1255-26-1Relevant articles and documents
-
Adam,G. et al.
, p. 3783 - 3788 (1969)
-
-
Bellamy,Doree
, p. 176,181 (1941)
-
Studies on Transition-metal Oxo and Nitrido Complexes. Part 9. Periodato and Tellurato Oxo-ruthenium Complexes as Organic Oxidants. X-Ray Crystal Structure of trans-NaK5*8H2O
El-Hendawy, Ahmed M.,Griffith, William P.,Piggott, Brian,Williams, David J.
, p. 1983 - 1988 (2007/10/02)
Salts of the anion trans-6-, earlier formulated as 6-, and of 6- have been prepared, and the X-ray crystal structure of the complex trans-NaK5*8H2O determined .Vibrational and electronic spectra for these diamagnetic 'ruthenyl' complexes are also reported.The periodato complexes function as overall six-electron oxidants in aqueous solution, converting primary alcohols to carboxylic acids and secondary alcohols to ketones; such reactions can be rendered catalytic if periodate is used as a co-oxidant.The tellurato complex functions as a two-electron oxidant for alcohols.