18585-06-3 Usage
General Description
ETHYL 4-CHLORO-3-TRIFLUOROMETHYLCARBANILATE is a chemical compound that is commonly used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. It is a white crystalline solid with a molecular formula of C10H8ClF3NO2 and a molecular weight of 269.62 g/mol. ETHYL 4-CHLORO-3-TRIFLUOROMETHYLCARBANILATE is known for its strong insecticidal and fungicidal properties, making it a valuable ingredient in the production of pesticides. It is also used in the manufacturing of various pharmaceuticals due to its ability to inhibit the growth of certain bacteria and fungi.ETHYL 4-CHLORO-3-TRIFLUOROMETHYLCARBANILATE is hazardous if ingested or inhaled and should be handled with care in a well-ventilated area and with protective equipment.
Check Digit Verification of cas no
The CAS Registry Mumber 18585-06-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,5,8 and 5 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 18585-06:
(7*1)+(6*8)+(5*5)+(4*8)+(3*5)+(2*0)+(1*6)=133
133 % 10 = 3
So 18585-06-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H9ClF3NO2/c1-2-17-9(16)15-6-3-4-8(11)7(5-6)10(12,13)14/h3-5H,2H2,1H3,(H,15,16)
18585-06-3Relevant articles and documents
Teaching Old Compounds New Tricks: DDQ-Photocatalyzed C?H Amination of Arenes with Carbamates, Urea, and N-Heterocycles
Das, Somnath,Natarajan, Palani,K?nig, Burkhard
supporting information, p. 18161 - 18165 (2017/12/28)
The C?H amination of benzene derivatives was achieved using DDQ as photocatalyst and BocNH2 as the amine source under aerobic conditions and visible light irradiation. Electron-deficient and electron-rich benzenes react as substrates with moderate to good product yields. The amine scope of the reaction comprises Boc-amine, carbamates, pyrazoles, sulfonimides and urea. Preliminary mechanistic investigations indicate arene oxidation by the triplet of DDQ to radical cations with different electrophilicity and a charge transfer complex between the amine and DDQ as intermediate of the reaction.
