146848-68-2Relevant articles and documents
Enantioselective Mukaiyama-Michael Reaction of Cyclic α-Alkylidene β-Keto Phosphine Oxide and Phosphonate and Asymmetric Synthesis of (R)-Homosarkomycin
Nagatani, Kotaro,Minami, Atsushi,Tezuka, Haruka,Hoshino, Yunosuke,Nakada, Masahisa
, p. 810 - 813 (2017)
The asymmetric Mukaiyama-Michael reaction of cyclic α-alkylidene β-oxo phosphates and phosphine oxides that proceeds in a highly enantioselective manner is described. It is possible to carry out these reactions using a catalytic amount of a bisoxazoline-Cu(II) complex without decreasing the enantioselectivity, and one of the products has been successfully used for the first enantioselective synthesis of (R)-homosarkomycin.
Efficient regiocontrolled synthesis of sarkomycin and homosarkomycin
Wexler,Toder,Minaskanian,Smith III
, p. 3333 - 3335 (2007/10/02)
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