172418-32-5

• 

• Basic information

  1. Product Name: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
  2. Synonyms: cataCXium(R) C, trans-Di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium(II);trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II), 97+% [cataCXium C];trans-Di-^m-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(II), 94%;trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II), 97+%;trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II);trans-Bis(acetato)bis[2-[bis(2-Methylphenyl)phosphiNA]benzyl]dipalladiuM(II);trans-Bis(acetato)bis[2-[bis(2;trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium
  3. CAS NO:172418-32-5
  4. Molecular Formula: C₄₆H₄₆O₄P₂Pd₂
  5. Molecular Weight: 937.65
  6. EINECS: N/A
  7. Product Categories: metal-phosphine complexes;Pd
  8. Mol File: 172418-32-5.mol
  9. Article Data: 1

• Chemical Properties

  1. Melting Point: 230°C
  2. Boiling Point: °Cat760mmHg
  3. Flash Point: °C
  4. Appearance: yellow/crystal
  5. Density: g/cm³
  6. Refractive Index: N/A
  7. Storage Temp.: Inert atmosphere,Room Temperature
  8. Solubility: N/A
  9. CAS DataBase Reference: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(CAS DataBase Reference)
  10. NIST Chemistry Reference: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(172418-32-5)
  11. EPA Substance Registry System: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(172418-32-5)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: 36/37/38
  3. Safety Statements: 26-36/37/39
  4. WGK Germany: 3
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 172418-32-5(Hazardous Substances Data)

• Suppliers
• Usage
• Well-known Company Product Price
• SDS
• Upstream product
• Downstream Products
• Article

172418-32-5 Suppliers

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• Palladium, bis[m-(acetato-kO:kO')]bis[[2-[bis(2-methylphenyl)phosphino-kP]phenyl]methyl-kC]di-, stereoisomer

  Cas No: 172418-32-5

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• trans-di-(my-Acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II)

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• (E)-Diacetatobis-{2-[bis-(o-tolyl)-phosphino]-benzyl}-dipalladium

  Cas No: 172418-32-5

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• TIANFU CHEM TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)

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• TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) CAS:172418-32-5

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• trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II)

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• Shandong Hanjiang Chemical Co., Ltd.
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• Palladium, bis[m-(acetato-kO:kO')]bis[[2-[bis(2-methylphenyl)phosphino-kP]phenyl]methyl-kC]di-, stereoisomer

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• trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II)

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172418-32-5 Usage

Reaction

Heck olefination of haloarenes.

Chemical Properties

Yellow powder

Uses

Different sources of media describe the Uses of 172418-32-5 differently. You can refer to the following data:
1. Homogeneous catalyst in carbon-carbon bond forming reactions such as the Heck and Suzuki reactions.
2. trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) is a useful catalyst for C-C and C-N cross coupling reaction.

General Description

sold in collaboration with Solvias AG

Check Digit Verification of cas no

The CAS Registry Mumber 172418-32-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,2,4,1 and 8 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 172418-32:
(8*1)+(7*7)+(6*2)+(5*4)+(4*1)+(3*8)+(2*3)+(1*2)=125
125 % 10 = 5
So 172418-32-5 is a valid CAS Registry Number.

InChI:InChI=1/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*2H,1H3;;/q;;2*-2;2*+1/p+2/rC46H50O4P2Pd2/c1-33-19-7-13-25-41(33)51(42-26-14-8-20-34(42)2)45-29-17-11-23-39(45)31-53(51)47-37(5)49-54(50-38(6)48-53)32-40-24-12-18-30-46(40)52(54,43-27-15-9-21-35(43)3)44-28-16-10-22-36(44)4/h7-30,37-38,51-52H,31-32H2,1-6H3

172418-32-5 Well-known Company Product Price

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• (Code)Product description
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• Aldrich

• (671916)  trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)  98%

• 172418-32-5

• 671916-1G

• 1,250.73CNY

• Detail

• Aldrich

• (671916)  trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)  98%

• 172418-32-5

• 671916-5G

• 4,744.35CNY

• Detail

172418-32-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name	Trans-Di-mu-Acetatobis[2-(di-o-Tolylphosphino)Benzyl]Dipalladium(II)

1.2 Other means of identification

Product number	-
Other names	TRANS-DI(μ-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:172418-32-5 SDS

172418-32-5Upstream product

• 3375-31-3 palladium diacetate 
• 6163-58-2 tris-(o-tolyl)phosphine 

172418-32-5Downstream Products

• 7440-05-3 palladium 
• 69861-71-8 bis(tri-ortho-tolylphosphine)palladium⁽⁰⁾ 
• 1199828-99-3 methyl 1-(benzyloxycarbonylamino)-2,3-dihydro-1H-indene-5-carboxylate 
• 183862-94-4 [Pd(OCOCH₃)(HN(C₂H₅)2)(C₂₁H₂₀P)] 
• 475578-47-3 [(Pd(CH2C6H4P(o-tolyl)2-κC,P)(μ-4-methylpyrazole))2] 
• 475578-46-2 [(Pd(CH2C6H4P(o-tolyl)2-κC,P)(μ-pyrazole))2] 

172418-32-5Relevant articles and documents

Palladacycles as structurally defined catalysts for the heck olefination of chloro- and bromoarenes

Herrmann, Wolfgang A.,Brossmer, Christoph,Oefele, Karl,Reisinger, Claus-Peter,Priermeier, Thomas,Beller, Matthias,Fischer, Hartmut

, p. 1844 - 1848 (1995)

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