13960-34-4Relevant articles and documents
Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation
Halder, Arjun,Kandambeth, Sharath,Biswal, Bishnu P.,Kaur, Gagandeep,Roy, Neha Chaki,Addicoat, Matthew,Salunke, Jagadish K.,Banerjee, Subhrashis,Vanka, Kumar,Heine, Thomas,Verma, Sandeep,Banerjee, Rahul
, p. 7806 - 7810 (2016)
Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and
Lanthanide(III) Ion Catalyzed Reaction of Ammonia and Nitriles: Synthesis of 2,4,6-Trisubstituted-s-triazines
Forsberg, John H.,Spaziano, Vincent T.,Klump, Stephen P.,Sanders, Kathleen M.
, p. 767 - 770 (2007/10/02)
Lanthanum and yttrium trifluoromethanesulfonates at 1 mole percent concentration, have been found to catalyze a reaction between ammonia and aromatic nitriles to yield symmetrically substituted 2,4,6-triaryl-s-triazines.The generally high yields and relatively mild reaction conditions of this procedure suggest it as an alternative to other aromatic nitrile cyclotrimerization reactions.Of the aliphatic nitriles studied, acetonitrile and cyclopropanecarbonitrile gave good yields of triazine, propionitrile and butyronitrile gave significantly reduced yields of triazines 3b and3c respectively.Rearrangement of 3a and 3b to alkylated-4-aminopyrimidines was observed.
