141377-58-4Relevant articles and documents
Synthesis of unsaturated silyl nitronates via the silylation of conjugated nitroalkenes
Khotyantseva, Elizaveta A.,Tabolin, Andrey A.,Novikov, Roman A.,Nelyubina, Yulia V.,Ioffe, Sema L.
supporting information, p. 3128 - 3131 (2018/07/13)
A new method for the synthesis of conjugated silyl nitronates from nitroalkenes is described. The procedure has wide substrate scope and is compatible with in situ generation of the substrates from 2-nitroalcohols or 2-chloro-nitroalkanes. A cascade transformation to give 3,4,5,6-tetrahydropyridine N-oxide derivatives was disclosed.
Preparation of Nd/Na heterogeneous catalyst from bench-stable and inexpensive Nd salt for an anti-selective catalytic asymmetric nitroaldol reaction
Nonoyama, Akihito,Hashimoto, Kazuki,Saito, Akira,Kumagai, Naoya,Shibasaki, Masakatsu
supporting information, p. 1815 - 1819 (2016/04/05)
A Nd/Na heterobimetallic complex prepared from an amide-based chiral ligand, Nd alkoxide, and NaHMDS is a highly efficient heterogeneous catalyst for an anti-selective catalytic asymmetric nitroaldol reaction. Nd alkoxide is sensitive to moisture, expensi
Syn- and enantioselective henry reactions of aliphatic aldehydes and application to the synthesis of safingol
Qin, Dan-Dan,Yu, Wen,Zhou, Jie-Dan,Zhang, Yan-Cheng,Ruan, Yuan-Ping,Zhou, Zhao-Hui,Chen, Hong-Bin
supporting information, p. 16541 - 16544 (2014/01/17)
An amino alcohol copper(II) catalyst was developed for syn- and enantioselective Henry reaction of aliphatic aldehydes. Nitroethane or 2-nitroethanol and aliphatic aldehyde were sequentially added to a solution of Cu(OAc)2 H2O and li
