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2-trimethylsilyltetrahydrothiophene-3,4-(N-phenyl)dicarboxyimide is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

100005-02-5

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100005-02-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 100005-02-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,0,0,0 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 100005-02:
(8*1)+(7*0)+(6*0)+(5*0)+(4*0)+(3*5)+(2*0)+(1*2)=25
25 % 10 = 5
So 100005-02-5 is a valid CAS Registry Number.

100005-02-5Relevant academic research and scientific papers

NEW GENERATION OF THIOCARBONYL YLIDE AND ITS 1,3-CYCLOADDITION LEADING TO TETRAHYDROTHIOPHENE DERIVATIVES

Terao, Yoshiyasu,Tanaka, Masaki,Imai, Nobuyuki,Achiwa, Kazuo

, p. 3011 - 3014 (1985)

Thiocarbonyl ylide was found to be generated by thermolysis of bromo(trimethylsilylmethylthio)methyltrimethylsilane and its 1,3-cycloaddition provided a new method for synthesis of tetrahydrothiophenes.

Thiocarbonyl Ylides. VI. New Generation of Thiocarbonyl Ylides from Organosilicon Compounds Containing Sulfur and Their 1,3-Cycloadditions

Terao, Yoshiyasu,Aono, Masahiro,Imai, Nobuyuki,Achiwa, Kazuo

, p. 1734 - 1740 (2007/10/02)

Thermolysis of bromo(trimethylsilyl)methyltrimethylsilylmethyl sulfide was found to give a thiocarbonyl ylide, the 1,3-cycloaddition of which proved a new method for the synthesis of tetrahydrothiophenes.The effect of the silyl group of the ylide on the regio- and stereoselectivity in these 1,3-dipolar cycloaddtions is discussed.Keywords---thiocarbonyl ylide; 1,3-cycloaddition; organosilicon compound; thermolysis; tetrahydrothiophene; regioselectivity

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