditionsYield
With peracetic acid In water; ethyl acetate at 0℃; for 2h;94%
With sodium tungstate (VI) dihydrate; dihydrogen peroxide; ethylene diamine tetraacetic acid tetrasodium salt In methanol; water at 15℃; for 21h;52%
Multi-step reaction with 3 steps
1: aq. K2CO3 / various solvent(s) / 5 h / 50 °C
2: aq. N2H4 / methanol / 75 h / 20 °C
3: aq. MeOBr / methanol / -78 - -20 °C
View Scheme
4-amino-7-tert-butyl-N,N-diisopropyl-5-nitro-9-oxo-9H-xanthene-2-carboxamide
866431-78-9

4-amino-7-tert-butyl-N,N-diisopropyl-5-nitro-9-oxo-9H-xanthene-2-carboxamide

phosgene
75-44-5

phosgene

tert-Octylamine
107-45-9

tert-Octylamine

7-tert-butyl-N,N-diisopropyl-5-nitro-9-oxo-4-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxamide
866431-79-0

7-tert-butyl-N,N-diisopropyl-5-nitro-9-oxo-4-({[(1,1,3,3-tetramethylbutyl)amino]carbonyl}amino)-9H-xanthene-2-carboxamide

Conditions
ConditionsYield
Stage #1: 4-amino-7-tert-butyl-N,N-diisopropyl-5-nitro-9-oxo-9H-xanthene-2-carboxamide; phosgene In dichloromethane; toluene for 0.333333h; Heating;
Stage #2: tert-Octylamine In toluene at 20℃;
94%
pyridine-2-carbaldehyde
1121-60-4

pyridine-2-carbaldehyde

tert-Octylamine
107-45-9

tert-Octylamine

(E)-2,4,4-trimethyl-N-(pyridin-2-ylmethylene)pentan-2-amine
1392472-53-5

(E)-2,4,4-trimethyl-N-(pyridin-2-ylmethylene)pentan-2-amine

Conditions
ConditionsYield
In dichloromethane for 1.5h; Inert atmosphere; Reflux; Dean-Stark;94%
2-chloropyrazin
14508-49-7

2-chloropyrazin

tert-Octylamine
107-45-9

tert-Octylamine

N-(2,4,4-trimethylpentan-2-yl)pyrazin-2-amine

N-(2,4,4-trimethylpentan-2-yl)pyrazin-2-amine

Conditions
ConditionsYield
With C47H70BrO4PPdSi; sodium t-butanolate In tetrahydrofuran at 20℃; for 1h; Schlenk technique; Inert atmosphere; Sealed tube;94%
With C41H42N3O3PPdS; sodium t-butanolate In 1,4-dioxane at 120℃; for 12h; Inert atmosphere;50%
tert-Octylamine
107-45-9

tert-Octylamine

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxy-N-tert-octylaniline

2-methoxy-N-tert-octylaniline

Conditions
ConditionsYield
With chloro(η3-2-cinnam-1-yl)(1,3-(diisopropylphenyl)-4-(diisopropylamino)imidazol-2-ylidene)palladium(II); potassium tert-butylate In 1,2-dimethoxyethane at 60℃; for 4h; Buchwald-Hartwig Coupling; Schlenk technique; Glovebox; Sealed tube; Inert atmosphere;94%
tert-Octylamine
107-45-9

tert-Octylamine

5-bromo-3-chloro-2-hydroxybenzoic acid
2200-85-3

5-bromo-3-chloro-2-hydroxybenzoic acid

5-bromo-3-chloro-2-hydroxy-N-(2,4,4-trimethylpentan-2-yl)benzamide

5-bromo-3-chloro-2-hydroxy-N-(2,4,4-trimethylpentan-2-yl)benzamide

Conditions
ConditionsYield
Stage #1: 5-bromo-3-chloro-2-hydroxybenzoic acid With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 0.166667h;
Stage #2: tert-Octylamine In N,N-dimethyl-d6-formamide at 20℃;
94%
Stage #1: 5-bromo-3-chloro-2-hydroxybenzoic acid With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 0.166667h;
Stage #2: tert-Octylamine In N,N-dimethyl-formamide at 20℃;
94%
tert-Octylamine
107-45-9

tert-Octylamine

4-methoxy-phenyl-sulphonyl chloride
98-68-0

4-methoxy-phenyl-sulphonyl chloride

4-methoxy-N-(2,4,4-trimethylpentan-2-yl)benzenesulfonamide

4-methoxy-N-(2,4,4-trimethylpentan-2-yl)benzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 12h;94%
Glyoxal
131543-46-9

Glyoxal

tert-Octylamine
107-45-9

tert-Octylamine

glyoxal-bis-(1,1,3,3-tetramethyl-butylimine)
56376-10-4

glyoxal-bis-(1,1,3,3-tetramethyl-butylimine)

Conditions
ConditionsYield
In water at 20℃; for 4h;93%
In water at 20℃; for 4h;93%
With formic acid In hexane for 3h; Ambient temperature;
With water
tert-Octylamine
107-45-9

tert-Octylamine

di-tert-butyl tricarbonate
24424-95-1

di-tert-butyl tricarbonate

1,1,3,3-tetramethylbutyl isocyanate
1611-57-0

1,1,3,3-tetramethylbutyl isocyanate

Conditions
ConditionsYield
In dichloromethane for 0.0833333h; Ambient temperature;93%

107-45-9Related news

Synthesis and characterization of three-layered zinc phosphites containing tert-Octylamine (cas 107-45-9) molecules with template and ligand roles08/18/2019

Three-layered zinc phosphites containing single monoamine molecules with different roles have been synthesized using hydro(solvo)thermal methods and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and infrared spectroscopy. Compound 1, (C8H17NH3)4Zn3(HPO3)5·3H2O, ...detailed

107-45-9Relevant articles and documents

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Smolin

, p. 295,296 (1955)

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Di-tert-alkyl nitroxyl radicals. Synthesis, physical properties and applications as inhibitors of vinyl polmerization at elevated temperatures

Sosnovsky, George,Jawdosiuk, Mikolaj,Clumpner, J. Michael

, p. 109 - 126 (2007/10/03)

Stable di-tert-alkylnitroxyl radicals, tert-butyl-tert-pentylnitroxyl (4a), di-tert-pentylnitroxyl (4b) and tert-octyl-tert-pentylnitroxyl (4c), the homologs of di-tert-butylnitroxyl (1), were synthesized from tert-alkyl amines 7a-c via the 3-tert-alkylamino-3-methyl-1-butynes 8a-c. Oxidation of 8a,b with hydrogen peroxide lead to relatively unstable N-tert-alkyl-N-(1,1-dimethyl-prop-2-ynyl)nitroxyl radicals 15a,b. The thermal stability, vapor pressure data, ultraviolet, visible and electron paramagnetic resonance spectra of 4a-c were recorded. The radicals were explored as potential inhibitors of unwanted alkene polymerization reactions at elevated temperatures, in comparison with the aliphatic di-tert-butyl nitroxyl (1), the alicyclic nitroxyl radicals 2,2,6,6-tetramethylpiperidin-1-oxyl (2) and 4-hydroxy-2,2,6,6-tetramethyl-piperidin-1-oxyl (3), some commercial polymerization inhibitors, such as diethyl-hydroxylamine (Pennstop, 16), ammonium salt of N-hydroxy-N-nitrosobenzenamine (Cupferron, 17), bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate (Tinuvin 770, 18), and the well-known spin traps 2-methyl-2-nitrosopropane (19) and tert-butylhydroxylamine (20).

Catalysts for alkoxylation reactions

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, (2008/06/13)

Catalysts producing a sharply peaked alkoxylation distribution during the alkoxylation of organic materials comprise mixtures of BF3 and metal alkyls or metal alkoxides, SiF4 and metal alkyls or metal alkoxides, or mixtures of these catalysts.

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