146387-13-5

• 

• Basic information

  1. Product Name: N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE
  2. Synonyms: N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE
  3. CAS NO:146387-13-5
  4. Molecular Formula: C₁₇H₂₅NO₃S
  5. Molecular Weight: 323.4503
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 146387-13-5.mol
  9. Article Data: 2

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 451.2°C at 760 mmHg
  3. Flash Point: 226.7°C
  4. Appearance: /
  5. Density: 1.24g/cm³
  6. Vapor Pressure: 6.27E-09mmHg at 25°C
  7. Refractive Index: 1.589
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. PKA: 11.52±0.70(Predicted)
  11. CAS DataBase Reference: N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE(CAS DataBase Reference)
  12. NIST Chemistry Reference: N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE(146387-13-5)
  13. EPA Substance Registry System: N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE(146387-13-5)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 146387-13-5(Hazardous Substances Data)

• Suppliers
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• SDS
• Upstream product
• Downstream Products
• Article

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• N-(3-HYDROXY-4,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL)-4-METHYL-BENZENESULFONAMIDE

  Cas No: 146387-13-5

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146387-13-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 146387-13-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,6,3,8 and 7 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 146387-13:
(8*1)+(7*4)+(6*6)+(5*3)+(4*8)+(3*7)+(2*1)+(1*3)=145
145 % 10 = 5
So 146387-13-5 is a valid CAS Registry Number.

InChI:InChI=1/C17H25NO3S/c1-11-5-7-12(8-6-11)22(20,21)18-14-13-9-10-17(4,15(14)19)16(13,2)3/h5-8,13-15,18-19H,9-10H2,1-4H3

146387-13-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	N-(3-hydroxy-4,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)-4-methylbenzenesulfonamide

1.2 Other means of identification

Product number	-
Other names	Benzenesulfonamide,N-[(1S,2R,3S,4R)-3-hydroxy-4,7,7-trimethylbicyclo[2.2.1]hept-2-yl]-4-methyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:146387-13-5 SDS

146387-13-5Upstream product

• 41719-73-7 (2S)-3-exo-aminoisoborneol 
• 98-59-9 p-toluenesulfonyl chloride 

146387-13-5Downstream Products

• 211869-54-4 (1R,2S,6R,7S)-4-Allyl-1,10,10-trimethyl-5-(toluene-4-sulfonyl)-3-oxa-5-aza-4-bora-tricyclo[5.2.1.0^2,6]decane 
• 146311-08-2 (S)-Hydroxy-phenyl-acetic acid (1R,2S,3R,4S)-1,7,7-trimethyl-3-(toluene-4-sulfonylamino)-bicyclo[2.2.1]hept-2-yl ester 
• 146311-02-6 2-Oxo-propionic acid (1R,2S,3R,4S)-1,7,7-trimethyl-3-(toluene-4-sulfonylamino)-bicyclo[2.2.1]hept-2-yl ester 

146387-13-5Relevant articles and documents

Enantioselective synthesis of optically active homoallylamines by nucleophilic addition of chirally modified allylboranes to N-silylimines

Itsuno, Shinichi,Watanabe, Katsuhiro,Matsumoto, Takeshi,Kuroda, Shizuc,Yokoi, Ayako,El-Shehawy, Ashraf

, p. 2011 - 2016 (2007/10/03)

Enantioselectivity in the allylboration of W-silylimines with a variety of chirally modified allylboron reagents has been examined. Optically active N-sulfonylarhino alcohols (16,17 and 19) derived from D-camphor and norephedrine were found to be efficient chiral ligands for the allylboration reagent. These reagents smoothly reacted with Ar-silylimines to give the corresponding homoallylic amines in a high level of enantioselectivity up to 96% ee.

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