14611-34-8

• 

• Basic information

  1. Product Name: Z-ARG(Z)2-OH
  2. Synonyms: N-ALPHA,N-OMEGA,N-OMEGA'-TRIS-Z-L-ARGININE;N-ALPHA,N-OMEGA1,N-OMEGA2-TRI CARBOBENZOXY-L-ARGININE;N-ALPHA ,N-OMEGA1,N-OMEGA2-TRI CARBOBENZOXY-L-ARGININE SODIUM SALT;N-ALPHA,NG,NG-TRI-CBZ-L-ARGININE;N-ALPHA,N-DELTA,N-OMEGA-TRIBENZYLOXYCARBONYL-L-ARGININE;N-ALPHA,N-DELTA,N-OMEGA-TRI-Z-L-ARGININE;Z-L-ARG(Z2)-OH;Z-ARG(DI-Z)-OH
  3. CAS NO:14611-34-8
  4. Molecular Formula: C₃₀H₃₂N₄O₈
  5. Molecular Weight: 576.6
  6. EINECS: 238-647-8
  7. Product Categories: Z-Amino Acids and Derivatives;Amino Acids;Amino Acids (N-Protected);Biochemistry;Cbz-Amino Acids;Z-Amino acid series
  8. Mol File: 14611-34-8.mol
  9. Article Data: 4

• Chemical Properties

  1. Melting Point: 137-140°C
  2. Boiling Point: °Cat760mmHg
  3. Flash Point: °C
  4. Appearance: /Solid
  5. Density: 1.27 g/cm3
  6. Refractive Index: 1.595
  7. Storage Temp.: -15°C
  8. Solubility: almost transparency in hot Methanol
  9. PKA: 3.94±0.21(Predicted)
  10. CAS DataBase Reference: Z-ARG(Z)2-OH(CAS DataBase Reference)
  11. NIST Chemistry Reference: Z-ARG(Z)2-OH(14611-34-8)
  12. EPA Substance Registry System: Z-ARG(Z)2-OH(14611-34-8)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 14611-34-8(Hazardous Substances Data)

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• SDS
• Upstream product
• Downstream Products
• Article

14611-34-8 Suppliers

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• Tris(carbobenzoxy)-L-arginine Manufacturer/High quality/Best price/In stock

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• USD $ 3.0-3.0 / Kilogram

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• Tris(carbobenzoxy)-L-arginine

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• Henan Tianfu Chemical Co., Ltd.
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• Pharmaceutical Grade CAS 14611-34-8 with competitive price

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• 2-Oxa-4,6,11-triazadodecan-12-oicacid, 10-carboxy-5-imino-3-oxo-1-phenyl-6-[(phenylmethoxy)carbonyl]-,12-(phenylmethyl) ester, (10S)-

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• Cbz-Arg-Arg(Cbz)2-OH cas no.14611-34-8 0.98

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14611-34-8 Usage

Chemical Properties

White to off-white powder

Uses

Tris(carbobenzoxy)-L-arginine is a protected L-argenine derivative used in the preparation of synthetic peptides and amides, such as argiopine.

Check Digit Verification of cas no

The CAS Registry Mumber 14611-34-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,6,1 and 1 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14611-34:
(7*1)+(6*4)+(5*6)+(4*1)+(3*1)+(2*3)+(1*4)=78
78 % 10 = 8
So 14611-34-8 is a valid CAS Registry Number.

InChI:InChI=1/C30H32N4O8/c31-27(33-29(38)41-20-23-13-6-2-7-14-23)34(30(39)42-21-24-15-8-3-9-16-24)18-10-17-25(26(35)36)32-28(37)40-19-22-11-4-1-5-12-22/h1-9,11-16,25H,10,17-21H2,(H,32,37)(H,35,36)(H2,31,33,38)/t25-/m0/s1

14611-34-8 Well-known Company Product Price

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• TCI America

• (T0755)  Tris(carbobenzoxy)-L-arginine  >98.0%(HPLC)

• 14611-34-8

• 1g

• 590.00CNY

• Detail

• Alfa Aesar

• (H63621)  Nalpha,Ndelta,Nomega-Tris(benzyloxycarbonyl)-L-arginine, 95%   

• 14611-34-8

• 1g

• 377.0CNY

• Detail

• Alfa Aesar

• (H63621)  Nalpha,Ndelta,Nomega-Tris(benzyloxycarbonyl)-L-arginine, 95%   

• 14611-34-8

• 5g

• 1509.0CNY

• Detail

14611-34-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name	Z-ARG(Z)2-OH

1.2 Other means of identification

Product number	-
Other names	Cbz-Arg(Z)2-OH

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14611-34-8 SDS

14611-34-8Upstream product

• 74-79-3 L-arginine 
• 13795-28-3 benzylpentachlorophenyl carbonate 
• 1234-35-1 Z-Arg-OH 
• 501-53-1 benzyl chloroformate 

14611-34-8Downstream Products

• 102249-12-7 N^α,N^G,N^G-tribenzyloxycarbonylarginylalanine p-nitrobenzyl ester 
• 79220-26-1 N-(N^α,N^δ,N^ω-tris-benzyloxycarbonyl-L-arginyl)-L-alanine benzyl ester 
• 1549810-59-4 C₃₉H₃₈N₆O₇ 
• 1549810-55-0 C₄₀H₃₉N₅O₇ 
• 1549810-51-6 C₃₆H₃₇N₅O₇ 
• 1432584-84-3 (S,Z)-N-((S)-2-(((benzyloxy)carbonyl)amino)-5-(1,3-bis((benzyloxy)carbonyl)guanidino)pentylidene)-1-(tertbutoxy)-1-oxopropan-2-amine oxide 
• 1432584-85-4 (10S,13S)-tert-butyl 6-((benzyloxy)carbonyl)-10-(((benzyloxy)carbonyl)amino)-5-imino-13-methyl-3,11-dioxo-1-phenyl-2-oxa-4,6,12-triazatetradecan-14-oate 
• 151012-20-3 C₃₂H₃₇N₅O₈ 
• 1246677-11-1 5'-(N-α,δ,ω-tri-Z-L-arginyl)-C-(2'-deoxy-β-D-ribofuranosyl-1')-N-[3-(2-acetylaminothiazole-4-yl)phenyl]carboxamide 
• 1246677-12-2 3',5'-di-(N-α,δ,ω-tri-Z-L-arginyl)-C-(2'-deoxy-β-D-ribofuranosyl-1')-N-[3-(2-acetylaminothiazole-4-yl)phenyl]carboxamide 
• 1201651-38-8 C₃₉H₄₆N₈O₇ 
• 1160927-35-4 C₄₂H₅₂N₆O₁₁ 
• 1083006-04-5 C₉₁H₁₃₄N₁₀O₁₄ 
• 1101849-73-3 C₆₈H₇₀N₁₀O₁₅ 

14611-34-8Relevant articles and documents

The total large-scale synthesis of argiopine

Formanovsky,Popova,Mikhura

experimental part, p. 752 - 758 (2010/07/15)

The total large-scale synthesis of a natural toxin argiopine, a polymethylenepolyamine derivative, was developed. It consisted of 26 stages and included three key block schemes. Most of the stages proceeded quantitatively, which excluded the necessity of using the chromatographic separation of intermediates.

A One-Pot N-Protection of L-Arginine.

Jetten, Mieke,Peters, Co A. M.,Nispen, Jan W. F. M. van,Ottenheijm, Harry C. J.

, p. 6025 - 6028 (2007/10/02)

A facile, one-pot synthesis of Nα-t-Butyloxycarbonyl,Nδ,Nω-di-benzyloxycarbonyl-L-Arginine (3a) and Nα,Nδ,Nω-tri-benzyloxycarbonyl-L-Arginine (3b) is reported.Nα-t-Butyloxycarbonyl-L-Arginine (1b) is treated with trimethylsilylchloride and the tri-silylated intermediate 2c is subsequently allowed to react with benzyloxycarbonyl chloroformate to give 3a in 50percent overall yield.Starting from 1a or 1c, 3b was prepared according to the same procedure in 72percent and 60-85percent yield, respectively.

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