1833-27-8Relevant articles and documents
Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
Lv, Haiping,Laishram, Ronibala Devi,Li, Jiayan,Shi, Guangrui,Sun, Weiqing,Xu, Jianbin,Yang, Yong,Luo, Yang,Fan, Baomin
supporting information, p. 971 - 974 (2019/03/07)
We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.
Preparation method of 1,3-diphenyl-1,1,3,3-tetramethyl disiloxane
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Paragraph 0022, (2017/05/25)
The invention discloses a preparation method of 1,3-diphenyl-1,1,3,3-tetramethyl disiloxane. The preparation method is characterized in that the Wurtz method or Grignard method is adopted, and 1,3-diphenyl-1,1,3,3-tetramethyl disiloxane is synthesized through disiloxane rectified from an organosilicon high-boiling component and a halogenated compound. According to the preparation method, market application and high-value utilization of the organosilicon high-boiling component are expanded, and a raw material basis can be further provided for preparation of organosilicon materials with special functions.
SYNTHESIS OF SILICON-CONTAINING ESTERS OF PHOSPHORUS ACIDS AND STUDY OF THEIR THERMAL STABILITY. 3. THERMAL REARRANGEMENT OF TRIORGANOSILYLMETHYL ESTERS OF DIPHENYL PHOSPHORIC ACID
Kabachnik, M. I.,Zakharov, L. S.,Molchanova, G. N.,Drozdova, T. D.,Petrovskii, P. V.
, p. 1527 - 1532 (2007/10/02)
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