111160-45-3Relevant articles and documents
Copper-catalyzed semihydrogenation of alkynes to Z -alkenes
Semba, Kazuhiko,Kameyama, Ryohei,Nakao, Yoshiaki
supporting information, p. 318 - 322 (2015/02/19)
Copper-catalyzed semihydrogenation of internal alkynes has been developed. The reaction proceeds under an atmosphere of hydrogen (5 atm) at 100 °C in the presence of a readily available [(PPh3)CuCl]4 catalyst to give various Z-alkenes stereoselectively.