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128-81-4

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128-81-4 Usage

Uses

1,4,-Diaminoanthraquinone-2,3-dicarboxyimide is the intermediate for CI Disperse Blue 60.

Check Digit Verification of cas no

The CAS Registry Mumber 128-81-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,2 and 8 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 128-81:
(5*1)+(4*2)+(3*8)+(2*8)+(1*1)=54
54 % 10 = 4
So 128-81-4 is a valid CAS Registry Number.
InChI:InChI=1/C16H9N3O4/c17-11-7-8(12(18)10-9(11)15(22)19-16(10)23)14(21)6-4-2-1-3-5(6)13(7)20/h1-4H,17-18H2,(H,19,22,23)

128-81-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,11-diaminonaphtho[2,3-f]isoindole-1,3,5,10-tetrone

1.2 Other means of identification

Product number -
Other names 4,11-diamino-naphth[2,3-f]isoindole-1,3,5,10-tetraone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:128-81-4 SDS

128-81-4Synthetic route

1,4-diamino-2,3-dicyano-anthraquinone
81-41-4

1,4-diamino-2,3-dicyano-anthraquinone

NSC 115447
128-81-4

NSC 115447

Conditions
ConditionsYield
Stage #1: 1,4-diamino-2,3-dicyano-anthraquinone With sulfuric acid at 150℃; for 1h;
Stage #2: With water at 40 - 50℃;
In sulfuric acid; water
With sulfuric acid at 80 - 140℃; for 1.75h;
With sulfuric acid
1,4-diamino-9,10-dioxo-9,10-dihydro-anthracene-2,3-dicarboxylic acid diamide
6647-20-7

1,4-diamino-9,10-dioxo-9,10-dihydro-anthracene-2,3-dicarboxylic acid diamide

NSC 115447
128-81-4

NSC 115447

Conditions
ConditionsYield
With sulfuric acid
1-amino-4-vinylsulphonylbenzene
25781-90-2

1-amino-4-vinylsulphonylbenzene

NSC 115447
128-81-4

NSC 115447

1,4-diaminoanthraquinone-(N-anilinesulfonylethyl)-2,3-dicarboxyimide

1,4-diaminoanthraquinone-(N-anilinesulfonylethyl)-2,3-dicarboxyimide

Conditions
ConditionsYield
tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 40 - 50℃; for 7h; Michael addition;97%
Divinyl sulfone
77-77-0

Divinyl sulfone

NSC 115447
128-81-4

NSC 115447

1,4-diaminoanthraquinone-(N-vinylsulfonylethyl)-2,3-dicarboxyimide
911674-46-9

1,4-diaminoanthraquinone-(N-vinylsulfonylethyl)-2,3-dicarboxyimide

Conditions
ConditionsYield
tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 40 - 50℃; for 6h; Michael addition;95%
Divinyl sulfone
77-77-0

Divinyl sulfone

NSC 115447
128-81-4

NSC 115447

bis(1,4-diaminoanthraquinone-(N-ethyl)-2,3-dicarboxyimide)sulfone

bis(1,4-diaminoanthraquinone-(N-ethyl)-2,3-dicarboxyimide)sulfone

Conditions
ConditionsYield
tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 40 - 60℃; for 4h; Product distribution / selectivity; Michael addition;87%
1,4-diaminoanthraquinone-(N-vinylsulfonylethyl)-2,3-dicarboxyimide
911674-46-9

1,4-diaminoanthraquinone-(N-vinylsulfonylethyl)-2,3-dicarboxyimide

NSC 115447
128-81-4

NSC 115447

bis(1,4-diaminoanthraquinone-(N-ethyl)-2,3-dicarboxyimide)sulfone

bis(1,4-diaminoanthraquinone-(N-ethyl)-2,3-dicarboxyimide)sulfone

Conditions
ConditionsYield
tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 40 - 60℃; for 3h; Product distribution / selectivity; Michael addition;86%
NSC 115447
128-81-4

NSC 115447

1,2-diaminopropan
78-90-0, 10424-38-1

1,2-diaminopropan

4,11-diamino-2-(2-amino-propyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone

4,11-diamino-2-(2-amino-propyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With 1,2-dichloro-benzene
NSC 115447
128-81-4

NSC 115447

ethanolamine
141-43-5

ethanolamine

4,11-diamino-2-(2-hydroxyethyl)-1h-naphtho[2,3-f]isoindole-1,3,5,10(2h)-tetraone
3319-48-0

4,11-diamino-2-(2-hydroxyethyl)-1h-naphtho[2,3-f]isoindole-1,3,5,10(2h)-tetraone

Conditions
ConditionsYield
In 1,2-dichloro-benzene at 120 - 150℃; for 3h;
In water
In 1-methyl-pyrrolidin-2-one at 130℃; for 2h;
With methanol; nitrobenzene
NSC 115447
128-81-4

NSC 115447

2-(2-Aminoethylamino)ethanol
111-41-1

2-(2-Aminoethylamino)ethanol

4,11-diamino-2-[2-(2-hydroxy-ethylamino)-ethyl]-naphth[2,3-f]isoindole-1,3,5,10-tetraone

4,11-diamino-2-[2-(2-hydroxy-ethylamino)-ethyl]-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With 2-ethoxy-ethanol
NSC 115447
128-81-4

NSC 115447

ethylenediamine
107-15-3

ethylenediamine

4,11-diamino-2-(2-amino-ethyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone
49743-51-3

4,11-diamino-2-(2-amino-ethyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With 2-ethoxy-ethanol
NSC 115447
128-81-4

NSC 115447

N-butylamine
109-73-9

N-butylamine

4,11-diamino-2-butyl-naphth[2,3-f]isoindole-1,3,5,10-tetraone
3176-88-3

4,11-diamino-2-butyl-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With ethanol; 1,2-dichloro-benzene
NSC 115447
128-81-4

NSC 115447

1-amino-3-(dimethylamino)propane
109-55-7

1-amino-3-(dimethylamino)propane

4,11-diamino-2-(3-dimethylamino-propyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone
6647-34-3

4,11-diamino-2-(3-dimethylamino-propyl)-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With 2-ethoxy-ethanol
NSC 115447
128-81-4

NSC 115447

methylamine
74-89-5

methylamine

4,11-diamino-2-methyl-naphth[2,3-f]isoindole-1,3,5,10-tetraone
71307-97-6

4,11-diamino-2-methyl-naphth[2,3-f]isoindole-1,3,5,10-tetraone

Conditions
ConditionsYield
With methanol; 1,2-dichloro-benzene
3-(2-methoxyethoxy)propan-1-amine
54303-31-0

3-(2-methoxyethoxy)propan-1-amine

NSC 115447
128-81-4

NSC 115447

N-[3-(2-methoxyethoxy)propyl]-1,4-diaminoanthraquinone-2,3-dicarboximide

N-[3-(2-methoxyethoxy)propyl]-1,4-diaminoanthraquinone-2,3-dicarboximide

Conditions
ConditionsYield
In methanol; water
NSC 115447
128-81-4

NSC 115447

3-methoxypropylamine
5332-73-0

3-methoxypropylamine

N-(3-methoxypropyl)-1,4-diaminoanthraquinone-2,3-dicarboximide

N-(3-methoxypropyl)-1,4-diaminoanthraquinone-2,3-dicarboximide

Conditions
ConditionsYield
In methanol; water
methacryloyl anhydride
760-93-0

methacryloyl anhydride

NSC 115447
128-81-4

NSC 115447

2-(4,11-diamino-1,3,5,10-tetraoxo-1h-naphtho[2,3-f]isoindol-2(3h,5h,10h)-yl)ethyl methacrylate
162887-95-8

2-(4,11-diamino-1,3,5,10-tetraoxo-1h-naphtho[2,3-f]isoindol-2(3h,5h,10h)-yl)ethyl methacrylate

Conditions
ConditionsYield
With dmap; triethanolamine In tetrahydrofuran; water
1,2-bis(3-aminopropoxy)ethane
2997-01-5

1,2-bis(3-aminopropoxy)ethane

NSC 115447
128-81-4

NSC 115447

C40H32N6O10
1209470-30-3

C40H32N6O10

Conditions
ConditionsYield
In pentan-1-ol for 8h; Reflux;
NSC 115447
128-81-4

NSC 115447

1,4-diaminoanthraquinone-(N-succinimidylethanesulfonylethyl)-2,3-dicarboxyimide

1,4-diaminoanthraquinone-(N-succinimidylethanesulfonylethyl)-2,3-dicarboxyimide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetra(n-butyl)ammonium hydroxide / 1,4-dioxane; water / 6 h / 40 - 50 °C
2: tetra(n-butyl)ammonium hydroxide / 1,4-dioxane; water / 3 h / 40 - 60 °C
View Scheme
NSC 115447
128-81-4

NSC 115447

3-aminopentane
616-24-0

3-aminopentane

C21H19N3O4

C21H19N3O4

Conditions
ConditionsYield
With sulfolane at 140℃; for 6h; Autoclave;
In sulfolane at 140℃; for 6h; Autoclave;
2-methyl-2-butylamine
594-39-8

2-methyl-2-butylamine

NSC 115447
128-81-4

NSC 115447

C21H19N3O4

C21H19N3O4

Conditions
ConditionsYield
In sulfolane at 160℃; for 18h;
NSC 115447
128-81-4

NSC 115447

2-pentylamine
625-30-9

2-pentylamine

C21H19N3O4

C21H19N3O4

Conditions
ConditionsYield
In sulfolane at 140℃; for 6h; Autoclave;

128-81-4Relevant articles and documents

Anthraquinone dye-containing material, composition including the same, camera including the same, and associated methods

-

Page/Page column 10, (2013/07/25)

A (meth)acrylate ester includes a (meth)acrylate moiety having an ester oxygen, an anthraquinone moiety having a transmittance spectrum producing blue light, and a linking group covalently bound to the ester oxygen and to a ring of the anthraquinone moiety, the linking group including, as a first component: phenyl, naphthyl, a linear alkyl group having from 1 to about 6 carbons, a branched alkyl group having from 3 to about 6 carbons, a cycloalkyl group having from about 3 to about 20 carbons, or a substituted aromatic group.

OLIGOMERIC DYES AND PREPARATION THEREOF

-

Page 27, (2010/02/06)

The invention provides a method for preparing an oligomeric dye by reacting a first component oligomer, having a carbon-carbon backbone, comprising a plurality of polymerized monomer units comprising pendant reactive nucleophilic or electrophilic functional groups; and a dye component having a co-reactive functional group.These oligomeric dyes are suitable for use as additives to impart coloration or fluorescence to thermoplastic polymers, particularly olefinic polymers. The oligomeric dyes of the present invention advantageously are compatible in polymers where conventional dyes often have poor compatibility or solubility.

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