19997-42-3Relevant articles and documents
A Hg(OTf)2-Catalyzed Enolate Umpolung Reaction Enables the Synthesis of Coumaran-3-ones and Indolin-3-ones
Dai, Ning,Hu, Weican,Qian, Guoying,Rong, Zhouting
, p. 3286 - 3290 (2020/04/21)
The potential of mercury catalysis has been extended to the arena of enolate umpolung reactions for the first time by the generation of enolonium species via Hg(OTf)2-catalyzed N-oxide addition to alkynes. The enolonium species formed can undergo intramolecular nucleophilic attack by hydroxyl or amino groups, leading to the synthesis of various coumaran-3-ones and indolin-3-ones.
Facile synthesis of novel fluorescence active 12H-benzo[e]indolo[3,2-b] benzofuran and its derivatives
Karnik,Upadhyay
, p. 1345 - 1348 (2007/10/03)
Successful preparation of novel penta-heterocyclic compounds, 12H-benzo[e]indolo[3,2-b]benzofurans, in good yields is reported. The synthesized compounds with planar geometry and extended conjugation exhibit excellent fluorescence properties.
Synthesis, resolution, and applications of 2,2′-bis(diphenylphosphino)-3,3′-binaphtho[2,1-d]furan
Andersen, Neil G.,Parvez, Masood,Keay, Brian A.
, p. 2817 - 2820 (2007/10/03)
A short five-step synthesis of (±)-2,2′-bis(diphenylphosphino)-3,3′-binaphtho[2,1-b]furan (BINAPFu, 1) starting from 2-naphthoxyacetic acid is reported. The resolution of BINAPFu 1 was possible using our newly developed resolution procedure for phosphines