1000153-25-2Relevant academic research and scientific papers
Reprint of "Allene-alkyne cross-coupling for stereoselective synthesis of substituted 1,4-dienes and cross-conjugated trienes"
Shimp, Heidi L.,Hare, Alissa,McLaughlin, Martin,Micalizio, Glenn C.
, p. 6831 - 6837 (2008/09/21)
Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays a critical role in the determination of reaction pathway.
Allene-alkyne cross-coupling for stereoselective synthesis of substituted 1,4-dienes and cross-conjugated trienes
Shimp, Heidi L.,Hare, Alissa,McLaughlin, Martin,Micalizio, Glenn C.
, p. 3437 - 3445 (2008/09/20)
Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays
An alkoxide-directed alkyne-allene cross-coupling for stereoselective synthesis of 1,4-dienes
Shimp, Heidi L.,Micalizio, Glenn C.
, p. 4531 - 4533 (2008/09/16)
A titanium alkoxide-mediated convergent coupling between internal alkynes and allenes is described for the regio- and stereocontrolled synthesis of substituted acyclic 1,4-dienes. The Royal Society of Chemistry.
