15391-24-9 Usage
Description
BIS(SALICYLIDENIMINATO-3-PROPYL)METHYLAMINOCOBALT(II) is a complex cobalt-based compound with a Schiff base structure, characterized by its unique coordination chemistry and catalytic properties. It is derived from the combination of salicylideneimine ligands and a methylamino group, which together form a stable complex with cobalt(II). BIS(SALICYLIDENIMINATO-3-PROPYL)METHYLAMINOCOBALT(II) exhibits versatile catalytic activities and has potential applications in various chemical reactions and industries.
Uses
Used in Chemical Synthesis:
BIS(SALICYLIDENIMINATO-3-PROPYL)METHYLAMINOCOBALT(II) is used as a catalyst for the biomimetic coupled catalytic system, facilitating the cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics. This application is particularly relevant in the synthesis of various organic compounds and pharmaceuticals, where selective oxidation reactions are crucial.
Used in Allylation, Oxidation, and Oxidative Cleavages:
In the field of organic chemistry, BIS(SALICYLIDENIMINATO-3-PROPYL)METHYLAMINOCOBALT(II) is employed as a catalyst for allylation, oxidation, and oxidative cleavages. Its ability to selectively promote these reactions contributes to the synthesis of complex organic molecules and the development of novel chemical compounds.
Used in Oxidative Carbonylation of Phenol:
BIS(SALICYLIDENIMINATO-3-PROPYL)METHYLAMINOCOBALT(II) is used as a catalyst in the oxidative carbonylation of phenol, a process that is essential for the production of various phenolic compounds and their derivatives. This application is particularly important in the chemical and pharmaceutical industries, where phenolic compounds are widely used as building blocks for the synthesis of various products.
Check Digit Verification of cas no
The CAS Registry Mumber 15391-24-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,3,9 and 1 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 15391-24:
(7*1)+(6*5)+(5*3)+(4*9)+(3*1)+(2*2)+(1*4)=99
99 % 10 = 9
So 15391-24-9 is a valid CAS Registry Number.
InChI:InChI=1/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,22-23H,6-7,12-15H2,1H3;/b18-16-,19-17-;
15391-24-9Relevant articles and documents
Niswander, R. H.,Taylor, L. T.
, p. L7 - L8 (1976)
STERIC AND ELECTRONIC EFFECTS OF LIGAND VARIATION ON COBALT DIOXYGEN CATALYSTS
Corden, Barry B.,Drago, Russel S.,Perito, Richard P.
, p. 2903 - 2907 (2007/10/02)
We report herein the observation that electronic and steric factors of cobalt dioxygen complexes with systematically derivatized pentadentate Schiff-base ligands affects their ability to catalyze the oxidation of sustituted phenols and alter the rate of catalyst decomposition.The electronic and steric factors can be separated sufficiently to indicate that the activity of the cobalt dioxygen catalyst roughly parallels the trends in basicity of the bound O2 suggested by EPR cobalt hyperfine coupling constants of the adducts and predicted from the electronic effects of substituents.
