124929-03-9Relevant articles and documents
The Exocyclic Effect: Protecting Group Strategy to Enhance Stereoselectivity in Hydrogen Transfer Reactions of Acyclic Free Radicals
Guindon, Yvan,Faucher, Anne-Marie,Bourque, Elyse,Caron, Valerie,Jung, Grace,Landry, Serge R.
, p. 9276 - 9283 (1997)
To enhance the diastereoselectivity of the hydrogen transfer reaction of acyclic substrates bearing 1,2- or 1,3-diols, the feasibility of a strategy employing bifunctional protecting groups has been demonstrated. This strategy is based upon the "exocyclic