168433-86-1Relevant articles and documents
Chemoenzymatic syntheses of naturally occurring β-glucosides
Akita, Hiroyuki,Kurashima, Katsumi,Nakamura, Takuya,Kato, Keisuke
, p. 2429 - 2439 (1999)
Enzymatic glycosidation of the various kinds of primary alcohols 5, 7, 9, 11, 13 and 15 and 4-nitrophenyl-β-D-glucopyranoside 4 using β- glucosidase from almonds gave stereoselectively β-D-glucosides 6, 8, 10, 12, 14 and 16 including the naturally occurring β-glucosides in moderate yield. Among them, the β-glucosides 6, 8 and 10 were converted to the cyanoglycosides, rhodiocyanoside A 20a, osmaronin 24a and sutherlandin 29, respectively.