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14447-34-8

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14447-34-8 Usage

General Description

2-Cyclohexenyl acetate is a chemical compound with the molecular formula C8H12O2. It is a colorless liquid with a sweet, fruity odor and is commonly used as a flavor and fragrance additive in various products. It is a natural constituent of a variety of fruits, such as apple, peach, and strawberry, and is also found in essential oils. 2-Cyclohexenyl acetate is produced synthetically for use in perfumes, cosmetics, and food products. It is considered to be safe for use in these applications and is regulated by various authorities to ensure its safety and quality.

Check Digit Verification of cas no

The CAS Registry Mumber 14447-34-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,4,4 and 7 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14447-34:
(7*1)+(6*4)+(5*4)+(4*4)+(3*7)+(2*3)+(1*4)=98
98 % 10 = 8
So 14447-34-8 is a valid CAS Registry Number.

14447-34-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohex-2-en-1-yl acetate

1.2 Other means of identification

Product number -
Other names ZLD0689

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14447-34-8 SDS

14447-34-8Relevant articles and documents

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Waters

, p. 1805,1806 (1939)

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Generation and Reactivity of the Acetylacetonyl Radical

Chow, Yuan L.,Buono-Core, Gonzalo E.

, p. 3770 - 3771 (1982)

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SUPRAphos-based palladium catalysts for the kinetic resolution of racemic cyclohexenyl acetate

Jiang, Xiao-Bin,Van Leeuwen, Piet W. N. M.,Reek, Joost N. H.

, p. 2287 - 2289 (2007)

High-throughput screening of the SUPRAphos library revealed a palladium catalyst based on supramolecular ligands that gave fast and highly efficient kinetic resolution of cyclohexenyl acetate with an S-value up to 12. The Royal Society of Chemistry.

PALLADIUM-CATALYZED ASYMMETRIC COUPLING REACTIONS BETWEEN ALLYLIC ACETATES AND ORGANOZINC REAGENTS. MECHANISTIC IMPLICATIONS

Fiaud, Jean-Claude,Aribi-Zouioueche, Louisa

, p. 383 - 388 (1985)

Asymmetric induction and deuterium distribution studies have provided information about the mechanism of the palladium-catalyzed coupling reaction between allylic acetates and phenylzinc chloride, namely the presence of a symmetric η3-allylic ligand in the inetrmediate, probably along with a monodentate phosphine ligand.

Onopchenko,Schulz

, p. 3338,3339-3343 (1975)

Palladium-catalyzed deracemization of allylic carbonates in water with formation of allylic alcohols: Hydrogen carbonate ion as nucleophile in the palladium-catalyzed allylic substitution and kinetic resolution

Luessem, Bernhard J.,Gais, Hans-Joachim

, p. 6066 - 6067 (2003)

The palladium-catalyzed deracemization of racemic cyclic and acyclic allylic methyl carbonates in water in the presence of N,N′-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphophino)benzamide] proceeds with high enantioselectivities to give the corresponding allylic alcohols in high yields. This deracemization involves a palladium-catalyzed allylic substitution with the in-situ-formed hydrogen carbonate ion and an irreversible decomposition of the intermediate allylic hydrogen carbonates, with formation of the corresponding allylic alcohols. The palladium-catalyzed reaction of racemic cyclic allylic acetates with potassium hydrogen carbonate in water in the presence of the chiral bisphosphane proceeds with a highly selective kinetic resolution to give the corresponding allylic alcohols and allylic acetates. Copyright

A further step to sustainable palladium catalyzed oxidation: Allylic oxidation of alkenes in green solvents

dos Santos Costa, Maíra,de Camargo Faria, Amanda,Mota, Rayssa L.V.,Gusevskaya, Elena V.

, (2021/09/14)

The palladium catalyzed oxidation of alkenes with molecular oxygen is a synthetically important reaction which employs palladium catalysts in solution; therefore, a solvent plays a critical role for the process. In this study, we have tested several green solvents as a reaction medium for the allylic oxidation of a series of alkenes. Dimethylcarbonate, methyl isobutyl ketone, and propylene carbonate, solvents with impressive sustainability ranks and very scarcely exploited in palladium catalyzed oxidations, were proved to be excellent alternatives for the solvents conventionally employed in these processes, such as acetic acid. Palladium acetate alone or in the combination with p-benzoquinone efficiently operates as the catalyst for the oxidation of alkenes by dioxygen under 5–10 atm. For most substrates, the systems in green solvents showed better selectivity for allylic oxidation products as compared to pure acetic acid; moreover, the reactions in propylene carbonate solutions occurred even faster than in acetic acid.

CHOLINE METABOLISM INHIBITORS

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Page/Page column 50; 102-103, (2020/07/05)

The present disclosure relates to compounds, compositions and methods for inhibiting choline metabolism, e.g., conversion of choline to trimethylamine. Disclosed herein are compounds, compositions, and methods for inhibiting choline metabolism, e.g., conversion of choline to TMA. Also disclosed herein are compounds, methods and compositions for inhibiting choline metabolism by gut microbiota resulting in reduction in the formation of trimethylamine (TMA) and trimethylamine N-oxide (TMAO).

The Allylic Acetoxylation of 1,1-Disubstituted Alkenes Catalyzed by a Palladium(II)/Monothiadiazole Ligand System

Jin, Can,Li, Xiaohan,Sun, Bin,Wang, Jiayang,Yang, Jin,Yu, Chuangming,Zhang, Xun,Zhuang, Xiaohui

supporting information, p. 1479 - 1483 (2019/07/15)

A palladium(II)/monothiadiazole ligand catalytic system and its application in catalyzing the acetoxylation of 1,1-disubstituted alkenes have been developed. With this newly designed monothiadiazole thioether ligand, the reaction showed a broad scope with respect to 1,1-disubstituted olefins, giving the corresponding products in yields of 30-86percent.

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