1536-78-3Relevant articles and documents
Catalytic oxidation of hydrocarbons of natural and oil gas
Chepaikin,Bezruchenko,Menchikova,Moiseeva,Gekhman
experimental part, p. 332 - 337 (2011/04/26)
Alkane oxidation by O2 and CO in the presence of Rh-, Pd-, and Pt-containing catalytic systems leads to the product of C-H bond oxidation and the products of C-C bond oxidative destruction. A deuterated methyl group in acetic acid is observed in the oxidation of n-propane in a deuterium-donor medium. The possible mechanisms of alkane C2-C4 conversion are proposed.
Toluene-p-sulfonic Acid-catalysed Reaction of But-1-ene with Trifluoroacetic Acid: Return and Elimination from the Intimate Ion Pair
Farcasiu, Dan
, p. 2611 - 2612 (2007/10/02)
At short times, reaction of but-1-ene with toluene-p-sulfonic acid in trifluoroacetic acid gives 2-butyl tosylate 1, 2-butyl trifluoroacetate 2 and but-2-ene 3 in ratios of (>=)2.3:1:(>=)0.41; thus internal return is the major pathway and elimination is important for the tight 2-butyl cation-tosylate anion pair.
