146300-62-1Relevant articles and documents
Selective lipase-catalyzed acylation of epimeric α-sulfinyl alcohols: An efficient method of separation
Medio-Simon, Mercedes,Gil, Jesus,Aleman, Pedro,Varea, Teresa,Asensio, Gregorio
, p. 561 - 566 (1999)
A facile and efficient separation of mixtures of epimeric α-sulfinyl alcohols 2:3 can be accomplished by selective lipase-catalyzed acylation with neat vinyl acetate. Pseudomonas cepacia and Candida rugosa lipase showed opposite epimer differentiation in
Preparation of enantiomerically pure sulfoxides from lactic acid and 3-hydroxybutyric acid. Isopropenyl tolyl sulfoxide and 2-(phenylsulfinyl)acrylate
Breitschuh,Seebach
, p. 1170 - 1178 (2007/10/02)
The EPC-synthesis of sulfoxides from readily available starting materials ('chiral pool') is demonstrated for the first time. Cyclic and open-chain thioethers derived from lactic and 3-hydroxybutyric acid are oxidized to sulfoxides, and the resulting prod