1000622-41-2Relevant academic research and scientific papers
Redox-responsive conformational alteration of aromatic amides bearing N-quinonyl system
Okamoto, Iwao,Takahashi, Yusuke,Sawamura, Mika,Matsumura, Mio,Masu, Hyuma,Katagiri, Kosuke,Azumaya, Isao,Nishino, Masanori,Kohama, Yukari,Morita, Nobuyoshi,Tamura, Osamu,Kagechika, Hiroyuki,Tanatani, Aya
experimental part, p. 5346 - 5355 (2012/09/07)
Redox-induced conformational alteration of N-aryl-N-phenylamides, in which the N-aryl group consists of a hydroquinone-p-quinone system, was examined. The reduced form bearing a dihydroxyphenyl or dimethoxyphenyl group exists mainly in the E-form, whereas the oxidized form bearing a N-benzoquinone moiety takes the Z-form both in the crystal and in solution. This redox-induced conformational alteration is associated with a marked change in optical properties. This system appears to have suitable properties for use in external redox stimulus-responsive functional switching.
Redox-induced conformational alteration of N,N-diarylamides
Okamoto, Iwao,Yamasaki, Ryu,Sawamura, Mika,Kato, Takako,Nagayama, Naomi,Takeya, Tetsuya,Tamura, Osamu,Masu, Hyuma,Azumaya, Isao,Yamaguchi, Kentaro,Kagechika, Hiroyuki,Tanatani, Aya
, p. 5545 - 5547 (2008/09/17)
We constructed a novel molecular conformational alteration system with an N-aryl-N-phenylacetamide structure, in which the N-aryl group consists of a hydroquinone-p-quinone system as a redox-dependent aromatic trigger. The amide conformation depended on t
