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14064-41-6

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14064-41-6 Usage

General Description

1-Methoxy-3-[(E)-2-phenylethenyl]benzene, also known as Anethole, is an organic compound that belongs to the class of phenylpropanoids. It is a colorless to pale yellow liquid that is found in the essential oils of anise, fennel, and star anise. Anethole is commonly used as a flavoring agent in the food and beverage industry, particularly in licorice and anise-flavored products. It also has antibacterial and antifungal properties, and is used in the pharmaceutical and cosmetic industries. Additionally, anethole has been studied for its potential medicinal properties, including anti-inflammatory, antioxidant, and cancer-fighting effects. However, it is important to note that anethole may have potential toxic effects if consumed in large quantities.

Check Digit Verification of cas no

The CAS Registry Mumber 14064-41-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,6 and 4 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 14064-41:
(7*1)+(6*4)+(5*0)+(4*6)+(3*4)+(2*4)+(1*1)=76
76 % 10 = 6
So 14064-41-6 is a valid CAS Registry Number.

14064-41-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methoxy-3-(2-phenylethenyl)benzene

1.2 Other means of identification

Product number -
Other names (E)-1-methoxy-3-stytylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14064-41-6 SDS

14064-41-6Relevant articles and documents

Rh-catalyzed reagent-free ring expansion of cyclobutenones and benzocyclobutenones

Chen, Peng-Hao,Sieber, Joshua,Senanayake, Chris H.,Dong, Guangbin

, p. 5440 - 5445 (2015)

Here we report a reagent-free rhodium-catalyzed ring-expansion reaction via C-C cleavage of cyclobutenones. A variety of poly-substituted cyclopentenones and 1-indanones can be synthesized from simple cyclobutenones and benzocyclobutenones. The reaction condition is near pH neutral without additional oxidants or reductants. The potential for developing a dynamic kinetic asymmetric transformation of this reaction has also been demonstrated. Further study supports the proposed pathway involving Rh-insertion into the cyclobutenone C-C bond, followed by β-hydrogen elimination, olefin insertion and reductive elimination.

Geometry constrained N-(5,6,7-trihydroquinolin-8-ylidene)arylaminopalladium dichloride complexes: Catalytic behavior toward methyl acrylate (MA), methyl acrylate-co-norbornene (MA-co-NB) polymerization and heck coupling

Zeng, Yanning,Mahmood, Qaiser,Liang, Tongling,Sun, Wen-Hua

, (2016)

A new pair of plladium complexes (Pd4 and Pd5) ligated with constrained N-(5,6,7-trihydroquinolin-8-ylidene)arylamine ligands have been prepared and well characterized by 1H-, 13C-NMR and FTIR spectroscopies as well as elemental analysis. The molecular structure of Pd4 and Pd5 in solid state have also been determined by X-ray diffraction, showing slightly distorted square planar geometry around the palladium metal center. All complexes Pd1-Pd5 are revealed highly efficient catalyst in methyl acrylate (MA) polymerization as well as methyl acrylate/norbornene (MA/NB) copolymerization. In the case of MA polymerization, as high as 98.4% conversion with high molecular weight up to 6282 kg·mol-1 was achieved. Likewise, Pd3 complex has good capability to incorporate about 18% NB content into MA polymer chains. Furthermore, low catalyst loadings (0.002 mol %) of Pd4 or Pd5 are able to efficiently mediate the coupling of haloarenes with styrene affording up to 98% conversion.

Catalytic application of zwitterionic palladium complexes in Mizoroki-Heck reactions using ionic liquid as solvent

Wang, Yi-Ping,Lee, Hon Man

, p. 90 - 98 (2015)

New ligand precursors with different pendent alky chain length were obtained in a single step by reacting appropriate 1-alkyl-2-methyl-1H-imidazoles with chloroacetone in THF at 80°C overnight. Zwitterionic palladium complexes were prepared by reacting Pd

Synthesis of N-Heterocyclic Carbine Silver(I) and Palladium(II) Complexes with Acylated Piperazine Linker and Catalytic Activity in Three Types of C—C Coupling Reactions

Liu, Qingxiang,Zhang, Xiantao,Zhao, Zhixiang,Li, Xinying,Zhang, Wei

supporting information, p. 605 - 613 (2021/02/01)

Two bis-imidazolium salts LH2·Cl2 and LH2·(PF6)2 with acylated piperazine linker and two N-heterocyclic carbene (NHC) silver(I) and palladium(II) complexes [L2Ag2](PF6)2 (1) and [L2Pd2Cl4] (2) were prepared. The crystal structures of LH2·Cl2 and 1 were confirmed by X-ray analysis. In 1, one 26-membered macrometallocycle was generated through two silver(I) ions and two bidentate ligands L. The catalytic activity of 2 was investigated in Sonogashira, Heck-Mizoroki and Suzuki-Miyaura reactions. The results displayed that these C—C coupling reactions can be smoothly carried out under the catalysis of 2.

Stereospecific Iron-Catalyzed Carbon (sp2)-Carbon (sp2) Cross-Coupling of Aryllithium with Vinyl Halides

Chen, Peng,Peng, Xiao-Shui,Wang, Zhi-Yong,Wong, Henry N. C.

supporting information, p. 4385 - 4390 (2021/06/27)

We present herein an efficient synthetic protocol involving iron-catalyzed cross-coupling of organolithium compounds with vinyl halides as key coupling partners. More than 30 examples were obtained with moderate to good yields and high stereoselectivities. The practicality of this method is evidenced by a gram-scale synthesis. In addition, a preliminary mechanistic investigation was also performed.

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