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17151-27-8

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17151-27-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 17151-27-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,1,5 and 1 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 17151-27:
(7*1)+(6*7)+(5*1)+(4*5)+(3*1)+(2*2)+(1*7)=88
88 % 10 = 8
So 17151-27-8 is a valid CAS Registry Number.
InChI:InChI=1/C11H18OSi/c1-4-12-13(2,3)10-11-8-6-5-7-9-11/h5-9H,4,10H2,1-3H3

17151-27-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name benzyl-ethoxy-dimethylsilane

1.2 Other means of identification

Product number -
Other names Benzylethoxydimethylsilane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17151-27-8 SDS

17151-27-8Relevant articles and documents

Synthesis of alkoxybenzylmethylsilanes and polybenzylmethylsiloxane polymers on their basis

Milenin,Kalinina,Gorodov,Vasilenko,Buzin,Muzafarov

, p. 2498 - 2504 (2016/09/28)

An efficient solvent-free procedure for the preparation of alkoxybenzylmethylsilanes by organomagnesium synthesis was developed. The reaction conditions gave the high yields of the target products. A number of benzylmethylsiloxane polymers was synthesized by polycondensation of alkoxybenzylmethylsilanes in anhydrous acetic acid. The products obtained can become a good alternative to phenylsiloxanes in some practical applications.

Remarkably robust monomeric alkylperoxyzinc compounds from tris(oxazolinyl)boratozinc alkyls and O2

Mukherjee, Debabrata,Ellern, Arkady,Sadow, Aaron D.

experimental part, p. 13018 - 13026 (2012/10/08)

Metal alkylperoxides are remarkable, highly effective, yet often thermally unstable, oxidants that may react through a number of possible pathways including O-O homolytic cleavage, M-O homolytic cleavage, nucleophilic O-atom transfer, and electrophilic O-atom transfer. Here we describe a series of zinc alkyl compounds of the type ToMZnR (ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate; R = Et, n-C3H 7, i-C3H7, t-Bu) that react with O2 at 25 °C to form isolable monomeric alkylperoxides ToMZnOOR in quantitative yield. The series of zinc alkylperoxides is crystallographically characterized, and the structures show systematic variations in the Zn-O-O angle and O-O distances. The observed rate law for the reaction of ToMZnEt (2) and O2 is consistent with a radical chain mechanism, where the rate-limiting SH2 step involves the interaction of ?OOR and ToMZnR. In contrast, ToMZnH and ToMZnMe are unchanged even to 120 °C under 100 psi of O 2 and in the presence of active radical chains (e.g., ?OOEt). This class of zinc alkylperoxides is unusually thermally robust, in that the compounds are unchanged after heating at 120 °C in solution for several days. Yet, these compounds are reactive as oxidants with phosphines. Additionally, an unusual alkylperoxy group transfer to organosilanes affords ToMZnH and ROOSiR3'.

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