15831-62-6Relevant articles and documents
Enantioselective preparation of N-chirogenic tertiary amine oxides
Suzuki, Ichiro,Kerakawauchi, Ran,Hirokawa, Takako,Takeda, Kei
, p. 6873 - 6876 (2008/02/12)
We found that PLE can be used as an efficient catalyst for desymmetrization of prochiral tertiary amine N-oxides and demonstrated that they were hydrolyzed by PLE efficiently to afford N-chirogenic tertiary amine oxides up to 99% ee in moderate to good yields.
A mild and efficient cyanosilylation of ketones using in situ generated n-oxides-ti(iPrO)4 complexes as catalysts
Shen, Yongcun,Feng, Xiaoming,Li, Yan,Zhang, Guolin,Jiang, Yaozhong
, p. 793 - 795 (2007/10/03)
The addition of TMSCN to ketones catalyzed by complex of racemic N-(2′-pyridylmethyl)-2-diphenylhydroxymethylpyrrolidine N-oxide (rac-1) or N-benzyl-N,N-dihydroxyethylamine N-oxide and Ti(iPrO)4 affords the racemic O-TMS cyanohydrins in good to excellent isolated yields (up to 97%) under mild reaction conditions.