Welcome to LookChem.com Sign In|Join Free

CAS

  • or

129-44-2

129-44-2

Post Buying Request

129-44-2 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

129-44-2 Usage

Uses

1,5-Diaminoanthraquinone (DAAQ) may be used in the preparation of vertical nanowire arrays. It may be used in the synthesis of poly(1,5-diaminoanthraquinone) (PDAA) particles, via chemically oxidative polymerization of DAAQ.

General Description

1,5-Diaminoanthraquinone (DAAQ) is an organic dye compound. Rapid preparation of 1,5-diaminoanthraquinone nanofibers (DAAQNFs) decorated with small platinum nanoparticles (PtNPs) has been reported. The absorption and fluorescence spectra of DAAQ has been investigated in various organic solvents. Preparation of vertical organic nanowire arrays of DAAQ on solid substrates by a facile physical vapor transport method has been reported.

Purification Methods

Recrystallise it from aniline (m 313-314o) EtOH or acetic acid [Flom & Barbara J Phys Chem 89 4481 1985]. [Beilstein 14 H 303, 14 I 467, 14 II 116, 14 III 466, 14 IV 479.]

Check Digit Verification of cas no

The CAS Registry Mumber 129-44-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,2 and 9 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 129-44:
(5*1)+(4*2)+(3*9)+(2*4)+(1*4)=52
52 % 10 = 2
So 129-44-2 is a valid CAS Registry Number.
InChI:InChI=1/C14H10N2O2/c15-9-5-1-3-7-11(9)14(18)8-4-2-6-10(16)12(8)13(7)17/h1-6H,15-16H2

129-44-2 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail

  • Alfa Aesar

  • (A18840)  1,5-Diaminoanthraquinone, 90+%   

  • 129-44-2

  • 25g

  • 529.0CNY

  • Detail

  • Alfa Aesar

  • (A18840)  1,5-Diaminoanthraquinone, 90+%   

  • 129-44-2

  • 100g

  • 1590.0CNY

  • Detail

129-44-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,5-Diaminoanthraquinone

1.2 Other means of identification

Product number -
Other names 9,10-Anthracenedione, 1,5-diamino-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:129-44-2 SDS

129-44-2Synthetic route

N,N-(anthraquinon-1,5-diyl)-bis(triphenylphosphazene)
85193-25-5

N,N-(anthraquinon-1,5-diyl)-bis(triphenylphosphazene)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With sulfuric acid at 140℃; for 0.166667h;69%
1,5-Dichloroanthraquinone
82-46-2

1,5-Dichloroanthraquinone

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

1-amino-5-chloroanthracene-9,10-dione
117-11-3

1-amino-5-chloroanthracene-9,10-dione

Conditions
ConditionsYield
In ammonia; waterA 54%
B n/a
In ammonia; waterA 53%
B n/a
In ammonia; waterA 51.8%
B n/a
With ammonium hydroxide at 170℃;
decahydro-2-methylquinoline
20717-43-5

decahydro-2-methylquinoline

1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

1-amino-5-nitroanthraquinone
6937-75-3

1-amino-5-nitroanthraquinone

C

1,5-bis-hydroxyamino-anthraquinone
60080-32-2

1,5-bis-hydroxyamino-anthraquinone

1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With acid durch elektrolytische Reduktion;
With tin oxidepotash
With phenylhydrazine
1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

1-amino-5-nitroanthraquinone
6937-75-3

1-amino-5-nitroanthraquinone

Conditions
ConditionsYield
With sodium disulfite at 120 - 180℃; unter Druck;
1,5-bis-(toluene-4-sulfonylamino)-anthraquinone
79285-23-7

1,5-bis-(toluene-4-sulfonylamino)-anthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With sulfuric acid at 50 - 60℃;
sodium anthraquinone-1,5-disulphonate
853-35-0

sodium anthraquinone-1,5-disulphonate

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck;
With ammonium hydroxide; barium(II) chloride at 180 - 186℃; im Autoklaven;
With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck;
1,5-Dichloroanthraquinone
82-46-2

1,5-Dichloroanthraquinone

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With copper diacetate; potassium carbonate; 1,2-dichloro-benzene weiteres Reagens: Kupfer(I)-chlorid; Behandeln des Reaktionsprodukts mit Schwefelsaeure;
1,5-Dichloroanthraquinone
82-46-2

1,5-Dichloroanthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 65 percent / Heating
2: 10percent aq. HCl / tetrahydrofuran
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate; copper acetate; nitrobenzene
2: concentrated sulfuric acid / 50 - 60 °C
View Scheme
With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser;
With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser;
1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

phenylhydrazine
100-63-0

phenylhydrazine

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

1,5-bis-hydroxyamino-anthraquinone
60080-32-2

1,5-bis-hydroxyamino-anthraquinone

1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

1-amino-5-nitroanthraquinone
6937-75-3

1-amino-5-nitroanthraquinone

C

1,5-bis-hydroxyamino-anthraquinone
60080-32-2

1,5-bis-hydroxyamino-anthraquinone

1,5-diaminoanthrone
87120-49-8

1,5-diaminoanthrone

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

7-amino-8,10-dimethylthio-6H-anthra<9,1-cd>isothiazol-6-one
116935-08-1

7-amino-8,10-dimethylthio-6H-anthra<9,1-cd>isothiazol-6-one

C

7-amino-10-methylthio-6H-anthra<9,1-cd>isothiazol-6-one
116935-07-0

7-amino-10-methylthio-6H-anthra<9,1-cd>isothiazol-6-one

Conditions
ConditionsYield
With sodium hydroxide; sulfur; triethylamine; dimethyl sulfate 1) reflux 15 min DMFA; Multistep reaction. Title compound not separated from byproducts;
1,5-diaminoanthrone
87120-49-8

1,5-diaminoanthrone

dimethyl sulfate
77-78-1

dimethyl sulfate

A

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

B

7-amino-8,10-dimethylthio-6H-anthra<9,1-cd>isothiazol-6-one
116935-08-1

7-amino-8,10-dimethylthio-6H-anthra<9,1-cd>isothiazol-6-one

C

7-amino-10-methylthio-6H-anthra<9,1-cd>isothiazol-6-one
116935-07-0

7-amino-10-methylthio-6H-anthra<9,1-cd>isothiazol-6-one

Conditions
ConditionsYield
With sodium hydroxide; sulfur; triethylamine 1) reflux 15 min DMFA; Multistep reaction. Title compound not separated from byproducts;
With sodium hydroxide; sulfur; triethylamine 1) reflux 15 min DMFA; Multistep reaction;
1,5-Bis-(2,2-diethoxy-ethylamino)-anthraquinone

1,5-Bis-(2,2-diethoxy-ethylamino)-anthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran
1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

acid

acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
elektrolytische Reduktion;
ammonium salt of/the/ 1-phenoxy-anthraquinone-sulfonic acid-(5)

ammonium salt of/the/ 1-phenoxy-anthraquinone-sulfonic acid-(5)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonium hydroxide at 180℃; unter Druck;
potassium salt of/the/ 5-nitro-anthraquinone-sulfonic acid-(1)

potassium salt of/the/ 5-nitro-anthraquinone-sulfonic acid-(1)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonia at 225℃; im Rohr;
potassium salt of/the/ anthraquinone-disulfonic acid-(1.5)

potassium salt of/the/ anthraquinone-disulfonic acid-(1.5)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonium hydroxide unter Druck;
salt of/the/ anthraquinone-disulfonic acid-(1.5)

salt of/the/ anthraquinone-disulfonic acid-(1.5)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonia
With ammonia
sodium-salt of 9.10-dioxo-9.10-dihydro-anthracene-disulfonic acid-(1.5)

sodium-salt of 9.10-dioxo-9.10-dihydro-anthracene-disulfonic acid-(1.5)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonium hydroxide; oxidizing agent; barium(II) chloride at 180℃;
1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

water
7732-18-5

water

sodium sulfide

sodium sulfide

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

tin oxidepotash

tin oxidepotash

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

ammonia
7664-41-7

ammonia

potassium 5-nitroanthraquinone-1-sulfonate
93804-31-0

potassium 5-nitroanthraquinone-1-sulfonate

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
at 225℃;
1,5-bis-hydroxyamino-anthraquinone
60080-32-2

1,5-bis-hydroxyamino-anthraquinone

tin oxide/sodium carbonate

tin oxide/sodium carbonate

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

anthra<1,9-cd:5,10-c'd'>bis(isoxazole)
201-91-2

anthra<1,9-cd:5,10-c'd'>bis(isoxazole)

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 98 percent / xylene / 1.5 h / Heating
2: 69 percent / 85percent H2SO4 / 0.17 h / 140 °C
View Scheme
1-nitroanthraquinone
82-34-8

1-nitroanthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated sulfuric acid; nitric acid
2: tin oxidepotash
View Scheme
9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated sulfuric acid; nitric acid
2: tin oxidepotash
View Scheme
Multi-step reaction with 2 steps
1: HNO3+H2SO4
2: sodium sulfide
View Scheme
Pd on active charcoal

Pd on active charcoal

1.5-dinitroanthraquinone
82-35-9

1.5-dinitroanthraquinone

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
In methoxybenzene
C14H10N2O2*2ClH

C14H10N2O2*2ClH

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Conditions
ConditionsYield
With ammonia neat (no solvent);
4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carboxylic acid
877869-07-3

4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carboxylic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C70H64N8O10
1181305-97-4

C70H64N8O10

Conditions
ConditionsYield
With benzotriazol-1-ol; dicyclohexyl-carbodiimide In dichloromethane at 20℃; Reflux;98%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

9,10-anthraquinone 1,5-bis(diazonium hydrogensulfate)
81622-38-0

9,10-anthraquinone 1,5-bis(diazonium hydrogensulfate)

Conditions
ConditionsYield
With nitrosylsulfuric acid In sulfuric acid for 1h; under 25 deg C;96.7%
With nitrosylsulfuric acid; sulfuric acid for 1h; Ambient temperature;92%
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid at 60℃; for 0.5h;
Stage #2: With nitrosylsulfuric acid; sulfuric acid In water at 20℃; for 1.66667h;		91%
9-{2-[(4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carboxylic acid
1005329-65-6

9-{2-[(4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carboxylic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C126H120N16O18

C126H120N16O18

Conditions
ConditionsYield
With benzotriazol-1-ol; dicyclohexyl-carbodiimide In dichloromethane at 20℃; Reflux;96%
pyrrolidinedithiocarbamate
25769-03-3

pyrrolidinedithiocarbamate

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(pyrrolidin-1-carbodithioate)

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(pyrrolidin-1-carbodithioate)

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite
Stage #2: pyrrolidinedithiocarbamate In water at 5 - 10℃; for 0.5h;		96%
piperidine-1-carbodithioic acid
98-99-7

piperidine-1-carbodithioic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(piperidin-1-carbodithioate)

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(piperidin-1-carbodithioate)

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite
Stage #2: piperidine-1-carbodithioic acid In water at 5 - 10℃; for 0.5h;		95%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1,5-diamino-2,4,6,8-tetrabromoanthracene-9,10-dione
81-56-1

1,5-diamino-2,4,6,8-tetrabromoanthracene-9,10-dione

Conditions
ConditionsYield
With bromine at 50 - 60℃; Bio-ionic liquid;94%
With hydrogen bromide; 3-chloro-benzenecarboperoxoic acid In methanol at 30 - 32℃; for 0.166667h; Reagent/catalyst;90%
With 1,9-diperoxynonanedioic acid; acetic acid; potassium bromide at 30 - 32℃; for 3h;80%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

N-(2,6-diisopropylphenyl)-1,6-bis(4-(1,1,3,3-tetramethylbutyl)phenoxy)-9-bromoperylene-3,4-dicarboximide

N-(2,6-diisopropylphenyl)-1,6-bis(4-(1,1,3,3-tetramethylbutyl)phenoxy)-9-bromoperylene-3,4-dicarboximide

N,N'-bis[9-(N-(2,6-diisopropylphenyl)-1,6-bis(4-tert-octylphenoxy)perylene-3,4-dicarboximide)yl]-1,5-diaminoanthraquinone

N,N'-bis[9-(N-(2,6-diisopropylphenyl)-1,6-bis(4-tert-octylphenoxy)perylene-3,4-dicarboximide)yl]-1,5-diaminoanthraquinone

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 80℃; for 16h;94%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

chloroacetyl chloride
79-04-9

chloroacetyl chloride

1,5-Bis(chloracetylamino)-9,10-anthracendion
43182-25-8

1,5-Bis(chloracetylamino)-9,10-anthracendion

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 20℃; for 24h;93%
With pyridine In nitrobenzene for 3h; Heating;89%
With pyridine at 20℃; for 24h;80%
With N-ethyl-N,N-diisopropylamine; pyridine at 20℃; Cooling; Inert atmosphere; Darkness;80%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione
187536-93-2

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

N,N'-bis[4-(N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)yl]-1,5-diaminoanthraquinone

N,N'-bis[4-(N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)yl]-1,5-diaminoanthraquinone

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 80℃; for 16h;92%
2-thienylacetic acid chloride
39098-97-0

2-thienylacetic acid chloride

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C26H18N2O4S2
1616115-66-2

C26H18N2O4S2

Conditions
ConditionsYield
In tetrahydrofuran Inert atmosphere; Reflux;92%
In tetrahydrofuran Reflux;92%
2-thienylacetic acid chloride
39098-97-0

2-thienylacetic acid chloride

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C26H18N2O4S2

C26H18N2O4S2

Conditions
ConditionsYield
In tetrahydrofuran Inert atmosphere; Reflux;92%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1,5-diiodoanthracene-9,10-dione
3311-73-7

1,5-diiodoanthracene-9,10-dione

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite In water at -20℃; for 0.5h;
Stage #2: With potassium iodide In water at -20 - 80℃; for 5h;		90%
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite for 3h;
Stage #2: With potassium iodide In water for 3h; Further stages.;		82%
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid for 0.166667h; Inert atmosphere;
Stage #2: With sodium nitrite In water at 0℃; for 3.5h; Inert atmosphere;
Stage #3: With potassium iodide In water for 6h; Inert atmosphere;		40%
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite at 0℃; for 3h; Inert atmosphere; Schlenk technique;
Stage #2: With potassium iodide at 20℃; for 6h; Inert atmosphere; Schlenk technique;		37%
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite In water at 15℃; for 0.5h;
Stage #2: With potassium iodide In water at 20 - 80℃; for 5h;		33%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

4-Chlorobutanoyl chloride
4635-59-0

4-Chlorobutanoyl chloride

1,5-bis(4-chlorobutyramido)anthraquinone

1,5-bis(4-chlorobutyramido)anthraquinone

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 20℃; for 24h;90%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

Chloroacetic anhydride
541-88-8

Chloroacetic anhydride

1,5-Bis(chloracetylamino)-9,10-anthracendion
43182-25-8

1,5-Bis(chloracetylamino)-9,10-anthracendion

Conditions
ConditionsYield
With pyridine In nitrobenzene for 3h; Heating;89%
9-{2-[(9-{2-[(4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carboxylic acid

9-{2-[(9-{2-[(4,7-diisobutoxy-9-phenylcarbamoyl-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carbonyl)-amino]-phenylcarbamoyl}-4,7-diisobutoxy-[1,10]phenanthroline-2-carboxylic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C182H176N24O26

C182H176N24O26

Conditions
ConditionsYield
With benzotriazol-1-ol; dicyclohexyl-carbodiimide In dichloromethane at 20℃; Reflux;89%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

acetaldehyde
75-07-0

acetaldehyde

N,N'-bis(1-methyl-2-formylethyl)-1,5-diaminoanthraquinone
89734-96-3

N,N'-bis(1-methyl-2-formylethyl)-1,5-diaminoanthraquinone

Conditions
ConditionsYield
With oxalic acid at 20℃; for 3h;88%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1,5-dibromo-9,10-anthraquinone
602-77-7

1,5-dibromo-9,10-anthraquinone

Conditions
ConditionsYield
With tert.-butylnitrite; copper(ll) bromide In acetonitrile at 65℃; for 2.5h;88%
With tert.-butylnitrite; copper(I) bromide In acetonitrile for 1h; Sandmeyer Reaction; Reflux;87%
With tert.-butylnitrite; copper(ll) bromide In acetonitrile at 65℃; for 5h;84%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

anthracene-1,5-diamine
79015-49-9

anthracene-1,5-diamine

Conditions
ConditionsYield
With sodium hydroxide In water Clemmensen Reduction; Reflux;87%
With sodium tetrahydroborate In isopropyl alcohol at 80℃; for 14h;87%
With zinc In sodium hydroxide at 90℃; for 60h;68%
With sodium tetrahydroborate In isopropyl alcohol at 80℃; for 14h; Inert atmosphere;41%
morpholine-4-carbodithioic acid
3581-30-4

morpholine-4-carbodithioic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(morpholin-4-carbodithioate)

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(morpholin-4-carbodithioate)

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite
Stage #2: morpholine-4-carbodithioic acid In water at 5 - 10℃; for 0.5h;		87%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

phenylacetyl chloride
103-80-0

phenylacetyl chloride

C30H22N2O4

C30H22N2O4

Conditions
ConditionsYield
In tetrahydrofuran Reflux;85%
Diethyldithiocarbamic acid
147-84-2

Diethyldithiocarbamic acid

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(diethylcarbamodithioate)

9,10-dihydro-9,10-dioxoanthracen-1,5-diyl bis(diethylcarbamodithioate)

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid; sodium nitrite
Stage #2: Diethyldithiocarbamic acid In water at 5 - 10℃; for 0.5h;		85%
4-cyanoacetylmorpholine
15029-32-0

4-cyanoacetylmorpholine

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1,7-dicyano-2,8-dimorpholino-3,9-diazaperylene
90904-51-1

1,7-dicyano-2,8-dimorpholino-3,9-diazaperylene

Conditions
ConditionsYield
With trichlorophosphate In 1,4-dioxane at 75 - 80℃; for 4h;84%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

4,8-diamino-1,5-dihydroxyanthraquinone
145-49-3

4,8-diamino-1,5-dihydroxyanthraquinone

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With sulfuric acid at 0℃; for 0.25h;
Stage #2: With sodium chlorate at 0 - 20℃; for 3.75h;		83%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C14H8Cl8N2O2P2
129973-17-7

C14H8Cl8N2O2P2

Conditions
ConditionsYield
With phosphorus pentachloride In benzene for 1.5h; Heating;82%
cis,trans-2,5-dimethoxytetrahydrofuran
696-59-3

cis,trans-2,5-dimethoxytetrahydrofuran

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

1,5-di(1H-pyrrol-1-yl)anthracene-9,10-dione

1,5-di(1H-pyrrol-1-yl)anthracene-9,10-dione

Conditions
ConditionsYield
With iodine In water; N,N-dimethyl-formamide at 120℃; for 3h; Clauson-Kaas Synthesis;78%
With water; iodine In N,N-dimethyl-formamide at 120℃; for 3h; Clauson-Kaas Synthesis;78%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

N,N-diethylaniline
91-66-7

N,N-diethylaniline

1,5-bis((E)-(4-(diethylamino)phenyl)diazenyl)anthracene-9,10-dione

1,5-bis((E)-(4-(diethylamino)phenyl)diazenyl)anthracene-9,10-dione

Conditions
ConditionsYield
Stage #1: 1,5-diaminoanthraquinone With hydrogenchloride; sodium nitrite In water at 0 - 2℃; for 1.75h;
Stage #2: N,N-diethylaniline In ethanol; water at 0 - 5℃; for 4h;		77.3%
Cyclopentanecarboxylic acid chloride
4524-93-0

Cyclopentanecarboxylic acid chloride

1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

C26H26N2O4

C26H26N2O4

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 20℃; for 24h;77%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

4-isobutoxy-8-nitro-2-quinolinecarboxylic acid chloride
754216-33-6

4-isobutoxy-8-nitro-2-quinolinecarboxylic acid chloride

C42H34N6O10

C42H34N6O10

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In toluene at 70℃; for 2h;76%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

(1SR,2SR)-2-phenylcyclopropanecarbonyl chloride
939-87-7, 5685-36-9, 37107-48-5, 42916-08-5, 42916-12-1, 42916-13-2, 62624-90-2, 78738-39-3

(1SR,2SR)-2-phenylcyclopropanecarbonyl chloride

1,5-bis(trans-2-phenyl-1-cyclopropanylcarbonylamino)anthraquinone

1,5-bis(trans-2-phenyl-1-cyclopropanylcarbonylamino)anthraquinone

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 20℃; for 24h;75%
1,5-diaminoanthraquinone
129-44-2

1,5-diaminoanthraquinone

cyclopropanecarboxylic acid chloride
4023-34-1

cyclopropanecarboxylic acid chloride

C22H18N2O4

C22H18N2O4

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 20℃; for 24h;75%

129-44-2Related news

All solid-state redox supercapacitors based on supramolecular 1,5-DIAMINOANTHRAQUINONE (cas 129-44-2) oligomeric electrode and polymeric electrolytes09/27/2019

Supramolecular conducting oligomeric 1,5-diaminoanthraquinone (DAAQ)-based all solid-state redox supercapacitors have been fabricated with the solid polymer electrolyte, poly vinyl alcohol (PVA)-H 3 PO 4 blend and polymeric gel electrolyte poly methyl methacrylate (PMMA)-ethylene...detailed

Low-temperature formation of self-assembled 1,5-DIAMINOANTHRAQUINONE (cas 129-44-2) nanofibers: Substrate effects and field emission characteristics09/26/2019

In this study, we used thermal evaporation with a low sublimation temperature (42°C) to deposit 1,5-diaminoanthraquinone (DAAQ) in various morphologies—including nanorods, nanocornerstones, and nanofibers—onto various substrates. Three major factors influenced the growth of vertically aligned...detailed

129-44-2Relevant articles and documents

Vertical organic nanowire arrays: Controlled synthesis and chemical Sensors

Yong, Sheng Zhao,Jinsong, Wu,Jiaxing, Huang

, p. 3158 - 3159 (2009)

-

A facile method for preparing substituted 1-aminoanthraquinones

Wormser,Sardessai,Abramson

, p. 3211 - 3222 (2007/10/02)

An efficient and simple preparation of α-substituted aminoanthraquinones using 2,2,-dialkoxyethylamines is described.

Ring Opening Reactions of 6H-Anthraisoxazol-6-ones and Related Compounds

Sutter, P.,Weis, C. D.

, p. 997 - 1011 (2007/10/02)

Nucleophilic attack of anthraisoxazol-6-ones, and of anthraisoxazole by various sulfoxides, triphenyl phosphine, and aliphatic or aromatic phosphites proceeded with cleavage of the nitrogen-oxygen bond of the isoxazole ring.This method provided ready access to substituted anthraquinones bearing sulfoximido-, triphenylphosphazo-, and dialkyl(aryl)phosphoramidic groups attached to the 1- and the 1,5-positions of the anthraquinone system.The structures of the newly synthesized anthraquinone derivatives were supported by analytical and spectral data. 1 -S,S-dimethyl-N-(5-benzamidoanthraquinon-1-yl)sulfoximide yielded in 90percent sulfuric acid the 1-amino-5-sulfoximido anthraquinone without hydrolyzing the sulfoximido group.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 129-44-2