1000682-39-2

Basic information

• Product Name: Methyl 5-(4-broMophenyl)-1H-pyrrole-2-carboxylate
• Synonyms: Methyl 5-(4-broMophenyl)-1H-pyrrole-2-carboxylate;5-(4-Bromophenyl)-1H-pyrrole-2-carboxylic acid methyl ester
• CAS NO: 1000682-39-2
• Molecular Formula: C₁₂H₁₀BrNO₂
• Molecular Weight: 280.1173
• Mol File: 1000682-39-2.mol
• Article Data: 2

Chemical Properties

• Melting Point: 182-183℃
• Appearance: /
• Density: 1.497
• CAS DataBase Reference: Methyl 5-(4-broMophenyl)-1H-pyrrole-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 5-(4-broMophenyl)-1H-pyrrole-2-carboxylate(1000682-39-2)
• EPA Substance Registry System: Methyl 5-(4-broMophenyl)-1H-pyrrole-2-carboxylate(1000682-39-2)

Safety Data

• Hazardous Substances Data: 1000682-39-2(Hazardous Substances Data)

Upstream product

• 17101-78-9 <(1-bromoethenyl)sulfonyl>benzene 
• 139575-14-7 N-(4-bromobenzylidene)glycine methyl ester 
• 1000682-26-7 C₁₂H₁₀BrN₃O₂ 

Relevant articles and documents

Phenyl α-bromovinyl sulfone in cycloadditions with azomethine ylides: An unexpected facile aromatization of the cycloadducts into pyrroles

Phenyl α-bromovinyl sulfone reacts with glycine ester Schiff bases regioselectively in the presence of catalytic amounts of AgOAc and DBU yielding polysubstituted pyrrolidine cycloadducts. Utilization of excess DBU induces subsequent facile aromatization of the cycloadducts and affords 5-arylpyrrole-2-carboxylic acid esters in 39-85% yields in a single step.