120500-69-8

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• Basic information

  1. Product Name: (2E,4E)-N-[[(2R,3S,4R,5R)-5-(2,4-dioxohexahydropyrimidin-1-yl)-3,4-dihydroxy-tetrahydrofuran-2-yl]methyl]-5-[(1S)-2-[(1R)-2-[(1R)-2-[(1R,2S)-2-[(E)-2-[(1R,2R)-2-methylcyclopropyl]vinyl]cyclopropyl]cyclopropyl]cyclopropyl]cyclopropyl]penta-2,4-dienamide
  2. Synonyms: FR 900848;Jawsamycin
  3. CAS NO:120500-69-8
  4. Molecular Formula: C₃₂H₄₃N₃O₆
  5. Molecular Weight: 565.7003
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 120500-69-8.mol
  9. Article Data: 3

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: N/A
  3. Flash Point: N/A
  4. Appearance: N/A
  5. Density: 1.466g/cm³
  6. Refractive Index: 1.749
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: (2E,4E)-N-[[(2R,3S,4R,5R)-5-(2,4-dioxohexahydropyrimidin-1-yl)-3,4-dihydroxy-tetrahydrofuran-2-yl]methyl]-5-[(1S)-2-[(1R)-2-[(1R)-2-[(1R,2S)-2-[(E)-2-[(1R,2R)-2-methylcyclopropyl]vinyl]cyclopropyl]cyclopropyl]cyclopropyl]cyclopropyl]penta-2,4-dienamide(CAS DataBase Reference)
  10. NIST Chemistry Reference: (2E,4E)-N-[[(2R,3S,4R,5R)-5-(2,4-dioxohexahydropyrimidin-1-yl)-3,4-dihydroxy-tetrahydrofuran-2-yl]methyl]-5-[(1S)-2-[(1R)-2-[(1R)-2-[(1R,2S)-2-[(E)-2-[(1R,2R)-2-methylcyclopropyl]vinyl]cyclopropyl]cyclopropyl]cyclopropyl]cyclopropyl]penta-2,4-dienamide(120500-69-8)
  11. EPA Substance Registry System: (2E,4E)-N-[[(2R,3S,4R,5R)-5-(2,4-dioxohexahydropyrimidin-1-yl)-3,4-dihydroxy-tetrahydrofuran-2-yl]methyl]-5-[(1S)-2-[(1R)-2-[(1R)-2-[(1R,2S)-2-[(E)-2-[(1R,2R)-2-methylcyclopropyl]vinyl]cyclopropyl]cyclopropyl]cyclopropyl]cyclopropyl]penta-2,4-dienamide(120500-69-8)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 120500-69-8(Hazardous Substances Data)

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• URIDINE,5'-DEOXY-5,6-DIHYDRO-5'-[[(2E,4E)-5-[(1R,...

  Cas No: 120500-69-8

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120500-69-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 120500-69-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,0,5,0 and 0 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 120500-69:
(8*1)+(7*2)+(6*0)+(5*5)+(4*0)+(3*0)+(2*6)+(1*9)=68
68 % 10 = 8
So 120500-69-8 is a valid CAS Registry Number.

120500-69-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	(2E,4E)-N-[[(2R,3S,4R,5R)-5-(2,4-dioxo-1,3-diazinan-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl]-5-[(1S)-2-[(1R)-2-[(1R)-2-[(1R,2S)-2-[(E)-2-[(1R,2R)-2-methylcyclopropyl]ethenyl]cyclopropyl]cyclopropyl]cyclopropyl]cyclopropyl]penta-2,4-dienamide

1.2 Other means of identification

Product number	-
Other names	-

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:120500-69-8 SDS

120500-69-8Upstream product

• 178436-04-9 tert-Butyl-{(1S,2R,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-methyl-cyclopropyl)-vinyl]-[1,1';2',1'';2'',1''']quatercyclopropan-2-ylmethoxy}-diphenyl-silane 
• 197013-60-8 (2E,4E)-5-{(1R,2S,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-Methyl-cyclopropyl)-vinyl]-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl}-penta-2,4-dienoic acid ethyl ester 
• 15083-05-3 5'-azido-5'-deoxy-2',3'-O-isopropylideneuridine 
• 39483-48-2 5'-azido-5'-deoxyuridine 
• 362-43-6 2',3'-O-isopropylideneuridine 
• 176168-11-9 (2E,4E)-5-[(1R,2S,1'R,2'R,1''R,2''R,1'''S,2'''R)-2'''-(tert-Butyl-dimethyl-silanyloxymethyl)-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl]-penta-2,4-dienoic acid methyl ester 
• 176300-19-9 (2E,4Z)-5-[(1R,2S,1'R,2'R,1''R,2''R,1'''S,2'''R)-2'''-(tert-Butyl-dimethyl-silanyloxymethyl)-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl]-penta-2,4-dienoic acid methyl ester 
• 176168-15-3 (2E,4E)-5-{(1R,2S,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-Methyl-cyclopropyl)-vinyl]-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl}-penta-2,4-dienoic acid methyl ester 
• 176300-20-2 (2E,4Z)-5-{(1R,2S,1'R,2'R,1''R,2''R,1'''R,2'''S)-2'''-[(E)-2-((1R,2R)-2-Methyl-cyclopropyl)-vinyl]-[1,2';1',1'';2'',1''']quatercyclopropan-2-yl}-penta-2,4-dienoic acid methyl ester 
• 176168-13-1 (1R,3S,4R,6S,7S,9R,10S,12R)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-12-<2-<(1S,2R)-2-<(phenylthio)methyl>cyclopropyl>-1(E)-ethen-1-yl>quatercyclopropane 
• 176168-12-0 (1R,3S,4R,6S,7S,9R,10S,12R)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-12-<2-<(1S,2R)-2-(hydroxymethyl)cyclopropyl>-1(E)-ethen-1-yl>quatercyclopropane 
• 176168-16-4 (1R,3S,4R,6S,7S,9R,10S,12R)-1-<5-hydroxy-5-oxo-1,3(E,E)-pentadien-1-yl>-12-<2-<(1R,2R)-2-methylcyclopropyl>-1(E)-ethen-1-yl>quatercyclopropane 
• 183617-27-8 (1R,3S,4R,6S,7S,9R,10S,12R)-1-<<(tert-butyldimethylsilyl)oxy>methyl>-12-<5-hydroxy-1,3(E,E)-pentadien-1-yl>quatercyclopropane 
• 176168-14-2 (1R,3S,4R,6S,7S,9R,10S,12R)-1-(hydroxymethyl)-12-<2-<(1S,2R)-2-methylcyclopropyl>-1(E)-ethen-1-yl>quatercyclopropane 

120500-69-8Downstream Products

120500-69-8Relevant articles and documents

Total synthesis of the antifungal agent FR-900848

Barrett, Anthony G. M.,Kasdorf, Krista

, p. 325 - 326 (1996)

The total synthesis of the antifungal agent FR-900848 is accomplished using Charette asymmetric cyclopropanation to control ten stereocentres.

Total synthesis of the pentacyclopropane antifungal agent FR-900848

Barrett, Anthony G.M.,Kasdorf, Krista

, p. 11030 - 11037 (2007/10/03)

Quatercyclopropane 31 was oxidized, homologated, reduced, and monocyclopropanated to provide the pentacyclopropane alcohol 35. Subsequent deoxygenation of alcohol 35 was effected using N-(phenylthio)succinimide (24) and tributylphosphine followed by Raney

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