13280-16-5Relevant articles and documents
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Hortmann et al.
, p. 2289 (1978)
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Itoh et al.
, p. 3199 (1968)
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Visible-Light-Mediated Umpolung Reactivity of Imines: Ketimine Reductions with Cy2NMe and Water
Wang, Rui,Ma, Mengyue,Gong, Xu,Panetti, Grace B.,Fan, Xinyuan,Walsh, Patrick J.
supporting information, p. 2433 - 2436 (2018/04/27)
A novel carbanionic reactivity of imines mediated by photoredox catalysis is demonstrated. The umpolung imine reactivity is exemplified by proton abstraction from water as a key step in the reduction of benzophenone ketimines to amines (up to 98% yield). Deuterium is introduced into amines efficiently using D2O as an inexpensive deuterium source (≥95% D ratio). The mechanism of this unusual transformation is probed.
Photolysis of 3-Methyl-5,5-diphenyl-3,5-dihydro-4H-1,2,3-triazol-4-one
Quast, Helmut,Hergenroether, Thomas
, p. 2625 - 2628 (2007/10/02)
Irradiation (λ >/= 280 nm) of a degassed solution in deuterated benzene of the dihydro-1,2,3-triazolone 5 yields the dihydroindolone 7, the imine 9, and its photoreduction product 10, besides molecular nitrogen. Key Words: 4H-1,2,3-Triazol-4-one, 3,5-dihydro- / Photoextrusion of molecular nitrogen / Indol-2-one, 2,3-dihydro- / Aziridone / α-Lactam / Decarbonylation
Reactions of N-Halo-N-methylbenzylamines with MeONa-MeOH and t-BuOK-t-BuOH. Effects of β-Carbon Substituent and Base-Solvent System upon the Imine-Forming Transition State
Bartsch, Richard A.,Cho, Bong Rae
, p. 2252 - 2257 (2007/10/02)
Elimination reactions of YC6H4CH(R)N(X)CH3 in which R = Me and Ph and X = Cl and Br promoted by MeONa-MeOH and t-BuOK-t-BuOH have been studied kinetically.The elimination reactions are regiospecific, producing only the corresponding N-benzylidenemethylami
