111209-55-3Relevant articles and documents
Intramolecular Azide-Olefin Cycloadditions. A Novel Synthesis of 2,5-Dihydrooxazoles
Hassner, Alfred,Amarasekara, Ananda S.,Andisik, Donald
, p. 27 - 30 (2007/10/02)
A facile synthetic route from aldehydes to allyl α-azidoalkyl ether 2 is described.Thermolysis of 2 proceeds by intramolecular azide-olefin cycloaddition via triazolines and provides a novel synthesis of 2,5-dihydrooxazoles 6.The use of silica gel in the chemoselective conversion of the intermediate triazolines to bicyclic aziridines 7 is described.