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15004-86-1

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  • Rhodium(3+),tris(1,2-ethanediamine-kN,kN')-, trichloride, trihydrate,(OC-6-11)- (9CI) Manufacturer/High quality/Best price/In stock

    Cas No: 15004-86-1

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15004-86-1 Usage

Uses

Used as precursor for supported RH catalyst.

Check Digit Verification of cas no

The CAS Registry Mumber 15004-86-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,0,0 and 4 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 15004-86:
(7*1)+(6*5)+(5*0)+(4*0)+(3*4)+(2*8)+(1*6)=71
71 % 10 = 1
So 15004-86-1 is a valid CAS Registry Number.
InChI:InChI=1/3C2H8N2.3ClH.3H2O.Rh/c3*3-1-2-4;;;;;;;/h3*1-4H2;3*1H;3*1H2;/q;;;;;;;;;+3/p-3

15004-86-1 Well-known Company Product Price

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  • Alfa Aesar

  • (10553)  Tris(ethylenediamine)rhodium(III) chloride trihydrate, Rh 23.2%   

  • 15004-86-1

  • 0.5g

  • 792.0CNY

  • Detail
  • Alfa Aesar

  • (10553)  Tris(ethylenediamine)rhodium(III) chloride trihydrate, Rh 23.2%   

  • 15004-86-1

  • 1g

  • 2272.0CNY

  • Detail
  • Alfa Aesar

  • (10553)  Tris(ethylenediamine)rhodium(III) chloride trihydrate, Rh 23.2%   

  • 15004-86-1

  • 5g

  • 8933.0CNY

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  • Aldrich

  • (323500)  Trichlorotris(ethylenediamine)rhodium(III)trihydrate  ≥99.9%

  • 15004-86-1

  • 323500-500MG

  • 2,021.76CNY

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15004-86-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Tris(ethylenediamine)rhodium(III) chloride trihydrate, Rh 23.2%

1.2 Other means of identification

Product number -
Other names rhodium(III) tris(ethylenediamine) chloride trihydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15004-86-1 SDS

15004-86-1Downstream Products

15004-86-1Relevant articles and documents

Synthetically versatile (trifluoromethanesulfonato)metal amine complexes

Dixon, Nicholas E.,Lawrance, Geoffrey A.,Lay, Peter A.,Sargeson, Alan M.

, p. 2940 - 2947 (2008/10/08)

Facile synthetic routes to complexes of the labile unidentate coordinated trifluoromethanesulfonate (-OSO2CF3) ion are reported for M(NH3)5(OSO2CF3)n+ (M = Rh(III), Ir(III), Cr(III), Ru(III) where n = 2; M = Pt(IV) where n = 3), M(NH2CH3)5(OSO2CF3) 2+ (M = Co(III), Rh(III), Cr(III)), cis-M(en)2(OSO2CF3)2+ (M = Rh(III), Ir(III), Cr(III)), and trans-M(en)2Cl(OSO2CF3)+ (M = Rh(III), Ir(III)). The utility of these synthetically versatile intermediates in the preparation of a variety of complexes containing neutral ligands is illustrated. Rate constants for the aquation of the triflato complexes in 0.1 M CF3SO3H at 25°C span 3 orders of magnitude and for the pentaammine complexes show a reactivity order of Ru(III) > Co(III) ~ Cr(III) ~ Rh(III) ? Ir(III) ? Pt(IV). For the pentakis(methylamine) complexes, the aquation rate is greater for Co(III), slightly greater for Rh(III), and smaller for Cr(III) in comparison to the corresponding pentaammine complexes. The aquations of M(en)2X(OSO2CF3)+ proceed largely without isomerization (2(OSO2CF3)2+ ions, consecutive first-order aquation processes are observed with rate constants k1 ~ 2k2.

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