1564-99-4Relevant articles and documents
Dark singlet oxygenation of β-citronellol: A key step in the manufacture of rose oxide
Alsters, Paul L.,Jary, Walther,Nardello-Rataj, Veronique,Aubry, Jean-Marie
, p. 259 - 262 (2010)
We describe the development of a scalable process for the "dark" singlet oxygenation of β-citronellol as a key step in the manufacture of the fragrance compound, rose oxide. This process, based on catalytic disproportionation of hydrogen peroxide into singlet oxygen and water, has been carried out on production scale in 10 m3 reactors.
Unusual Oxidative Dealkylation Strategy toward Functionalized Phenalenones as Singlet Oxygen Photosensitizers and Photophysical Studies
De Bonfils, Paul,Verron, Elise,Sandoval-Altamirano, Catalina,Jaque, Pablo,Moreau, Xavier,Gunther, German,Nun, Pierrick,Coeffard, Vincent
, p. 10603 - 10616 (2020/09/23)
A series of functionalized 6-alkoxy phenalenones was prepared through an unprecedented oxidative dealkylation of readily available phenalene precursors. The starting phenalenes were efficiently synthesized via an aminocatalyzed annulation/O-alkylation str
Highly efficient continuous flow reactions using singlet oxygen as a "Green" reagent
Levesque, Francois,Seeberger, Peter H.
supporting information; experimental part, p. 5008 - 5011 (2011/12/04)
Described is a new method for the efficient in situ production of singlet oxygen in a simple continuous flow photochemical reactor. The extremely large interfacial area generated by running the biphasic mixture in a narrow channel at a high flow rate ensures high throughput as well as fast and efficient oxidation of various alkenes, 1,3-dienes, and thioethers on a preparative scale.
