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16537-09-0

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16537-09-0 Usage

Synthesis Reference(s)

Synthetic Communications, 20, p. 2033, 1990 DOI: 10.1080/00397919008053134Journal of the American Chemical Society, 99, p. 4833, 1977 DOI: 10.1021/ja00456a055

Check Digit Verification of cas no

The CAS Registry Mumber 16537-09-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,5,3 and 7 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 16537-09:
(7*1)+(6*6)+(5*5)+(4*3)+(3*7)+(2*0)+(1*9)=110
110 % 10 = 0
So 16537-09-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H16O2/c1-12(2,3)14-11(13)9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3

16537-09-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl 2-phenylacetate

1.2 Other means of identification

Product number -
Other names Benzeneacetic acid,1,1-dimethylethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16537-09-0 SDS

16537-09-0Relevant articles and documents

Identification of potent and novel small-Molecule inhibitors of caspase-3

Allen, Darin A.,Pham, Phuongly,Choong, Ingrid C.,Fahr, Bruce,Burdett, Matthew T.,Lew, Willard,DeLano, Warren L.,Gordon, Eric M.,Lam, Joni W.,O'Brien, Tom,Lee, Dennis

, p. 3651 - 3655 (2003)

The design and synthesis of a series of novel, reversible, small molecule inhibitors of caspase-3 are described.

-

Millard,A.A.,Rathke,M.W.

, p. 4833 - 4835 (1977)

-

A solvent-reagent selection guide for Steglich-type esterification of carboxylic acids

Jordan, Andrew,Sneddon, Helen F.,Sydenham, Jack,Whymark, Kyran D.

supporting information, p. 6405 - 6413 (2021/09/10)

The Steglich esterification is a widely employed method for the formation of esters under mild conditions. A number of issues regarding the sustainability of this transformation have been identified, chiefly the use of hazardous carbodiimide coupling reagents in conjunction with solvents with considerable issues such as dichloromethane (DCM) and N,N-dimethylformamide (DMF). To overcome these issues, we have developed a solvent-reagent selection guide for the formation of esters via Steglich-type reactions with the aim of providing safer, more sustainable conditions. Optimum reaction conditions have been identified after high-throughput screening of solvent-reagent combinations, namely the use of Mukaiyama's reagent (Muk) in conjunction with solvent dimethyl carbonate (DMC). The new reaction conditions were also exemplified through the synthesis of a small selection of building-block like molecules and includes the formation of t-butyl esters.

Catalytic Asymmetric Darzens-Type Epoxidation of Diazoesters: Highly Enantioselective Synthesis of Trisubstituted Epoxides

Jeong, Hye-Min,Nam, Dong Guk,Ryu, Do Hyun,Shim, Su Yong

supporting information, p. 22236 - 22240 (2021/09/13)

Highly enantioselective Darzens-type epoxidation of diazoesters with glyoxal derivatives was accomplished using a chiral boron–Lewis acid catalyst, which facilitated asymmetric synthesis of trisubstituted α,β-epoxy esters. In the presence of a chiral oxazaborolidinium ion catalyst, the reaction proceeded in high yield (up to 99 %) with excellent enantio- and diastereoselectivity (up to >99 % ee and >20:1 dr, respectively). The synthetic potential of this method was illustrated by conversion of the products to various compounds such as epoxy γ-butyrolactone, tertiary β-hydroxy ketone and epoxy diester.

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E?H Bonds

Ankudinov, Nikita M.,Chusov, Denis A.,Nelyubina, Yulia V.,Perekalin, Dmitry S.

supporting information, p. 18712 - 18720 (2021/07/20)

A new method for the synthesis of chiral diene rhodium catalysts is introduced. The readily available racemic tetrafluorobenzobarrelene complexes [(R2-TFB)RhCl]2 were separated into two enantiomers via selective coordination of one of them with the auxiliary S-salicyl-oxazoline ligand. One of the resulting chiral complexes with an exceptionally bulky diene ligand [(R,R-iPr2-TFB)RhCl]2 was an efficient catalyst for the asymmetric insertion of diazoesters into B?H and Si?H bonds giving the functionalized organoboranes and silanes with high yields (79–97 %) and enantiomeric purity (87–98 % ee). The stereoselectivity of separation via auxiliary ligand and that of the catalytic reaction was predicted by DFT calculations.

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