69974-55-6Relevant articles and documents
Mild and Direct Multiple Deuterium-Labeling of Saturated Fatty Acids
Yamada, Tsuyoshi,Park, Kwihwan,Yasukawa, Naoki,Morita, Kosuke,Monguchi, Yasunari,Sawama, Yoshinari,Sajiki, Hironao
supporting information, p. 3277 - 3282 (2016/10/21)
We have established a mild and direct platinum on carbon (Pt/C)-catalyzed multi-deuterium labeling of various saturated fatty acids including bioactive compounds with high deuterium efficiencies in a mixed solvent of isopropyl alcohol and deuterium oxide
Efficient H/D exchange reactions of alkyl-substituted benzene derivatives by means of the Pd/C-H2-D2O system
Esaki, Hiroyoshi,Aoki, Fumiyo,Umemura, Miho,Kato, Masatsugu,Maegawa, Tomohiro,Monguchi, Yasunari,Sajiki, Hironao
, p. 4052 - 4063 (2008/02/08)
A method for efficient and extensive H/D exchange of substituted benzene derivatives which is catalyzed by heterogeneous Pd/C in D2O as a deuterium source under hydrogen atmosphere is described. Multideuterium incorporation into unactivated linear or branched alkyl chains that bear a carboxyl, hydroxyl, ether, ester, or amide moiety and are connected with a benzene ring was achieved by using the Pd/C-H2-D2O system. The present method does not require expensive deuterium gas or any special equipment.
