1000592-11-9Relevant academic research and scientific papers
Highly efficient gold(I)-catalyzed Overman rearrangement in water
Xing, Dong,Yang, Dan
, p. 781 - 785 (2011)
A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacet
Effect of halogenation reagents on halocyclization and Overman rearrangement of allylic trichloroacetimidates
Liu, Na,Schienebeck, Casi M.,Collier, Michelle D.,Tang, Weiping
, p. 6217 - 6219 (2011/12/14)
Electrophilic halogen can promote either halocyclization or Overman rearrangement of allylic trichloroacetimidates. We found that the chemoselectivity was dependent on the nature of the halogenation reagents for primary allylic trichloroacetimidates. A one-pot procedure was developed for the preparation of allylic trichloroacetamides directly from allylic alcohols at room temperature.
