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1205-02-3

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1205-02-3 Usage

Uses

N-Benzoyl-DL-alanine is used as pharmaceutical intermediate.

Definition

ChEBI: An N-acylamino acid that is the N-benzoyl derivative of alanine.

Synthesis Reference(s)

Tetrahedron Letters, 17, p. 2205, 1976 DOI: 10.1016/0040-4039(76)80029-9

Check Digit Verification of cas no

The CAS Registry Mumber 1205-02-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,2,0 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1205-02:
(6*1)+(5*2)+(4*0)+(3*5)+(2*0)+(1*2)=33
33 % 10 = 3
So 1205-02-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H11NO3/c1-7(10(13)14)11-9(12)8-5-3-2-4-6-8/h2-7H,1H3,(H,11,12)(H,13,14)/t7-/m0/s1

1205-02-3 Well-known Company Product Price

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  • (Code)Product description
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  • TCI America

  • (B0135)  Benzoyl-DL-alanine  >98.0%(T)

  • 1205-02-3

  • 25g

  • 390.00CNY

  • Detail
  • Alfa Aesar

  • (L13100)  N-Benzoyl-DL-alanine, 97+%   

  • 1205-02-3

  • 10g

  • 265.0CNY

  • Detail
  • Alfa Aesar

  • (L13100)  N-Benzoyl-DL-alanine, 97+%   

  • 1205-02-3

  • 50g

  • 950.0CNY

  • Detail

1205-02-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name N-benzoylalanine

1.2 Other means of identification

Product number -
Other names 2-benzamidopropanoic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1205-02-3 SDS

1205-02-3Relevant articles and documents

Biosynthesis of antibiotics of the virginiamycin family. 4. Biosynthesis of A2315A

LeFevre,Kingston

, p. 2588 - 2593 (1984)

-

Cu(II)-promoted oxidative C-N bond cleavage of N-benzoylamino acids to primary aryl amides

Zhou, Liandi,Liu, Wei,Zhao, Yongli,Chen, Junmin

, p. 52 - 62 (2021/02/06)

A novel protocol for CuCl2-promoted oxidative C-N bond cleavage of N-benzoyl amino acids was developed. It is the first example of using accessible amino acid as an ammonia synthetic equivalent for the synthesis of primary aryl amides via CuCl2-promoted oxidative C-N bond cleavage reaction. The present protocol shows excellent functional group tolerance and provides an alternative method for the synthetic of primary aryl amides in 84-96% yields.

Nickel-Catalyzed Multicomponent Coupling: Synthesis of α-Chiral Ketones by Reductive Hydrocarbonylation of Alkenes

Chen, Jian,Zhu, Shaolin

supporting information, p. 14089 - 14096 (2021/09/13)

A nickel-catalyzed, multicomponent regio- and enantioselective coupling via sequential hydroformylation and carbonylation from readily available starting materials has been developed. This modular multicomponent hydrofunctionalization strategy enables the straightforward reductive hydrocarbonylation of a broad range of unactivated alkenes to produce a wide variety of unsymmetrical dialkyl ketones bearing a functionalized α-stereocenter, including enantioenriched chiral α-aryl ketones and α-amino ketones. It uses chiral bisoxazoline as a ligand, silane as a reductant, chloroformate as a safe CO source, and a racemic secondary benzyl chloride or an N-hydroxyphthalimide (NHP) ester of a protected α-amino acid as the alkylation reagent. The benign nature of this process renders this method suitable for late-stage functionalization of complex molecules.

Asymmetric construction of dihydrobenzofuran-2,5-dione derivatives via desymmetrization of p-quinols with azlactones

Xie, Lihua,Dong, Shunxi,Zhang, Qian,Feng, Xiaoming,Liu, Xiaohua

supporting information, p. 87 - 90 (2019/01/03)

The desymmetrization of p-quinols through a chiral bisguanidinium hemisalt catalyzed enantioselective Michael addition/lactonization cascade reaction with azlactones was reported. 3-Amino-benzofuran-2,5-diones containing a chiral amino acid residue were achieved with up to 99% ee and >19?:?1 dr. An exploration of the structure of the catalyst bisguanidinium was undertaken, revealing a bifunctional catalytic model.

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