1648-61-9Relevant articles and documents
Rozen,Menachem
, p. 479,480 (1979)
Stable Long-Chain Fluoroxy Compounds and Their Chemistry
Barnette, William E.,Wheland, Robert C.,Middleton, William J.,Rozen, Shlomo
, p. 3698 - 3701 (2007/10/02)
Certain alkali metal salts of long-chain perfluorinated acids were reacted with nitrogen-diluted fluorine to produce oxidative solutions.The reaction conditions can be controlled to afford mainly acyl hypofluorites (RfCOOF) or fluoroxy species fCF2OF and RfCF(OF)2> which have been identified by both chemical reactions and 19F NMR studies.These solutions are useful in electrophilic fluorination reactions and as initiators for the polimerization of some fluorinated monomers.As initiators they produce polymers with fewer reactive end groups when compared with standard methods of initiation.
TAMING ELEMENTAL FLUORINE: INDIRECT USE OF FLUORINE FOR THE SYNTHESIS OF α-FLUOROKETONES
Rozen Shlomo,Menahem, Ynon
, p. 19 - 32 (2007/10/02)
Fluorine and sodium trifloroacetate react at -75 deg to produce a variety of fluoroxy-compounds.Although it is possible to direct the reaction towards the formation of CF3COOF or CF3CF2O, mixtures may be used when only the electrophilic fluorine has to be