14055-74-4Relevant articles and documents
Large-scale synthesis of van der Waals 1-dimensional material Mo6S3I6 by using a MoI2 precursor
Oh, Seungbae,Chae, Sudong,Choi, Kyung Hwan,Kim, Bum Jun,Lee, Sang Hoon,Wang, Cong,Liu, Zhixiang,Jeon, Jiho,Lee, Jae-Hyun,Yu, Hak Ki,Choi, Jae-Young
, p. 499 - 504 (2019)
By using a MoI2 precursor, a one-dimensional linear chain material, Mo6S3I6, was synthesized on a centimeter scale. As MoI2 can be used to form Mo6S3I6 through a gas-phase reaction, a larger amount of single crystals can be synthesized; moreover, these crystals are significantly longer than those synthesized by using Mo, S, and I powder. The synthesized Mo6S3I6 exhibited the characteristics of paramagnetic semiconductors with excellent thermal stability and a low bandgap. Furthermore, Mo6S3I6 can be separated into long nanometer-scale chains by a solution dispersion process.
Photodynamic properties of tungsten iodide clusters incorporated into silicone: A2[M6I8L6]?silicone
Adamenko, Lyubov S.,Alekseev, Alexander Y.,Dutczak, Danuta,Enseling, David,Hummel, Thorsten,Jüstel, Thomas,Meyer, Hans-Jürgen,Mironov, Yuri V.,Shestopalov, Michael A.
, p. 22257 - 22263 (2020/07/03)
The light-induced antibacterial and antifungal properties of A2[M6I8L6] with M = Mo and W, A = organic cation, L = ligand have been studied. The photoactive compounds (TBA)2[W6I8(C7H7SO3)6] and (TBA)2[W6I8(COOCF3)6] have been incorporated into a permeable silicone matrix and were measured for their application in the decomposition of multi-resistant bioactive species (hospital germs) such asS. aureusandP. aeruginosaas well as fungi. In addition, we present a new high volume synthesis route for these types of cluster compounds departing from the soluble compound W6I22
