14737-09-8

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• Basic information

  1. Product Name: 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE
  2. Synonyms: 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE;1-Bromo-2-(bromodifluoromethyl)cyclohexane 97%;1-Bromo-2-(bromodifluoromethyl)cyclohexane97%
  3. CAS NO:14737-09-8
  4. Molecular Formula: C₇H₁₀Br₂F₂
  5. Molecular Weight: 291.96
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 14737-09-8.mol
  9. Article Data: 3

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 108 °C
  3. Flash Point: 92.2 °C
  4. Appearance: Clear colorless liquid
  5. Density: 1.806 g/cm³
  6. Vapor Pressure: 2.96E-08mmHg at 25°C
  7. Refractive Index: 1.589
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE(CAS DataBase Reference)
  11. NIST Chemistry Reference: 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE(14737-09-8)
  12. EPA Substance Registry System: 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE(14737-09-8)

• Safety Data

  1. Hazard Codes: Xi
  2. Statements: 36/37/38
  3. Safety Statements: 26-36
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 14737-09-8(Hazardous Substances Data)

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• 1-bromo-2-(bromodifluoromethyl)cyclohexane

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• 1-Bromo-2-(Bromodifluoromethyl)Cyclohexane

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• 1-Bromo-2-(Bromodifluoromethyl)Cyclohexane CAS No.14737-09-8

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14737-09-8 Usage

General Description

1-Bromo-2-(bromodifluoromethyl)cyclohexane is a chemical compound with the molecular formula C7H8Br2F2. It is a colorless liquid that is primarily used as an intermediate in the production of pharmaceuticals and agrochemicals. It is also used as a solvent and in the synthesis of other organic compounds. It is classified as a halogenated compound, which means it contains one or more halogen atoms, in this case, bromine and fluorine. 1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE is known to be toxic if ingested and can cause skin and eye irritation upon contact. It is important to handle and store this chemical with caution to avoid any potential harm.

Check Digit Verification of cas no

The CAS Registry Mumber 14737-09-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,7,3 and 7 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 14737-09:
(7*1)+(6*4)+(5*7)+(4*3)+(3*7)+(2*0)+(1*9)=108
108 % 10 = 8
So 14737-09-8 is a valid CAS Registry Number.

InChI:InChI=1/C14H7ClF3NO/c15-10-3-1-8(2-4-10)9-5-12(14(16,17)18)11(7-19)13(20)6-9/h1-6,20H

14737-09-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name	1-Bromo-2-(bromodifluoromethyl)-cyclohexane

1.2 Other means of identification

Product number	-
Other names	1-BROMO-2-(BROMODIFLUOROMETHYL)CYCLOHEXANE

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14737-09-8 SDS

14737-09-8Upstream product

• 75-61-6 dibromodifluoromethane 
• 110-83-8 cyclohexene 

14737-09-8Downstream Products

• 117711-60-1 1-(bromodifluoromethyl)cyclohex-1-ene 
• 134134-66-0 (bromodifluoromethyl)cyclohexane 
• 134134-69-3 cis-1-(difluoromethyl)-2-bromocyclohexane 
• 134134-69-3 trans-1-(difluoromethyl)-2-bromocyclohexane 
• 636-82-8 cyclohexene-1-carboxylic acid 
• 117711-62-3 cyclohex-1-enecarbonyl fluoride 
• 117711-61-2 3-Difluoromethylene-cyclohexene 
• 329-29-3 cyclohexylmethylene difluoride 

14737-09-8Relevant articles and documents

Mechanistic Studies on Zinc-Induced Addition of CF2Br2 to Olefins. A Novel Radical Reductive Cyclopropanation on the Zinc Surface

Wu, Shi-Hui,Liu, Wei-Zhong,Jiang, Xi-Kui

, p. 854 - 857 (1994)

The addition reaction of dibromodifluoromethane (1) to olefins induced by zinc in ethereal solvent differs surprisingly from addition reactions hitherto reported.Both cyclopropane derivatives and 1:1 addition products were obtained from this reaction.A free-radical chain addition reaction induced by single electron transfer (SET) is proposed.This reaction is inhibited by hydroquinone and completely quenched by p-dinitrobenzene.The nature of the 1:1 adducts formed revealed the character of a typical radical reaction.The nature of the cyclopropane derivatives formed was also much different from the usual cyclopropane adduct derived from carbene addition.When diallyl ether (15) and norbornadiene (16) were used as substrates, only rearranged 1:1 addition products could be obtained, and no cyclopropane product could be detected.The results of addition reactions with 4-octenes (27) showed also that the cyclopropanation reaction was not stereospecific.On the basis of the above-mentioned results, a novel reductive debromocyclopropanation reaction of the γ-bromopropyl radical intermediate proceeding on the zinc metal surface is suggested.

Difluoromethylation of Alkenes via Borohydride Reduction of 1,3-Dibromo-1,1-difluoroalkanes

Gonzales, Javier,Foti, Christopher J.,Elsheimer, Seth

, p. 4322 - 4325 (2007/10/02)

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