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1589-62-4

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1589-62-4 Usage

Chemical Properties

ORANGE TO ORANGE-BROWN CRYSTALLINE POWDER

Uses

Cyclohexanone 2,4-dinitrophenylhydrazone is a useful standard for elemental analysis. Also used as a pharmaceutical intermediate.

Check Digit Verification of cas no

The CAS Registry Mumber 1589-62-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,8 and 9 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1589-62:
(6*1)+(5*5)+(4*8)+(3*9)+(2*6)+(1*2)=104
104 % 10 = 4
So 1589-62-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H14N4O4/c17-15(18)10-6-7-11(12(8-10)16(19)20)14-13-9-4-2-1-3-5-9/h6-8,14H,1-5H2

1589-62-4 Well-known Company Product Price

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  • Price
  • Detail
  • Alfa Aesar

  • (A12203)  Cyclohexanone 2,4-dinitrophenylhydrazone, 99%   

  • 1589-62-4

  • 1g

  • 213.0CNY

  • Detail
  • Alfa Aesar

  • (A12203)  Cyclohexanone 2,4-dinitrophenylhydrazone, 99%   

  • 1589-62-4

  • 5g

  • 820.0CNY

  • Detail
  • Alfa Aesar

  • (A12203)  Cyclohexanone 2,4-dinitrophenylhydrazone, 99%   

  • 1589-62-4

  • 25g

  • 3465.0CNY

  • Detail
  • Supelco

  • (442533)  Cyclohexanone-2,4-DNPH  analytical standard

  • 1589-62-4

  • 000000000000442533

  • 441.09CNY

  • Detail

1589-62-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name Cyclohexanone-DNPH

1.2 Other means of identification

Product number -
Other names Cyclohexanone 2,4-dinitrophenylhydrazone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1589-62-4 SDS

1589-62-4Relevant articles and documents

Oxidative Dehomologation of Aldehydes with Oxygen as a Terminal Oxidant

Shipilovskikh, Sergei A.,Rubtsov, Aleksandr E.,Malkov, Andrei V.

supporting information, p. 6760 - 6762 (2017/12/26)

A mild, efficient protocol for oxidative cleavage of C-C bonds in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range.

Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: Alleviating steric and electronic constraints of Cu/TEMPO catalyst systems

Steves, Janelle E.,Stahl, Shannon S.

supporting information, p. 15742 - 15745 (2013/11/06)

Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcohols and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcohols. Here, we report a catalyst system, consisting of (MeObpy)CuI(OTf) and ABNO (MeObpy =4,4′-dimethoxy-2,2′-bipyridine; ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl), that mediates aerobic oxidation of all classes of alcohols, including primary and secondary allylic, benzylic, and aliphatic alcohols with nearly equal efficiency. The catalyst exhibits broad functional group compatibility, and most reactions are complete within 1 h at room temperature using ambient air as the source of oxidant.

Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: A convenient recyclable reagent for catalytic oxidation

Zhu, Chenjie,Yoshimura, Akira,Wei, Yunyang,Nemykin, Victor N.,Zhdankin, Viktor V.

supporting information; experimental part, p. 1438 - 1444 (2012/04/04)

Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid supported bifunctional catalysts could be simply recovered and reused.

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