1699-59-8

• 

• Basic information

  1. Product Name: 3,4-DIBENZYLOXYBENZYL CHLORIDE
  2. Synonyms: 4-(Chloromethyl)-1,2-bis(phenylmethoxy)benzene;3,4-Dibenzyloxybenzyl chloride,99%;3,4-DIBENZYLOXYBENZYL CHLORIDE;3,5-bis(benzyloxy)-alpha-chlorotoluene;3,4-DIBENZYLOXYBENZYL CHLORIDE 99%;3,4-Bis(benzyloxy)benzyl chloride
  3. CAS NO:1699-59-8
  4. Molecular Formula: C₂₁H₁₉ClO₂
  5. Molecular Weight: 338.83
  6. EINECS: 216-927-0
  7. Product Categories: Ethers;Organic Building Blocks;Oxygen Compounds
  8. Mol File: 1699-59-8.mol
  9. Article Data: 4

• Chemical Properties

  1. Melting Point: 41-43 °C(lit.)
  2. Boiling Point: 455.07°C (rough estimate)
  3. Flash Point: >230 °F
  4. Appearance: /
  5. Density: 1.0887 (rough estimate)
  6. Vapor Pressure: 5.91E-09mmHg at 25°C
  7. Refractive Index: 1.5330 (estimate)
  8. Storage Temp.: 2-8°C
  9. Solubility: N/A
  10. CAS DataBase Reference: 3,4-DIBENZYLOXYBENZYL CHLORIDE(CAS DataBase Reference)
  11. NIST Chemistry Reference: 3,4-DIBENZYLOXYBENZYL CHLORIDE(1699-59-8)
  12. EPA Substance Registry System: 3,4-DIBENZYLOXYBENZYL CHLORIDE(1699-59-8)

• Safety Data

  1. Hazard Codes: C
  2. Statements: 34-36/37
  3. Safety Statements: 26-27-28-36/37/39-45
  4. RIDADR: UN 3261 8/PG 2
  5. WGK Germany: 3
  6. RTECS:
  7. HazardClass: 8
  8. PackingGroup: III
  9. Hazardous Substances Data: 1699-59-8(Hazardous Substances Data)

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• SDS
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• Benzene,4-(chloromethyl)-1,2-bis(phenylmethoxy)-

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• Benzene,4-(chloromethyl)-1,2-bis(phenylmethoxy)-

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• 3,5-bis(benzyloxy)-α-chlorotoluene

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1699-59-8 Usage

Chemical Properties

almost white to light beige powder

Uses

3,4-Dibenzyloxybenzyl chloride was used to prepare benzylnitrile precursor, required for the synthesis of amidines.

Check Digit Verification of cas no

The CAS Registry Mumber 1699-59-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,6,9 and 9 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1699-59:
(6*1)+(5*6)+(4*9)+(3*9)+(2*5)+(1*9)=118
118 % 10 = 8
So 1699-59-8 is a valid CAS Registry Number.

InChI:InChI=1/C21H19ClO2/c22-14-19-11-12-20(23-15-17-7-3-1-4-8-17)21(13-19)24-16-18-9-5-2-6-10-18/h1-13H,14-16H2

1699-59-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name	4-(chloromethyl)-1,2-bis(phenylmethoxy)benzene

1.2 Other means of identification

Product number	-
Other names	3,4-Dibenzyloxybenzyl chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1699-59-8 SDS

1699-59-8Upstream product

• 100-39-0 benzyl bromide 
• 882427-72-7 3,4-(bisbenzyloxy)benzoic acid benzyl ester 
• 99-50-3 3,4-Dihydroxybenzoic acid 
• 139-85-5 3,4-dihydroxybenzaldehyde 
• 5447-02-9 3,4-dibenzyloxybenzaldehyde 
• 1699-58-7 3,4-bis(benzyloxy)benzyl alcohol 

1699-59-8Downstream Products

• 121102-14-5 N-<3,4-bis(benzyloxy)benzyl>ethylenediamine 
• 1699-60-1 (3,4-bis-benzyloxyphenyl)acetonitrile 
• 82071-48-5 1-(3,4-dihydroxyphenylmethyl)-4-(1,3-dihydro-2H-benzimidazol-2-one-1-yl)piperidine 
• 1422542-64-0 C₂₀H₁₇NO₄S 
• 1422542-59-3 C₂₁H₁₇NO₃ 
• 178415-79-7 (2R,4R) diethyl-4-(tert-butyloxycarbonylamino)-1-(3,4-dibenzyloxybenzyl)pyrrolidine-2,4-dicarboxylate 
• 167147-55-9 5'-[(3,4-dibenzyloxy)benzylthio]-5'-deoxythymidine 

1699-59-8Relevant articles and documents

Designing new analogs for streamlining the structure of cytotoxic lamellarin natural products

Tangdenpaisal, Kassrin,Worayuthakarn, Rattana,Karnkla, Supatra,Ploypradith, Poonsakdi,Intachote, Pakamas,Sengsai, Suchada,Saimanee, Busakorn,Ruchirawat, Somsak,Chittchang, Montakarn

, p. 925 - 937 (2015/03/31)

Despite the therapeutic potential of marine-derived lamellarin natural products, their preclinical development has been hampered by their lipophilic nature, causing very poor aqueous solubility. In order to develop more drug-like analogs, their structure was streamlined in this study from both the cytotoxic activity and lipophilicity standpoints. First, a modified total synthetic route was successfully devised to construct a library of 59 systematically designed lamellarin analogs, which were then subjected to cytotoxicity and log P determinations. Along with the 25 first-generation lamellarins previously synthesized in our laboratory, the structure-activity and structure-lipophilicity relationships were extensively evaluated. Our results clearly indicated the additional structural requirements around the lamellarin skeleton which, when combined with those reported previously, can provide invaluable guidance for further modifications to increase the aqueous solubility of these compounds.

CAFFEINATED COMPOUNDS AND COMPOSITIONS FOR TREATMENT OF AMYLOID DISEASES AND SYNUCLEINOPATHIES

-

Page/Page column 35; 36, (2013/05/21)

Compounds and their pharmaceutically acceptable salts for treatment of Beta-amyloid diseases, such as observed in Alzheimer's disease and synucleinopathies, such as Parkinson's disease

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